journal article·2012-06

Top slag refining for inclusion composition transform control in tire cord steel

Shu-hao Chen, Min Jiang, Xiao-fei He, Xin-hua Wang

Publisher page

Abstract

Controlling conditions for inclusion plasticization were calculated by FactSage, and the steel/slag reaction equilibration time was determined by pre-equilibrium experiments. Laboratory experiments with different top slags were carried out in 90 min, and industrial tests were performed based on the results of calculation and laboratory experiments. Scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) were used to determine the morphology and composition of inclusions in tire cord steel. It is found that the shape of inclusions can be controlled well, and the composition of inclusions varies in the industrial test as the following transformation route: MnO-Al2O3-SiO2→CaO-Al2O3-SiO2→MnO-Al2O3-SiO2. Inclusion plasticization can be achieved by controlling the binary basicity of top slag (CaO/SiO2 by mass) around 1.0 and the (Al2O3) content in top slag below 10wt%. Under these controlling conditions in the industrial test, almost all of inclusions in the wire rods achieve plastic deformation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Microstructure and Mechanical Properties of Steels · Iron and Steelmaking Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (19)

Show source-provided references
1. T. Minamida, N. Hiraga, and T. Shibata, Developments in steel cord wire rods, R&D Kobe Steel Eng. Rep., 50(2000), No.3, p.31.
2. Y. Ujiie and H. Kimura, Production technology for steel bars and wire rods, Nippon Steel Tech. Rep., 80(1999), p.1.
3. M. Kimura, Kobe Steel’s recent advancements in steel wire rod and bar products, R&D Kobe Steel Eng. Rep., 56(2006), No.3, p.1.
4. H. Tashiro, T. Tarui, S. Sasaki, A. Yoshie, S. Nishida, S. Ohashi, K. Nakamura, and H. Demachi, Ultra high tensile strength steel cord, Nippon Steel Tech. Rep., 80(1999), p.38.
5. Z.Z. Liu and K.K. Cai, Purity steel production technology, Iron Steel, 35(2000), No.2, p.64.
6. S.H. Zhang, Alloy Steel (in Chinese), Metallurgical Industry Press, Beijing, 1981, p.136.
7. C. Gatellier, H. Gaye, J. Lehman, J. Bellot, and M. Moncel, Inclusions control in low aluminium steels, Rev. Metall. Cah. Inf. Tech., 89(1992), No.4, p.361.
8. G. Bernard, P.V. Ribound and G. Urbain, Investigation of the plasticity of oxide inclusions, Rev. Metall. Cah. Inf. Tech., 78(1981), No.5, p.421.
9. L.F. Wang, J.M. Zhang, X.H. Wang and W.J. Wang, Experimental research of composition control of CaO-SiO2-Al2O3-MgO inclusion by using low basic top slag for tire cord steel, J. Univ. Sci. Technol. Beijing (in Chinese), 26(2004), No.1, p.26.
10. H. Suito and R. Inoue, Thermodynamics on control of inclusions composition in ultra-clean steels, ISIJ Int., 36(1996), No.5, p.528.10.2355/isijinternational.36.528 ↗
11. S. Kimura, T. Mimura, I. Hoshikawa, N. Ibaraki, and T. Chouda, Control techniques to reduce inclusions during the manufacture of steel for tire cords, R&D Kobe Steel Eng. Rep., 54(2004), No.3, p.25.
12. L.F. Wang, J.M. Zhang, X.H. Wang, and Q.F. Jin, Composition control of CaO-SiO-Al2O3-MgO inclusion by using low basic slag for tire cord steel in laboratory, J. Univ. Sci. Technol. Beijing (in Chinese), 25(2003), No.6, p.528.
13. S.W. Cho and H. Suito, Assessment of aluminum-oxygen equilibrium in liquid iron and activities in CaO-Al2O3-SiO2 slags, ISIJ Int., 34(1994), No.2, p.177.10.2355/isijinternational.34.177 ↗
14. G.K. Sigworth and J.F. Elliott, Thermodynamics of liquid dilute iron alloys, Met. Sci. J., 8(1974), No.9, p.298.10.1179/msc.1974.8.1.298 ↗
15. H. Ohta and H. Suito, Activities in MnO-SiO2-Al2O3 slags and deoxidation equilibria of Mn and Si, Metall. Mater. Trans. B, 27(1996), No.2, p.263.10.1007/BF02915052 ↗
16. J.X. Chen, Common Charts and Data Book for Steel Making, Metallurgical Industry Press, Beijing, 1984, p.548.
17. C.H.P. Lupis, Chemical Thermodynamics of Materials, North-Holland, New York, 1983, p.289.
18. M. Jiang, X.H. Wang, B. Chen, and W.J. Wang, Laboratory study on evolution mechanisms of non-metallic inclusions in high strength alloyed steel refined by high basicity slag, ISIJ Int., 50(2010), No.1, p.95.10.2355/isijinternational.50.95 ↗
19. M. Jiang, X.H. Wang, B. Chen, and W.J. Wang, Formation of MgO-Al2O3 inclusions in high strength alloyed structural steel refined by CaO-SiO2-Al2O3-MgO slag, ISIJ Int., 48(2008), No.7, p.885.10.2355/isijinternational.48.885 ↗