journal article·2025-09-25

Effects of sequential plasma modification and alkali treatment applied to cellulose fibers on the properties of the paper

Meral Coban Ugurdan, Ayşe Aytac

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Abstract

Abstract This study investigates the effects of plasma treatment, alkaline treatment, and their sequential application on eucalyptus cellulose fibers and laboratory-made paper sheets. Handsheet samples were prepared from eucalyptus cellulose under four different conditions: untreated (control), plasma-treated, alkaline-treated, and plasma-treated followed by alkaline treatment. The untreated eucalyptus cellulose handsheets served as the control group. Plasma treatment was performed in air under a vacuum of 89.2 kPa using a 100 kHz radio frequency at a flow rate of 0.6 L/min. The samples were exposed to 200 W of radio frequency power for 2 min on both sides. Alkaline treatment was applied at concentrations of 1 and 3 wt%. In the sequential treatment, the alkaline solution was applied at the same concentrations following plasma modification on both sides under the same conditions. An increase in plasma intensity and treatment duration resulted in a decrease in dry tensile strength. Overall, the use of modified fibers had a significant impact on the water absorption properties of the handsheets. This study highlights the potential of sequential fiber modification to enhance paper properties and supports the development of more sustainable paper-based products.
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Research context

OpenAlex topics: Advanced Cellulose Research Studies · Material Properties and Processing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Engineering, Engineering Faculty , Kocaeli University , 41380 , Kocaeli , Türkiye

Department of Research & Development, Department of Patent , Hayat Kimya A.S., 41275 , Kocaeli , Türkiye

Polymer Science and Technology Program , Kocaeli University , 41380 , Kocaeli , Türkiye

Funding

Scientific and Technological Research Council of Turkey

References (15)

Show source-provided references
1. An, X., Liu, J., Liu, L., Zhang, H., Nie, S., Cao, H., Xu, Q., and Liu, H. (2020). Improving the flexibility of bamboo mechanical pulp fibers for production of high soft tissue handsheets. Ind. Crops Prod. 150: 112410, https://doi.org/10.1016/j.indcrop.2020.112410.10.1016/j.indcrop.2020.112410 ↗
2. Aydın, M., Tozlu, H., Kemaloglu, S., Aytac, A., and Ozkoc, G. (2011). Effects of alkali treatment on the properties of short flax fiber–poly(lactic acid) eco-composites. J. Polym. Environ. 19: 11–17, https://doi.org/10.1007/s10924-010-0233-9.10.1007/s10924-010-0233-9 ↗
3. Chand, N. and Fahim, M. (2008). Natural fibers and their composites. Tribology of natural fiber polymer composites (1. Baskı). London: CRC Press, 1–55.10.1533/9781845695057.1 ↗
4. Cordeiro, N., Ornelas, M., Ashori, A., Sheshmani, S., and Norouzi, H. (2012). Investigation on the surface properties of chemically modified natural fibers using inverse gas chromatography. Carbohydr. Polym. 87: 2367–2375, ISSN 0144-8617. https://doi.org/10.1016/j.carbpol.2011.11.001.10.1016/j.carbpol.2011.11.001 ↗
5. De Oliveira, D.M., Cioffi, M.O.H., de Carvalho Benini, K.C.C., and Voorwald, H.J.C. (2017). Effects of plasma treatment on the sorption properties of coconut fibers. Procedia Eng. 200: 357–364, https://doi.org/10.1016/j.proeng.2017.07.050.10.1016/j.proeng.2017.07.050 ↗
6. Engin, M. (2022). An examination of the characteristics of cellulosic handsheets treated with glutaraldehyde. Cellul. Chem. Technol. 56: 1049–1059, https://doi.org/10.35812/CelluloseChemTechnol.2022.56.93.10.35812/CelluloseChemTechnol.2022.56.93 ↗
7. Fiore, V., Scalici, T., Nicoletti, F., Vitale, G., Prestipino, M., and Valenza, A. (2016). A new eco-friendly chemical treatment of natural fibres: effect of sodium bicarbonate on properties of sisal fibre and its epoxy composites. Composites, Part B 85: 150–160, https://doi.org/10.1016/j.compositesb.2015.09.028.10.1016/j.compositesb.2015.09.028 ↗
8. Güler, N. (2008). Rejenere selüloz liflerinin yüzey özelliklerinin incelenmesi. Yüksek Lisans Tezi, Uludağ Üniversitesi, Fen Bilimleri Enstitüsü, Bursa, 246483.
9. Jawaid, M., Thariq, M., and Saba, N. (Eds.) (2018). Mechanical and physical testing of biocomposites, fibre-reinforced composites and hybrid composites. Woodhead Publishing, Cambridge.
10. Le Troedec, M., Sedan, D., Peyratout, C., Bonnet, J.P., Smith, A., Guinebretiere, R., Gloaguen, V., and Krausz, P. (2008). Influence of various chemical treatments on the composition and structure of hemp fibres. Composites Part A 39: 514–522, https://doi.org/10.1016/j.compositesa.2007.12.001.10.1016/j.compositesa.2007.12.001 ↗
11. Macedo, M.J., Silva, G.S., Feitor, M.C., Costa, T.H., Ito, E.N., and Melo, J.D. (2020). Surface modification of kapok fibers by cold plasma surface treatment. J. Mater. Res. Technol. 9: 2467–2476, https://doi.org/10.1016/j.jmrt.2019.12.077.10.1016/j.jmrt.2019.12.077 ↗
12. Seki, Y., Sarikanat, M., Sever, K., and Durmuşkahya, C. (2013). Extraction and properties of Ferula communis (chakshir) fibers as novel reinforcement for composites materials. Composites, Part B 44: 517–523, https://doi.org/10.1016/j.compositesb.2012.03.013.10.1016/j.compositesb.2012.03.013 ↗
13. Sun, X.F., Xu, F., Sun, R.C., Fowler, P., and Baird, M.S. (2005). Characteristics of degraded cellulose obtained from steam-exploded wheat straw. Carbohydr. Res. 340: 97–106, https://doi.org/10.1016/j.carres.2004.10.022.10.1016/j.carres.2004.10.022 ↗
14. Teke, A.G., Atik, C., Bertoncelj, J., Poljanšek, I., and Oven, P. (2023). Effects of modified cellulose fiber and nanofibril integration on basic and thermo-mechanical properties of paper. Forests 14: 2150, https://doi.org/10.3390/f14112150.10.3390/f14112150 ↗
15. Vosmanska, V., Kolarova, K., Rimpelova, S., and Svorcik, V. (2014). Surface modification of oxidized cellulose haemostat by argon plasma treatment. Cellulose 21: 2445–2456, https://doi.org/10.1007/s10570-014-0328-x.10.1007/s10570-014-0328-x ↗