3D patterned fabric-based wearable micro-supercapacitor operating at high voltage by electrostatic actuation
Source abstract
Abstract
To address the energy storage needs of wearable electronics, this study developed high-performance, flexible micro-supercapacitors (MSCs) using 2D and 3D patterned fabric-based microelectrodes. The 2D electrodes were created via a screen-printing method with an omnidirectional pre-stretching strategy, while 3D array-structured electrodes were formed through electrostatic actuation. Nano-MnO 2 and Na 0.77 MnO 2 were deposited to enhance pseudo-capacitive storage and widen the electrochemical window. The C-C/MnO 2 -based MSCs exhibited a 21% pseudo-capacitance ratio, achieving an area-specific capacitance of 118.2 mF cm −2 at 5 mV s −1 and an energy density of 39.25 mWh cm −2 at 0.21 mW cm −2 . These MSCs maintained 95.05%, 92.04%, and 89.74% of their capacitance under stretched, twisted, and folded conditions, respectively, and showed stable performance across temperatures from −20 °C to 60 °C. Additionally, C-C/Na 0.77 MnO 2 -based MSCs extended the electrochemical window to 1.6 V and retained 100.2% capacitance after 6500 cycles. This work offers innovative strategies for advancing portable and wearable electronic devices.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Sensor and Energy Harvesting Materials · Advanced Materials and Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (57)
Show source-provided references
1. Feng, X. et al. Recent advances in micro-supercapacitors for AC line-filtering performance: from fundamental models to emerging applications. EScience 1, 124–140 (2021).10.1016/j.esci.2021.11.005 ↗
2. Zhang, P., Wang, F., Yu, M., Zhuang, X. & Feng, X. Two-dimensional materials for miniaturized energy storage devices: from individual devices to smart integrated systems. Chem. Soc. Rev. 47, 7426–7451 (2018).10.1039/C8CS00561C ↗
3. Huang, P. et al. On-chip and freestanding elastic carbon films for micro-supercapacitors. Sci 351, 691–695 (2016).10.1126/science.aad3345 ↗
4. Kyeremateng, N. A., Brousse, T. & Pech, D. Microsupercapacitors as miniaturized energy-storage components for on-chip electronics. Nat. Nanotechnol. 12, 7–15 (2017).10.1038/nnano.2016.196 ↗
5. Wang, D. et al. Chemical formation of soft metal electrodes for flexible and wearable electronics. Chem. Soc. Rev. 47, 4611–4641 (2018).10.1039/C7CS00192D ↗
6. Chen, X., Paul, R. & Dai, L. Carbon-based supercapacitors for efficient energy storage. Natl Sci. Rev. 4, 453–489 (2017).10.1093/nsr/nwx009 ↗
7. Mustaqeem, M. et al. Rational design of metal oxide based electrode materials for high performance supercapacitors-a review. J. Energy Storage 55, 105419 (2022).10.1016/j.est.2022.105419 ↗
8. Wang, Y., Ding, Y., Guo, X. & Yu, G. Conductive polymers for stretchable supercapacitors. Nano Res. 12, 1978–1987 (2019).10.1007/s12274-019-2296-9 ↗
9. Xu, P. et al. Carbon nanotube fiber based stretchable wire‐shaped supercapacitors. Adv. Energy Mater. 4, 1300759 (2014).10.1002/aenm.201300759 ↗
10. Pu, J., Wang, X., Xu, R. & Komvopoulos, K. Highly stretchable microsupercapacitor arrays with honeycomb structures for integrated wearable electronic systems. ACS Nano 10, 9306–9315 (2016).10.1021/acsnano.6b03880 ↗
11. Lu, Z., Foroughi, J., Wang, C., Long, H. & Wallace, G. G. Superelastic hybrid CNT/graphene fibers for wearable energy storage. Adv. Energy Mater. 8, 1702047 (2018).10.1002/aenm.201702047 ↗
12. Kim, D., Shin, G., Kang, Y. J., Kim, W. & Ha, J. S. Fabrication of a stretchable solid-state micro-supercapacitor array. ACS Nano 7, 7975–7982 (2013).10.1021/nn403068d ↗
13. Xu, R. et al. Kirigami-inspired, highly stretchable micro-supercapacitor patches fabricated by laser conversion and cutting. Microsyst. Nanoeng. 4, 1–10 (2018).10.1038/s41378-018-0036-z ↗
14. Hong, S. Y. et al. High-density, stretchable, all-solid-state microsupercapacitor arrays. ACS Nano 8, 8844–8855 (2014).10.1021/nn503799j ↗
15. Yue, Y. et al. Highly self-healable 3D microsupercapacitor with MXene–graphene composite aerogel. ACS Nano 12, 4224–4232 (2018).10.1021/acsnano.7b07528 ↗
16. Lim, Y. et al. Biaxially stretchable, integrated array of high performance microsupercapacitors. ACS Nano 8, 11639–11650 (2014).10.1021/nn504925s ↗
17. Cong, Z. et al. Stretchable coplanar self-charging power textile with resist-dyeing triboelectric nanogenerators and microsupercapacitors. ACS Nano 14, 5590–5599 (2020).10.1021/acsnano.9b09994 ↗
18. Zhang, H., Qiao, Y. & Lu, Z. Fully printed ultraflexible supercapacitor supported by a single-textile substrate. ACS Appl. Mater. Inter. 8, 32317–32323 (2016).10.1021/acsami.6b11172 ↗
19. Xie, X. et al. Stencil-printed electrodes without current collectors and inactive additives on textiles for in-plane microsupercapacitors. J. Mater. Chem. A. 9, 25042–25050 (2021).10.1039/D1TA07302H ↗
20. Lv, J. et al. Transforming commercial regenerated cellulose yarns into multifunctional wearable electronic textiles. J. Mater. Chem. C. 8, 1309–1318 (2020).10.1039/C9TC05673D ↗
21. Li, X. et al. Wearable solid-state supercapacitors operating at high working voltage with a flexible nanocomposite electrode. ACS Appl. Mater. Inter. 8, 25905–25914 (2016).10.1021/acsami.6b06156 ↗
22. Xiaoping, L. et al. Design and construction of 1D/2D/3D fabric-based wearable micro-supercapacitors. J. Power Sources 560, 232712 (2023).10.1016/j.jpowsour.2023.232712 ↗
23. Gao, P. et al. The critical role of point defects in improving the specific capacitance of δ-MnO2 nanosheets. Nat. Commun. 8, 14559 (2017).10.1038/ncomms14559 ↗
24. Wang, Y., Zhang, Y.-Z., Dubbink, D. & ten Elshof, J. E. Inkjet printing of δ-MnO2 nanosheets for flexible solid-state micro-supercapacitor. Nano Energy 49, 481–488 (2018).10.1016/j.nanoen.2018.05.002 ↗
25. Abbas, S. et al. Zn doping induces rich oxygen vacancies in δ-MnO2 flower-like nanostructures for impressive energy density coin cell supercapacitor. J. Energy Storage 87, 111455 (2024).10.1016/j.est.2024.111455 ↗
26. Can, T. et al. Optimizing the electrons/ions diffusion kinetics in δ-MnO2 for realizing an ultra-high rate-capability supercapacitor. Chem. Eng. J. 471, 144784 (2023).10.1016/j.cej.2023.144784 ↗
27. Gnerlich, M., Ben-Yoav, H., Culver, J. N., Ketchum, D. R. & Ghodssi, R. Selective deposition of nanostructured ruthenium oxide using Tobacco mosaic virus for micro-supercapacitors in solid Nafion electrolyte. J. Power Sources 293, 649–656 (2015).10.1016/j.jpowsour.2015.05.053 ↗
28. Kim, K.-W. et al. Deformable micro-supercapacitor fabricated via laser ablation patterning of Graphene/liquid metal. npj Flex. Electron. 8, 18 (2024).10.1038/s41528-024-00306-2 ↗
29. Liu, L. et al. 3D printing of high-performance micro-supercapacitors with patterned exfoliated graphene/carbon nanotube/silver nanowire electrodes. Sci. China Technol. Sci. 64, 1065–1073 (2021).10.1007/s11431-020-1763-5 ↗
30. Wang, X., Yin, Y., Hao, C. & You, Z. A high-performance three-dimensional micro supercapacitor based on ripple-like ruthenium oxide-carbon nanotube composite films. Carbon 82, 436–445 (2015).10.1016/j.carbon.2014.10.087 ↗
31. Li, X. et al. Three-dimensional stretchable fabric-based electrode for supercapacitors prepared by electrostatic flocking. Chem. Eng. J. 390, 124442 (2020).10.1016/j.cej.2020.124442 ↗
32. Yu, M., Lu, Y., Zheng, H. & Lu, X. New insights into the operating voltage of aqueous supercapacitors. Chem. Eur. J. 24, 3639–3649 (2018).10.1002/chem.201704420 ↗
33. Zhao, L. et al. Honeycomb porous MnO2 nanofibers assembled from radially grown nanosheets for aqueous supercapacitors with high working voltage and energy density. Nano Energy 4, 39–48 (2014).10.1016/j.nanoen.2013.12.008 ↗
34. Li, X. et al. Different metal cation-doped MnO2/carbon cloth for wide voltage energy storage. J. Colloid Interf. Sci. 649, 731–740 (2023).10.1016/j.jcis.2023.06.145 ↗
35. Shan, X. et al. Framework doping of Ni enhances pseudocapacitive Na-ion storage of (Ni) MnO2 layered birnessite. Chem. Mater. 31, 8774–8786 (2019).10.1021/acs.chemmater.9b02568 ↗
36. Shan, X. et al. Structural water and disordered structure promote aqueous sodium-ion energy storage in sodium-birnessite. Nat. Commun. 10, 4975 (2019).10.1038/s41467-019-12939-3 ↗
37. Eustache, E. et al. High areal energy 3D-interdigitated micro‐supercapacitors in aqueous and ionic liquid electrolytes. Adv. Mater. Technol. 2, 1700126 (2017).10.1002/admt.201700126 ↗
38. Zheng, X. et al. Highly stretchable CNT/MnO2 nanosheets fiber supercapacitors with high energy density. J. Mater. Sci. 55, 8251–8263 (2020).10.1007/s10853-020-04608-4 ↗
39. Liu, N. et al. Cable‐type supercapacitors of three‐dimensional cotton thread based multi‐grade nanostructures for wearable energy storage. Adv. Mater. 25, 4925–4931 (2013).10.1002/adma.201301311 ↗
40. Wang, J. et al. Polymorphous supercapacitors constructed from flexible three-dimensional carbon network/polyaniline/MnO2 composite textiles. ACS Appl. Mater. Inter. 10, 10851–10859 (2018).10.1021/acsami.7b19195 ↗
41. Wang, Y. et al. Silicon-based 3D all-solid-state micro-supercapacitor with superior performance. ACS Appl. Mater. Inter. 12, 43864–43875 (2020).10.1021/acsami.0c14441 ↗
42. Du, J. et al. High-performance pseudocapacitive micro-supercapacitors with three-dimensional current collector of vertical ITO nanowire arrays. J. Mater. Chem. A. 7, 6220–6227 (2019).10.1039/C9TA00364A ↗
43. Liu, J. et al. Advanced energy storage devices: basic principles, analytical methods, and rational materials design. Adv. Sci. 5, 1700322 (2018).10.1002/advs.201700322 ↗
44. Gao, P. et al. Understanding the synergistic effects and structural evolution of Co(OH)2 and Co3O4 toward boosting electrochemical charge storage. Adv. Funct. Mater. 32, 2108644 (2022).10.1002/adfm.202108644 ↗
45. Jabeen, N. et al. High‐performance 2.6 V aqueous asymmetric supercapacitors based on in situ formed Na0.5MnO2 nanosheet assembled nanowall arrays. Adv. Mater. 29, 1700804 (2017).10.1002/adma.201700804 ↗
46. Yazar, S., Arvas, B., Arvas, M. B., Yolacan, C. & Sahin, Y. A biocompatible and flexible supercapacitor for wearable electronic devices. J. Energy Storage 74, 109400 (2023).10.1016/j.est.2023.109400 ↗
47. Gürkan, K., Karaman, H. & Ballikaya, S. Optimization of high-performance flexible thermoelectric generator from material synthesis to simulation and device application. Energ. Convers. Manag. 291, 117335 (2023).10.1016/j.enconman.2023.117335 ↗
48. Wang, Y. et al. Fixture-free omnidirectional prestretching fabrication and integration of crumpled in-plane micro-supercapacitors. Sci. Adv. 8, eabn8338 (2022).10.1126/sciadv.abn8338 ↗
49. Ren, J. et al. Twisting carbon nanotube fibers for both wire‐shaped micro‐supercapacitor and micro‐battery. Adv. Mater. 25, 1155–1159 (2013).10.1002/adma.201203445 ↗
50. Kim, C. & Moon, J. H. 3D bicontinuous structure of a pseudocapacitive ultrathin shell/carbon core: a novel electrode for thin-film supercapacitors with high areal energy density. ACS Sustain. Chem. Eng. 8, 14711–14717 (2020).10.1021/acssuschemeng.0c02058 ↗
51. Sajedi-Moghaddam, A., Gholami, M. & Naseri, N. Inkjet printing of MnO2 nanoflowers on surface-modified A4 paper for flexible all-solid-state microsupercapacitors. ACS Appl. Mater. Inter. 15, 3894–3903 (2023).10.1021/acsami.2c08939 ↗
52. Xu, R., Wang, Z., Gao, L., Wang, S. & Zhao, J. Effective design of MnO2 nanoparticles embedded in laser-induced graphene as shape-controllable electrodes for flexible planar microsupercapacitors. Appl. Surf. Sci. 571, 151385 (2022).10.1016/j.apsusc.2021.151385 ↗
53. Boruah, B. D., Maji, A. & Misra, A. Flexible array of microsupercapacitor for additive energy storage performance over a large area. ACS Appl. Mater. Inter. 10, 15864–15872 (2018).10.1021/acsami.8b02660 ↗
54. Patil, S. J., Park, J. S., Kim, Y. B. & Lee, D. W. A quasi 2D flexible micro‐supercapacitor based on MnO2//NiCo2O4 as a miniaturized energy‐storage device. Energy Technol. 6, 1380–1391 (2018).10.1002/ente.201700826 ↗
55. Hu, H., Pei, Z., Fan, H. & Ye, C. 3D interdigital Au/MnO2/Au stacked hybrid electrodes for on‐chip microsupercapacitors. Small 12, 3059–3069 (2016).10.1002/smll.201503527 ↗
56. Tao, S. et al. Important effect of Pt modification at the collector/active material interface of flexible micro-supercapacitors. Appl. Surf. Sci. 456, 410–418 (2018).10.1016/j.apsusc.2018.06.144 ↗
57. Wang, N., Liu, J., Zhao, Y., Hu, M. & Shan, G. High-performance asymmetric micro-supercapacitors based on electrodeposited MnO2 and N-doped graphene. Nanotechnology 30, 235403 (2019).10.1088/1361-6528/ab0bd8 ↗