journal article·2020-04

Strengthening iron enrichment and dephosphorization of high-phosphorus oolitic hematite using high-temperature pretreatment

Wen-tao Zhou, Yue-xin Han, Yong-sheng Sun, Yan-jun Li

Publisher page

Abstract

The efficient development and utilization of high-phosphorus oolitic hematite is of great strategic significance for the sustainable supply of iron-ore resources in China. In this paper, the mechanism of high-temperature pretreatment for enhancing the effect of iron enrichment and dephosphorization in the magnetization roasting-leaching process was studied by X-ray diffraction (XRD), vibration sample magnetometer (VSM), scanning electron microscopy and energy dispersive spectrometry (SEM-EDS). Compared with the process without high-temperature pretreatment, the iron grade of the magnetic separation concentrate after high-temperature pretreatment had increased by 0.98%, iron recovery rate had increased by 1.33%, and the phosphorus content in the leached residue had decreased by 0.12%. High-temperature pretreatment resulted in the dehydration and decomposition of hydroxyapatite, the dehydration of limonite and the thermal decomposition of siderite, which can produce pores and cracks and weaken the compactness of the ore, improve the magnetization characteristics of roasted ore, and strengthen the iron enrichment and dephosphorization during the magnetization roasting and leaching process.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Iron and Steelmaking Processes · Minerals Flotation and Separation Techniques · Metal Extraction and Bioleaching

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. Y.L. Li, T.C. Sun, A.H. Zou, and C.Y. Xu, Effect of coal levels during direct reduction roasting of high phosphorus oolitic hematite ore in a tunnel kiln, Int. J. Min. Sci. Technol., 22(2012), No. 3, p. 323.10.1016/j.ijmst.2012.04.007 ↗
2. H.Q. Tang, L. Ma, J.W. Wang, and Z.C. Guo, Slag/metal separation process of gas-reduced oolitic high-phosphorus iron ore fines, J. Iron Steel Res. Int., 21(2014), No. 11, p. 1009.10.1016/S1006-706X(14)60176-X ↗
3. Y.S. Sun, Y.F. Li, Y.X. Han, and Y.J. Li, Migration behaviors and kinetics of phosphorus during coal-based reduction of high-phosphorus oolitic iron ore, Int. J. Miner. Metall. Mater, 26(2019), No. 8, p. 938.10.1007/s12613-019-1810-0 ↗
4. H.Q. Tang, Y.Q. Qin, T.F. Qi, Z.L. Dong, and Q.G. Xue, Application of wood char in processing oolitic high-phosphorus hematite for phosphorus removal, J. Iron Steel Res. Int., 23(2016), No. 2, p. 109.10.1016/S1006-706X(16)30021-8 ↗
5. W. Yu, Q.Y. Tang, J.A. Chen, and T.C. Sun, Thermodynamic analysis of the carbothermic reduction of a high-phosphorus oolitic iron ore by Factsage, Int. J. Miner. Metall. Mater, 23(2016), No. 10, p. 1126.10.1007/s12613-016-1331-z ↗
6. K. Ionkov, S. Gaydardzhiev, A.C. de Araujo, D. Bastin, and M. Lacoste, Amenability for processing of oolitic iron ore concentrate for phosphorus removal, Miner. Eng., 46–47(2013), p. 119.10.1016/j.mineng.2013.03.028 ↗
7. Y.S. Sun, Y.X. Han, Y.F. Li, and Y.J. Li, Formation and characterization of metallic iron grains in coal-based reduction of oolitic iron ore, Int. J. Miner. Metall. Mater, 24(2017), No. 2, p. 123.10.1007/s12613-017-1386-5 ↗
8. M. Omran, T. Fabritius, A.M. Elmahdy, N.A. Abdel-Khalek, M. ElAref, and A.E.H. Elmanawi, Effect of microwave pre-treatment on the magnetic properties of iron ore and its implications on magnetic separation, Sep. Purif. Technol., 136(2014), p. 223.10.1016/j.seppur.2014.09.011 ↗
9. W. Yu, T.C. Sun, Z.Z. Liu, J. Kou, and C.Y. Xu, Study on the strength of cold-bonded high-phosphorus oolitic hematite-coal composite briquettes, Int. J. Miner. Metall. Mater, 21(2014), No. 5, p. 423.10.1007/s12613-014-0925-6 ↗
10. J.W. Yu, Y.X. Han, Y.J. Li, and P. Gao, Growth behavior of the magnetite phase in the reduction of hematite via a fluidized bed, Int. J. Miner. Metall. Mater, 26(2019), No. 10, p. 1231.10.1007/s12613-019-1868-8 ↗
11. S.P. Suthers, V. Nunna, A. Tripathi, J. Douglas, and S. Hapugoda, Experimental study on the beneficiation of low-grade iron ore fines using hydrocyclone desliming, reduc tion roasting and magnetic separation, Miner. Process. Extr. Metall., 123(2014), No. 4, p. 212.10.1179/1743285514Y.0000000067 ↗
12. N.A. Yunus, M.H. Ani, H.M. Salleh, R.Z.A. Rashid, T. Akiyama, H. Purwanto, and N.E.F. Othman, Effect of reduction roasting by using bio-char derived from empty fruit bunch on the magnetic properties of Malaysian iron ore, Int. J. Miner. Metall. Mater, 21(2014), p. 326.10.1007/s12613-014-0912-y ↗
13. S.S. Rath, H. Sahoo, and B. Das, Optimization of flotation variables for the recovery of hematite particles from BHQ ore, Int. J. Miner. Metall. Mater, 20(2013), No. 7, p. 605.10.1007/s12613-013-0773-9 ↗
14. C.C. Yang, D.Q. Zhu, J. Pan, and Y. Shi, Some basic properties of granules from ore blends consisting of ultrafine magnetite and hematite ores, Int. J. Miner. Metall. Mater., 26(2019), No. 8, p. 953.10.1007/s12613-019-1824-7 ↗
15. Y.F. Fu, W.Z. Yin, B. Yang, C. Li, Z.L. Zhu, and D. Li, Effect of sodium alginate on reverse flotation of hematite and its mechanism, Int. J. Miner. Metall. Mater., 25(2018), No. 10, p. 1113.10.1007/s12613-018-1662-z ↗
16. S. Yuan, W.T. Zhou, Y.X. Han, and Y.J. Li, Efficient enrichment of low-grade refractory rhodochrosite by precon-centration-neutral suspension roasting-magnetic separation process, Powder Technol., 361(2020), p. 529.10.1016/j.powtec.2019.11.082 ↗
17. Y.J. Li, R. Wang, Y.X. Han, and X.C. Wei, Phase transformation in suspension roasting of oolitic hematite ore, J. Cent. South Univ., 22(2015), No. 12, p. 4560.10.1007/s11771-015-3006-8 ↗
18. G. Lin, L.B. Zhang, J.H. Peng, T. Hu, and L. Yang, Microwave roasting of siderite and the catalytic combustion effects on anthracite, Appl. Therm.Eng., 117(2017), p. 668.10.1016/j.applthermaleng.2017.02.083 ↗
19. D.W. Yang, T.C. Sun, H.F. Yang, C.Y. Xu, C.Y. Qi, and Z.X. Li, Dephosphorization mechanism in a roasting process for direct reduction of high-phosphorus oolitic hematite in west Hubei Province, China, J. Univ. Sci. Technol. Beijing, 32(2010), No. 8, p. 968.
20. J.C. Wang, S.B. Shen, J.H. Kang, H.X. Li, and Z.C. Guo, Effect of ore solid concentration on the bioleaching of phosphorus from high-phosphorus iron ores using indigenous sulfur-oxidizing bacteria from municipal wastewater, Process Biochem., 45(2010), No. 10, p. 1624.10.1016/j.procbio.2010.06.013 ↗
21. Y.L. Zhang, H.M. Li, and X.J. Yu, Recovery of iron from cyanide tailings with reduction roasting-water leaching followed by magnetic separation, J. Hazard. Mater., 213–214(2012), p. 167.10.1016/j.jhazmat.2012.01.076 ↗
22. V.P. Ponomar, N.O. Dudchenko, and A.B. Brik, Synthesis of magnetite powder from the mixture consisting of siderite and hematite iron ores, Miner. Eng., 122(2018), p. 277.10.1016/j.mineng.2018.04.018 ↗
23. V.P. Ponomar, Thermomagnetic properties of the goethite transformation during high-temperature treatment, Miner. Eng., 127(2018), p. 143.10.1016/j.mineng.2018.08.016 ↗
24. Z. Cui, Q. Liu, and T.H. Etsell, Magnetic properties of ilmenite, hematite and oilsand minerals after roasting, Miner. Eng., 15(2002), No. 12, p. 1121.10.1016/S0892-6875(02)00260-1 ↗