journal article·2021-12-03Open access

Single-atom catalytic growth of crystals using graphene as a case study

Xiaoqin Yang, Yu Liu, Huy Q. Ta, Ehsan Rezvani, Yue Zhang, Mengqi Zeng, Lei Fu, Alicja Bachmatiuk, Jinping Luo, Lijun Liu, Mark H. Rümmeli

Abstract

Abstract Anchored Single-atom catalysts have emerged as a cutting-edge research field holding tremendous appeal for applications in the fields of chemicals, energy and the environment. However, single-atom-catalysts for crystal growth is a nascent field. Of the few studies available, all of them are based on state-of-the-art in situ microscopy investigations and computational studies, and they all look at the growth of monolayer graphene from a single-atom catalyst. Despite the limited number of studies, they do, collectively, represent a new sub-field of single-atom catalysis, namely single-atom catalytic growth of crystalline solids. In this review, we examine them on substrate-supported and as freestanding graphene fabrication, as well as rolled-up graphene, viz., single-walled carbon nanotubes (SWCNT), grown from a single atom. We also briefly discuss the catalytic etching of graphene and SWCNT’s and conclude by outlining the future directions we envision this nascent field to take.
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Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · Nanowire Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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