A review of polymer-derived carbon molecular sieve membranes for gas separation
Source abstract
Abstract
Membrane technology for gas separation and purification has unique economic and environmental advantages over conventional purification processes. Carbon molecular sieve membranes (CMSMs) have a higher gas permeability, selectivity, chemical resistance, and better thermal stability than polymer membranes, and have therefore received more attention. CMSMs are commonly fabricated by the pyrolysis of polymer precursors such as polyimides, resins, cellulose and polyetherimide. The reported fabrication process and gas separation performance of CMSMs made from various precursors are summarized and discussed. Both the chemical and physical structures of the precursor membranes affect the carbon structures and gas separation performances of the resulting CMSMs. Overall, the gas separation performance of CMSMs has been significantly improved in the last 20 years, and their possible commercial use is not far away. An in-depth understanding of this progress on CMSMs should provide researchers from different fields an understanding of how to promote their fabrication and applications.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Membrane Separation and Gas Transport · Graphene research and applications · Membrane Separation Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Formation and Modification of Polymeric Membranes: Overview[M]
2. Mechanism of permeation through molecular-sieve carbon membranev[J]10.1039/f19868202057 ↗
3. Study of molecular sieve carbons: the langmuir modelin ultramicroporous adsorbents[J]10.1016/0021-9797(82)90268-5 ↗
4. Study of molecular sieve carbons part 1.-pore structure, gradual pore opening and mechanism of molecular sieving[J]10.1039/f19807602457 ↗
5. New insights into structural evolution in carbon molecular sieve membranes during pyrolysis[J]10.1016/j.carbon.2018.09.039 ↗
6. Recent advances in the development of supported carbon membranes for gas separation[J]10.1016/j.ijhydene.2017.08.071 ↗
7. Effect of polymer precursors on carbon molecular sieve structure and separation performance properties[J]10.1016/j.carbon.2010.08.002 ↗
8. Carbon molecular sieve dense film membranes derived from Matrimid® for ethylene/ethane separation[J]10.1016/j.carbon.2011.11.019 ↗
9. Effect of pyrolysis atmosphere on separation performance of carbon molecular sieve membranes[J]10.1016/j.memsci.2009.10.019 ↗
10. Disk supported carbon membrane via spray coating method: Effect of carbonization temperature and atmosphere[J]10.1016/j.seppur.2017.12.032 ↗
11. Impact of stabilization environment and heating rates on P84 co-polyimide/nanocrystaline cellulose carbon membrane for hydrogen enrichment[J]10.1016/j.ijhydene.2018.06.039 ↗
12. 6FDA-DETDA: DABE polyimide-derived carbon molecular sieve hollow fiber membranes: Circumventing unusual aging phenomena[J]10.1016/j.memsci.2017.10.020 ↗
13. Pyrolysis end-doping to optimize transport properties of carbon molecular sieve hHollow fiber membranes[J]10.1021/acs.iecr.0c02479 ↗
14. Effect of stabilization temperature on gas permeation properties of carbon hollow fiber membrane[J]10.1002/app.37621 ↗
15. Molecular sieving effect of carbonized kapton polyimide membrane[J]10.1039/c39950001179 ↗
16. Carbon molecular sieve gas separation membranes-I. Preparation and characterization based on polyimide precursors[J]10.1016/0008-6223(94)90135-X ↗
17. Highly permeable polyimide membranes with a structural pyrene containing tert-butyl groups: Synthesis, characterization and gas transport[J]10.1016/j.memsci.2018.05.054 ↗
18. Construction of semi-fluorinated polyimides with perfluorocyclobutyl aryl ether-based side chains[J]10.1039/C8PY00004B ↗
19. Experimental study on physical properties and pervaporation performances of polyimide membranes[J]10.1016/j.ces.2007.01.019 ↗
20. Carbon molecular sieve membrane with tunable microstructure for CO2 separation: Effect of multiscale structures of polyimide precursors[J]
21. Effects on carbon molecular sieve membrane properties for a precursor polyimide with simultaneous flatness and contortion in the repeat unit[J]10.1002/cssc.202001572 ↗
22. Isomer-tailored carbon molecular sieve membranes with high gas separation performance[J]10.1002/cssc.202001567 ↗
23. Relationship between chemical structure of aromatic polyimides and gas permeation properties of their carbon molecular sieve membranes[J]10.1016/j.memsci.2003.10.023 ↗
24. Carbon molecular sieve membranes derived from troger's base-based microporous polyimide for gas separation[J]10.1002/cssc.201702243 ↗
25. The gas separation performance adjustment of carbon molecular sieve membrane depending on the chain rigidity and free volume characteristic of the polymeric precursor[J]10.1016/j.carbon.2018.11.037 ↗
26. Effects of brominating matrimid polyimide on the physical and gas transport properties of derived carbon membranes[J]10.1021/ma051354j ↗
27. Carbon molecular sieve membrane structure–property relationships for four novel 6FDA based polyimide precursors[J]10.1016/j.memsci.2015.03.079 ↗
28. Gas separation performance of carbon molecular sieve membranes based on 6FDA-mPDA/DABA (3: 2) polyimide[J]10.1002/cssc.201300851 ↗
29. Gas separation performance of 6FDA-based polyimides with different chemical structures[J]10.1016/j.polymer.2013.09.007 ↗
30. Carbon molecular sieve membranes derived from crosslinkable polyimides for CO2/CH4 and C2H4/C2H6 separations[J]
31. Fabrication and characterization of aging resistant carbon molecular sieve membranes for C3 separation using high molecular weight crosslinkable polyimide, 6FDA-DABA[J]10.1016/j.memsci.2019.03.065 ↗
32. Structure evolution in carbon molecular sieve membranes derived from binaphthol-6FDA polyimide and their gas separation performance[J]10.1016/j.jiec.2020.11.024 ↗
33. Mixed-matrix carbon molecular sieve membranes using hierarchical zeolite: A simple approach towards high CO2 permeability enhancements[J]10.1016/j.memsci.2019.117220 ↗
34. Structure and properties relationships for aromatic polyimides and their derived carbon membranes: Experimental and simulation approaches[J]10.1021/jp050177l ↗
35. Incorporation of thermally labile additives in polyimide carbon membrane for hydrogen separation[J]10.1016/j.ijhydene.2020.10.218 ↗
36. The phase structural evolution and gas separation performances of cellulose acetate/polyimide composite membrane from polymer to carbon stage[J]10.3390/membranes11080618 ↗
37. Fluorine-containing polyimide/polysilsesquioxane carbon molecular sieve membranes and techno-economic evaluation thereof for C3H6/C3H8 separation[J]10.1016/j.memsci.2019.117660 ↗
38. High performance carbon molecular sieving membranes derived from pyrolysis of metal-organic framework ZIF-108 doped polyimide matrices[J]10.1039/C6CC07833H ↗
39. Effect of polydispersity on the phase behavior of polymer blends[J]10.1002/marc.200400574 ↗
40. Mesoporous carbon membranes from polyimide blended with poly(ethylene glycol)[J]10.1002/1097-4628(20010131)79:5<836::AID-APP80>3.0.CO;2-1 ↗
41. Rigid double-stranded siloxane-induced high-flux carbon molecular sieve hollow fiber membranes for CO2/CH4 separation[J]10.1016/j.memsci.2018.10.076 ↗
42. Adjustable microstructure carbon molecular sieve membranes derived from thermally stable polyetherimide/polyimide blends for gas separation[J]10.1016/j.carbon.2016.11.026 ↗
43. Enhancing the properties and gas separation performance of PBI–polyimides blend carbon molecular sieve membranes via optimization of the pyrolysis process[J]10.1016/j.seppur.2013.11.021 ↗
44. High-performance porous carbon-zeolite mixed-matrix membranes for CO2/N2 separation[J]
45. Investigation of the attapulgite hybrid carbon molecular sieving membranes for permanent gas separation[J]10.1016/j.cherd.2019.09.011 ↗
46. Iron-containing carbon molecular sieve membranes for advanced olefin/paraffin separations[J]10.1016/j.memsci.2017.11.052 ↗
47. Carbon molecular sieve membranes derived from metal-substituted sulfonated polyimide and their gas separation properties[J]10.1016/j.memsci.2003.08.017 ↗
48. Preparation and characterisation of gas selective microporous carbon membranes[J]10.1016/j.micromeso.2006.07.041 ↗
49. Preparation of carbon molecular sieve membrane derived from phenolic resin over macroporous clay-alumina based support for hydrogen separation[J]10.1007/s10934-016-0226-8 ↗
50. Effects of phenolic resin pyrolysis conditions on carbon membrane performance for gas separation[J]10.1016/j.memsci.2003.09.010 ↗
51. Separation of hydrocarbon gas mixtures using phenolic resin-based carbon membranes[J]10.1016/S1383-5866(02)00006-0 ↗
52. Effect of air oxidation on gas separation properties of adsorption-selective carbon membranes[J]10.1016/S0008-6223(00)00168-8 ↗
53. Supported carbon molecular sieve membranes based on a phenolic resin[J]10.1016/S0376-7388(99)00083-6 ↗
54. Carbon molecular sieve membranes derived from a phenolic resin supported on porous ceramic tubes[J]10.1016/S1383-5866(01)00065-X ↗
55. Gas separation of pyrolyzed polymeric membranes: Effect of polymer precursor and pyrolysis conditions[J]10.1007/BF03218832 ↗
56. Preparation and gas permeation properties of carbon molecular sieve membranes based on sulfonated phenolic resin[J]10.1016/S0376-7388(03)00074-7 ↗
57. Carbon molecular sieve membranes derived from phenolic resin with a pendant sulfonic acid group[J]10.1021/ie010402v ↗
58. Composite-alumina-carbon molecular sieve membranes prepared from novolac resin and boehmite. Part I: Preparation, characterization and gas permeation studies[J]10.1016/j.ijhydene.2015.02.112 ↗
59. Boehmite-phenolic resin carbon molecular sieve membranes—Permeation and adsorption studies[J]10.1016/j.cherd.2013.12.028 ↗
60. Composite phenolic resin-based carbon molecular sieve membranes for gas separation[J]10.1016/j.carbon.2011.06.012 ↗
61. Carbon–Al2O3–Ag composite molecular sieve membranes for gas separation[J]10.1016/j.cherd.2012.05.016 ↗
62. Preparation and gas permeation of nano-sized zeolite NaA-filled carbon membranes[J]10.1016/j.seppur.2008.07.009 ↗
63. Novel preparation of NaA/carbon nanocomposite thin films with high permeance for CO2/CH4 separation[J]10.1016/j.cclet.2007.01.039 ↗
64. Carbon molecular sieve membranes on porous composite tubular supports for high performance gas separations[J]10.1016/j.micromeso.2015.12.054 ↗
65. Infiltrated glassy carbon membranes in γ-Al2O3 supports[J]10.1016/j.memsci.2006.04.020 ↗
66. Novel modification of a macroporous stainless steel tube by electroless Ni plating for use as a substrate for preparation of nanoporous carbon membranes[J]10.1021/ie202953n ↗
67. Evolution of ultramicroporous adsorptive structure in poly(furfury1 alcohol) -derived carbogenic molecular sieves[J]10.1021/ie00027a018 ↗
68. Experiments and simulation of transport and separation of gas mixtures in carbon molecular sieve membranes[J]10.1021/jp982075j ↗
69. Metal-supported carbogenic molecular sieve membranes: Synthesis and applications[J]10.1021/ie960769d ↗
70. Spray-coating of nanoporous carbon membranes for air separation[J]10.1016/S0376-7388(99)00173-8 ↗
71. Synthesis and characterization of catalytic nanoporous carbon membranes[J]10.1002/aic.690470110 ↗
72. On the preparation of supported nanoporous carbon membranes[J]10.1016/S0376-7388(00)00513-5 ↗
73. Ultrasonic deposition of high-selectivity nanoporous carbon membranes[J]10.1126/science.285.5435.1902 ↗
74. Preparation of supported carbon membranes from furfuryl alcohol by vapor deposition polymerization[J]10.1016/S0376-7388(00)00444-0 ↗
75. Carbon nanotube networks as nanoscaffolds for fabricating ultrathin carbon molecular sieve membranes[J]10.1021/acsami.8b04481 ↗
76. Gas separation performance of C/CMS membranes derived from poly(furfuryl alcohol) (PFA) with different chemical structure[J]10.1016/j.memsci.2010.06.018 ↗
77. Decoration of porous ceramic substrate with pencil for enhanced gas separation performance of carbon membrane[J]10.1016/j.carbon.2014.12.003 ↗
78. Zeolite L/carbon nanocomposite membranes on the porous alumina tubes and their gas separation properties[J]10.1016/j.memsci.2009.10.055 ↗
79. Modification of macroporous stainless steel supports with silica nanoparticles for size selective carbon membranes with improved flux[J]10.1016/j.carbon.2006.01.009 ↗
80. Preparation and gas separation properties of poly(furfuryl alcohol)-based C/CMS composite membranes[J]10.1016/j.seppur.2007.05.019 ↗
81. Preparation of C/CMS composite membranes derived from Poly(furfuryl alcohol) polymerized by iodine catalyst[J]10.1016/j.desal.2009.04.006 ↗
82. Thin zeolite T/carbon composite membranes supported on the porous alumina tubes for CO2 separation[J]10.1016/j.ijggc.2013.01.032 ↗
83. Effect of pyrolysis temperature and operating temperature on the performance of nanoporous carbon membranes[J]10.1016/j.memsci.2008.04.064 ↗
84. Intermediate gel coating on macroporous Al2O3 substrate for fabrication of thin carbon membranes[J]10.1016/j.ceramint.2014.03.010 ↗
85. Preparation and gas separation of nano-sized nickel particle-filled carbon membranes[J]10.1016/j.memsci.2006.04.011 ↗
86. Carbon membranes from cellulose and metal loaded cellulose[J]10.1016/j.carbon.2005.05.018 ↗
87. Carbon molecular sieve membranes for hydrogen purification from a steam methane reforming process[J]10.1016/j.memsci.2021.119241 ↗
88. Preparation of carbon molecular sieve membranes with remarkable CO2/CH4 selectivity for high-pressure natural gas sweetening[J]10.1016/j.memsci.2020.118529 ↗
89. Preparation of carbon molecular sieve membranes from an optimized ionic liquid-regenerated cellulose precursor[J]10.1016/j.memsci.2018.11.027 ↗
90. Preparation of a platinum and palladium/polyimide nanocomposite film as a precursor of metal-doped carbon molecular sieve membrane via supercritical impregnation[J]10.1021/cm0349250 ↗
91. Functionalized carbon molecular sieve membranes containing Ag-nanoclusters[J]10.1016/S0376-7388(03)00176-5 ↗
92. Production of bioactive cellulose films reconstituted from ionic liquids[J]10.1021/bm049748q ↗
93. Study on the interaction between urea and cellulose by combining solid-state 13C CP/MAS NMR and extended Hückel charges[J]10.1007/s10570-014-0461-6 ↗
94. Carbon hollow fiber membranes for a molecular sieve with precise-cutoff ultramicropores for superior hydrogen separation[J]10.1038/s41467-020-20628-9 ↗
95. Screening cellulose spinning parameters for fabrication of novel carbon hollow fiber membranes for gas separation[J]10.1021/acs.iecr.9b02480 ↗
96. Cellulose-based carbon hollow fiber membranes for high-pressure mixed gas separations of CO2/CH4 and CO2/N2[J]10.1016/j.seppur.2020.117473 ↗
97. Carbon membranes for oxygen enriched air – Part I: Synthesis, performance and preventive regeneration[J]10.1016/j.seppur.2018.05.014 ↗
98. Hydrogen separation performance of CMS membranes derived from the imide-functional group of two similar types of precursors[J]10.1016/j.ijhydene.2011.03.146 ↗
99. Influence of support structure on the permeation behavior of polyetherimide-derived carbon molecular sieve composite membrane[J]10.1016/j.memsci.2012.03.014 ↗
100. Enhanced H2/CH4 and H2/CO2 separation by carbon molecular sieve membrane coated on titania modified alumina support: Effects of TiO2 intermediate layer preparation variables on interfacial adhesion[J]10.1016/j.memsci.2016.02.036 ↗