journal article·2025-11-17Open access

Monolithically integrated ionic triboelectric nanogenerators for deformable energy harvesting and self powered sensing

Ji Hye Han, Hong Chul Moon

npj Flexible Electronics· Volume 9· Issue 1

Abstract

Stretchable triboelectric nanogenerators (TENGs) have garnered significant attention as wearable power sources by enabling the realization of self-powered systems through integration with other wearable platforms. However, achieving intrinsically stretchable TENGs with stable performance under deformation remains a major challenge, particularly in forming robust dielectric/electrode interfaces and fabricating fully stretchable materials. Here, we propose the intrinsically stretchable ionogel-based TENGs (S-iTENG) with a monolithic structure by directly coating silver nanowires (AgNWs) onto free-standing ionogel. The ionogel serves as the substrate, charge-generating, and trapping layer, simplifying device configuration. Its hydrophilic characteristics improve the wettability of AgNWs and their interfacial adhesion. The optimized S-iTENG exhibits a power density of ~109.8 mW·m − 2 , excellent stretchability (~195%), and stable operation even under 80% strain. The practical feasibility of the S-iTENG is demonstrated in self-powered sensory platforms. Overall, these results highlight the significance of monolithic, substrate-free S-iTENG as wearable energy harvesters and key components for future wearable electronics.
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Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Dielectric materials and actuators · Conducting polymers and applications

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References (55)

Show source-provided references
1. Wu, C., Wang, A. C., Ding, W., Guo, H. & Wang, Z. L. Triboelectric nanogenerator: A foundation of the energy for the new era. Adv. Energy Mater. 9, 1802906 (2019).10.1002/aenm.201802906 ↗
2. Zhang, S. L. et al. Rationally designed sea snake structure based triboelectric nanogenerators for effectively and efficiently harvesting ocean wave energy with minimized water screening effect. Nano Energy 48, 421–429 (2018).10.1016/j.nanoen.2018.03.062 ↗
3. Yu, Y. et al. Biocompatibility and in vivo operation of implantable mesoporous PVDF-based nanogenerators. Nano Energy 27, 275–281 (2016).10.1016/j.nanoen.2016.07.015 ↗
4. Garg, R. et al. Polarization-induced mechanically socketed ultra-stretchable and breathable textile-based nanogenerator and pressure sensor. Adv. Funct. Mater. 34, 2401593 (2024).10.1002/adfm.202401593 ↗
5. Lee, J. H., Yu, I., Hyun, S., Kim, J. K. & Jeong, U. Remarkable increase in triboelectrification by enhancing the conformable contact and adhesion energy with a film-covered pillar structure. Nano Energy 34, 233–241 (2017).10.1016/j.nanoen.2017.02.032 ↗
6. Wang, S. et al. Maximum surface charge density for triboelectric nanogenerators achieved by ionized-air injection: Methodology and theoretical understanding. Adv. Mater. 26, 6720–6728 (2014).10.1002/adma.201402491 ↗
7. Chen, X. et al. Electron trapping & blocking effect enabled by MXene/TiO₂ intermediate layer for charge regulation of triboelectric nanogenerators. Nano Energy 98, 107236 (2022).10.1016/j.nanoen.2022.107236 ↗
8. Park, H. et al. Electron blocking layer-based interfacial design for highly-enhanced triboelectric nanogenerators. Nano Energy 50, 9–15 (2018).10.1016/j.nanoen.2018.05.024 ↗
9. Wu, C. et al. Enhanced triboelectric nanogenerators based on MoS₂ monolayer nanocomposites acting as electron-acceptor layers. ACS Nano 11, 8356–8363 (2017).10.1021/acsnano.7b03657 ↗
10. Seung, W. et al. Nanopatterned textile-based wearable triboelectric nanogenerator. ACS Nano 9, 3501–3509 (2015).10.1021/nn507221f ↗
11. Luo, J. et al. Flexible and durable wood-based triboelectric nanogenerators for self-powered sensing in athletic big data analytics. Nat. Commun. 10, 5147 (2019).10.1038/s41467-019-13166-6 ↗
12. Li, H. et al. Multi-scale metal mesh based triboelectric nanogenerator for mechanical energy harvesting and respiratory monitoring. Nano Energy 89, 106423 (2021).10.1016/j.nanoen.2021.106423 ↗
13. Bai, P. et al. Integrated multilayered triboelectric nanogenerator for harvesting biomechanical energy from human motions. ACS Nano 7, 3713–3719 (2013).10.1021/nn4007708 ↗
14. Chung, I. J. et al. Layer-by-layer assembled graphene multilayers on multidimensional surfaces for highly durable, scalable, and wearable triboelectric nanogenerators. J. Mater. Chem. A 6, 3108–3115 (2018).10.1039/C7TA09876F ↗
15. Zhao, L., Lin, Z. & Lai, K. W. C. Skin-integrated, stretchable triboelectric nanogenerator for energy harvesting and mechanical sensing. Mater. Today Electron. 2, 100012 (2022).10.1016/j.mtelec.2022.100012 ↗
16. Salauddin, M. et al. Highly electronegative V2CTx/silicone nanocomposite-based serpentine triboelectric nanogenerator for wearable self-powered sensors and sign language interpretation. Adv. Energy Mater. 13, 2203812 (2023).10.1002/aenm.202203812 ↗
17. Liu, Z., Zhao, Z., Zeng, X., Fu, X. & Hu, Y. Ultrathin, flexible and transparent graphene-based triboelectric nanogenerators for attachable curvature monitoring. J. Phys. D: Appl. Phys. 52, 314002 (2019).10.1088/1361-6463/ab1faa ↗
18. Zhang, Y. et al. Ultra-thin and sensitive pressure sensor based on MXene/PVDF-HFP composite fiber TENG for self-diagnosis of ligament injuries. Nano Energy 132, 110372 (2024).10.1016/j.nanoen.2024.110372 ↗
19. Lim, D. U. et al. Ion-impregnated intermediate layer for enhancing triboelectric nanogenerator performance. Adv. Funct. Mater. 34, 2401717 (2024).10.1002/adfm.202401717 ↗
20. Kim, Y. M. & Moon, H. C. Ionoskins: nonvolatile, highly transparent, ultrastretchable ionic sensory platforms for wearable electronics. Adv. Funct. Mater. 30, 1907290 (2020).10.1002/adfm.201907290 ↗
21. Ding, Y. et al. Preparation of high-performance ionogels with excellent transparency, good mechanical strength, and high conductivity. Adv. Mater. 29, 1704253 (2017).10.1002/adma.201704253 ↗
22. Kim, Y. M., Kwon, J. H., Kim, S., Choi, U. H. & Moon, H. C. Ion-cluster-mediated ultrafast self-healable ionoconductors for reconfigurable electronics. Nat. Commun. 13, 3769 (2022).10.1038/s41467-022-31553-4 ↗
23. Ren, Y. et al. Ionic liquid-based click-ionogels. Adv. Sci. 5, eaax0648 (2019).10.1126/sciadv.aax0648 ↗
24. Kim, Y. M., Yu, K. S. & Moon, H. C. Regulating the π-π interactions of copolymer gelators: Effective molecular design of highly stretchable and tough ionogels for wearable ionotronics. Chem. Eng. J. 480, 147947 (2024).10.1016/j.cej.2023.147947 ↗
25. Liu, Y. et al. Versatile ion-gel fibrous membrane for energy-harvesting iontronic skin. Adv. Funct. Mater. 33, 2303723 (2023).10.1002/adfm.202303723 ↗
26. Li, G. et al. Transparent, stretchable and high-performance triboelectric nanogenerator based on dehydration-free ionically conductive solid polymer electrode. Nano Energy 88, 106289 (2021).10.1016/j.nanoen.2021.106289 ↗
27. Han, J. H., Kim, S. Y. & Moon, H. C. Unveiling the impact of tailoring ionic conductor characteristics on the performance of wearable triboelectric nanogenerators. ACS Appl. Mater. Interfaces 16, 27778–27784 (2024).10.1021/acsami.4c04169 ↗
28. Wang, S., Ding, L., Fan, X., Jiang, W. & Gong, X. A liquid metal-based triboelectric nanogenerator as stretchable electronics for safeguarding and self-powered mechanosensing. Nano Energy 53, 863–870 (2018).10.1016/j.nanoen.2018.09.035 ↗
29. Yang, L. et al. Stretchable triboelectric nanogenerator based on liquid metal with varying phases. Adv. Sci. 11, 2405792 (2024).10.1002/advs.202405792 ↗
30. Pan, C., Liu, D., Ford, M. J. & Majidi, C. Ultrastretchable, wearable triboelectric nanogenerator based on sedimented liquid metal elastomer composite. Adv. Mater. Technol. 5, 2000754 (2020).10.1002/admt.202000754 ↗
31. Jiang, F. et al. Stretchable, breathable, and stable lead-free perovskite/polymer nanofiber composite for hybrid triboelectric and piezoelectric energy harvesting. Adv. Mater. 34, 2200042 (2022).10.1002/adma.202200042 ↗
32. Hu, S. et al. A stretchable multimode triboelectric nanogenerator for energy harvesting and self-powered sensing. Adv. Mater. Technol. 7, 2100870 (2022).10.1002/admt.202100870 ↗
33. Xiong, Q., Yang, Z. & Zhang, X. Flexible triboelectric nanogenerator based on silk fibroin-modified carbon nanotube arrays. Chem. Eng. J. 482, 148986 (2024).10.1016/j.cej.2024.148986 ↗
34. Oguntoye, M., Johnson, M., Pratt, L. & Pesika, N. S. Triboelectricity generation from vertically aligned carbon nanotube arrays. ACS Appl. Mater. Interfaces 8, 27454–27457 (2016).10.1021/acsami.6b11457 ↗
35. Lai, Y.-C. et al. Preparation of high-performance ionogels with excellent transparency, good mechanical strength, and high conductivity. Adv. Mater. 29, 1704253 (2017).10.1002/adma.201704253 ↗
36. Hwang, B.-U. et al. Transparent stretchable self-powered patchable sensor platform with ultrasensitive recognition of human activities. ACS Nano 9, 8801–8810 (2015).10.1021/acsnano.5b01835 ↗
37. Liang, X. et al. Highly transparent triboelectric nanogenerator utilizing in-situ chemically welded silver nanowire network as electrode for mechanical energy harvesting and body motion monitoring. Nano Energy 59, 508–516 (2019).10.1016/j.nanoen.2019.02.071 ↗
38. Kwon, N. Y. et al. Uniform silver nanowire patterned electrode on robust PEN substrate using poly(2-hydroxyethyl methacrylate) underlayer. ACS Appl. Mater. Interfaces 14, 34909–34917 (2022).10.1021/acsami.2c07063 ↗
39. Xiong, M. et al. Silver nanowires deposited on triblock copolymer microfibers for stretchable conductive fabrics. ACS Appl. Nano Mater. 5, 17721–17730 (2022).10.1021/acsanm.2c03669 ↗
40. Prameswati, A. et al. Highly stretchable and mechanically robust silver nanowires on surface-functionalized wavy elastomers for wearable healthcare electronics. Org. Electron. 108, 106584 (2022).10.1016/j.orgel.2022.106584 ↗
41. Liu, H.-S., Pan, B.-C. & Liou, G.-S. Highly transparent AgNW/PDMS stretchable electrodes for elastomeric electrochromic devices. Nanoscale 9, 2633–2639 (2017).10.1039/C6NR09220A ↗
42. Hong, S. H., Kim, Y. M. & Moon, H. C. Dynamic metal–ligand coordination-assisted ionogels for deformable alternating current electroluminescent devices. ACS Appl. Mater. Interfaces 15, 28516–28523 (2023).10.1021/acsami.3c03812 ↗
43. Hwang, H. J. et al. An ultra-mechanosensitive visco-poroelastic polymer ion pump for continuous self-powering kinematic triboelectric nanogenerators. Adv. Energy Mater. 9, 1803786 (2019).10.1002/aenm.201803786 ↗
44. Kim, Y. et al. Ionic liquid-based molecular design for transparent, flexible, and fire-retardant triboelectric nanogenerator (TENG) for wearable energy solutions. Nano Energy 84, 105925 (2021).10.1016/j.nanoen.2021.105925 ↗
45. Hwang, H. J. et al. Ionic liquid with hydrogen bonding reducing leakage charge for enhancing triboelectric performance. Nano Energy 125, 109535 (2024).10.1016/j.nanoen.2024.109535 ↗
46. Lee, K. H., Zhang, S., Lodge, T. P. & Frisbie, C. D. Electrical impedance of spin-coatable ion gel films. J. Phys. Chem. B 115, 3315–3321 (2011).10.1021/jp110166u ↗
47. Sardana, S. et al. Flexible, humidity- and contamination-resistant superhydrophobic MXene-based electrospun triboelectric nanogenerators for distributed energy harvesting applications. Nanoscale 15, 19369–19380 (2023).10.1039/D3NR04537D ↗
48. Cheng, Y., Zhu, W., Lu, X. & Wang, C. Mechanically robust, stretchable, autonomously adhesive, and environmentally tolerant triboelectric electronic skin for self-powered healthcare monitoring and tactile sensing. Nano Energy 102, 107636 (2022).10.1016/j.nanoen.2022.107636 ↗
49. Jiang, C. et al. All-electrospun flexible triboelectric nanogenerator based on metallic MXene nanosheets. Nano Energy 59, 268–276 (2019).10.1016/j.nanoen.2019.02.052 ↗
50. Shen, X. et al. Punching pores on cellulose fiber paper as the spacer of triboelectric nanogenerator for monitoring human motion. Energy Rep. 6, 2851–2860 (2020).10.1016/j.egyr.2020.10.011 ↗
51. Niu, S. et al. Theoretical study of contact-mode triboelectric nanogenerators as an effective power source. Energy Environ. Sci. 6, 3576–3583 (2013).10.1039/c3ee42571a ↗
52. Jansen, J. C., Friess, K., Clarizia, G., Schauer, J. & Izak, P. High ionic liquid content polymeric gel membranes: Preparation and performance. Macromolecules 44, 39–45 (2011).10.1021/ma102438k ↗
53. Souri, H. et al. Wearable and stretchable strain sensors: Materials, sensing mechanisms, and applications. Adv. Intell. Syst. 2, 2000039 (2020).10.1002/aisy.202000039 ↗
54. Yadav, A., Yadav, N., Wu, Y., Ramakrishna, S. & Hongyu, Z. Wearable strain sensors: state-of-the-art and future applications. Mater. Adv. 4, 1444–1459 (2023).10.1039/D2MA00818A ↗
55. Zhu, G. et al. Toward large-scale energy harvesting by a nanoparticle-enhanced triboelectric nanogenerator. Nano Lett. 13, 847–853 (2013).10.1021/nl4001053 ↗