journal article·2025-06

High specific-energy lithium-rich manganese-based layered oxide cathodes: key challenges, modification strategies and future prospects

Yuning Han, Gong-rui Wang, Xuan-xuan Ren, Ming-zhe Yang, Zhong-tao Li, Zhong-shuai Wu

New Carbon Materials· Volume 40· Issue 3
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advancements in Battery Materials · Extraction and Separation Processes · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Charge transfer band gap as an indicator of hysteresis in Li-disordered rock salt cathodes for Li-ion batteries[J]10.1021/jacs.8b11413 ↗
2. Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries[J]10.1038/s41560-018-0097-0 ↗
3. Synthesis, structure, and electrochemical behavior of Li[NixLi1/3−2x/3Mn2/3−x/3]O2[J]10.1149/1.1471541 ↗
4. Spinel electrodes from the Li-MnO system for rechargeable lithium battery applications[J]10.1149/1.2069222 ↗
5. Layered cathode materials Li[NixLi(1/3− 2x/3) Mn(2/3− x/3)]O2 for lithium-ion batteries[J]10.1149/1.1407994 ↗
6. Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O2[J]10.1021/ja062027+ ↗
7. Mechanism of electrochemical activity in Li2MnO3[J]10.1021/cm030047u ↗
8. Electrochemistry Beyond Mn4+ in LixMn1−yLiyO2[J]10.1149/1.1625591 ↗
9. Li2MnO3-stabilized LiMO2 (M= Mn, Ni, Co) electrodes for lithium-ion batteries[J]10.1039/b702425h ↗
10. AlF3-coated Li(Li0.17Ni0.25Mn0.58)O2 as cathode material for Li-ion batteries[J]10.1016/j.electacta.2012.05.142 ↗
11. Reversible anionic redox chemistry in high-capacity layered-oxide electrodes[J]10.1038/nmat3699 ↗
12. Understanding the effect of an in situ generated and integrated spinel phase on a layered Li-rich cathode material using a non-stoichiometric strategy[J]10.1039/C6CP03683J ↗
13. Oxygen release and its effect on the cycling stability of LiNiMnyCozO2 (NMC) cathode materials for Li-ion batteries[J]10.1149/2.0021707jes ↗
14. All-solid-state lithium metal batteries with sulfide electrolytes: Understanding interfacial ion and electron transport[J]10.1021/accountsmr.1c00137 ↗
15. Al-doping driven suppression of capacity and voltage fadings in 4D-element containing Li-ion-battery cathode materials: machine learning and density functional theory[J]10.1002/aenm.202201497 ↗
16. Data-driven insights into the reaction mechanism of Li-rich cathodes[J]10.1039/D4EE05222F ↗
17. Direct atomic-resolution observation of two phases in the Li1.2Mn0.567Ni0.166Co0.067O2 cathode material for lithium-ion batteries[J]10.1002/anie.201301236 ↗
18. Synthesis of solid solutions in a system of LiCoO2-Li2MnO3 for cathode materials of secondary lithium batteries[J]10.1246/cl.1997.725 ↗
19. Lack of cation clustering in Li[NixLi1/3-2x/3Mn2/3-x/3]O2 (0<x<1/2) and Li[CrxLi(1-x)/3Mn(2-2x)/3]O2 (0<x<1)[J]10.1021/cm030194s ↗
20. High capacity Li-rich positive electrode materials with reduced first-cycle irreversible capacity loss[J]10.1021/cm504583y ↗
21. Li1.20Mn0.54Co0.13Ni0.13O2 with different particle sizes as attractive positive electrode materials for lithium-ion batteries: Insights into their structure[J]10.1021/jp301879x ↗
22. Insight into the atomic structure of cycled lithium-rich layered oxide Li1.20Mn0.54Co0.13Ni0.13O2 using HAADF-STEM and electron nano-diffraction[J]10.1021/jp509388j ↗
23. Atomic structure of a Lithium-rich layered oxide material for lithium-ion batteries: Evidence of a solid solution[J]10.1021/cm200831c ↗
24. Evolutions of Li1.2Mn0.61Ni0.18Mg0.01O2 during the initial charge/dischargecycle studied by advanced electron microscopy[J]10.1021/cm301140g ↗
25. High-capacity lithium insertion materials of lithium nickel manganese oxides for advanced lithium-ion batteries: Toward rechargeable capacity more than 300 mAh g–1[J]10.1039/c0jm04325g ↗
26. Direct atomic-resolution observation of two phases in the Li1.2Mn0.567Ni0.166Co0.067O2 cathode material for lithium-ion batteries[J]10.1002/anie.201301236 ↗
27. Linking structure to performance of Li1.2Mn0.54Ni0.13Co0.13O2 (Li- and Mn-rich NMC) cathode materials synthesized by different methods[J]10.1039/D0CP00400F ↗
28. Neutron diffraction and magnetic susceptibility studies on a high-voltage Li1.2Mn0.55Ni0.15Co0.10O2 lithium-ion battery cathode: Insight into the crystal structure[J]10.1021/cm402278q ↗
29. Recent developments and challenges of Li-rich Mn-based cathode materials for high-energy lithium-ion batteries[J]10.1016/j.mtener.2020.100518 ↗
30. Lack of cation clustering in Li[NixLi1/3-2xMn2/3-x]O2 (0<x<1/2) and Li[CrxLi(1-xMn(2-2x]O2 (0<x<1)[J]10.1021/cm030194s ↗
31. Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M= Mn, Ni, Co) for lithium batteries[J]10.1016/j.elecom.2006.06.030 ↗
32. A review of high-capacity lithium-rich manganese-based cathode materials for a new generation of lithium batteries[J]
33. Direct in situ observation of Li2O evolution on Li-rich high-capacity cathode material, Li[NixLi(1-2xMn(2-x]O2 (0≤x≤0.5)[J]10.1021/ja410137s ↗
34. Reaction mechanisms of layered lithium-rich cathode materials for high-energy lithium-ion batteries[J]10.1002/anie.202000262 ↗
35. The structural and chemical origin of the oxygen redox activity in layered and cationdisordered Li-excess cathode materials[J]10.1038/nchem.2524 ↗
36. Unraveling TM migration mechanisms in LiNi1/3Mn1/3Co1/3O2 by modeling and experimental studies[J]10.1021/acs.nanolett.1c01985 ↗
37. Research progress on interface optimization strategies for solid-state lithium batteries[J]
38. Deformation and stress in electrode materials for Li-ion batteries[J]10.1016/j.pmatsci.2014.02.001 ↗
39. Uncovering the roles of oxygen vacancies in cation migration in lithium excess layered oxides[J]10.1039/C4CP01799D ↗
40. Formation of the spinel phase in the layered composite cathode used in Li-ion batteries[J]10.1021/nn305065u ↗
41. Unraveling the voltage-fade mechanism in high-energy-density lithium-ion batteries: Origin of the tetrahedral cations for spinel conversion[J]10.1021/cm5031415 ↗
42. Formation of an anti-core-shell structure in layered oxide cathodes for Li-ion batteries[J]10.1021/acsenergylett.7b00921 ↗
43. Unraveling the rapid performance decay of layered high-energy cathodes: From nanoscale degradation to drastic bulk evolution[J]10.1021/acsnano.7b08945 ↗
44. Structural and chemical evolution of Li- and Mn-rich layered cathode material[J]10.1021/cm5045978 ↗
45. Mechanisms and applications of layer/spinel phase transition in Li- and Mn-rich cathodes for lithium-ion batteries[J]10.1007/s12598-021-01896-w ↗
46. A review on progress of lithium-rich manganese-based cathodes for lithium-ion batteries[J]10.1016/j.jpowsour.2020.229362 ↗
47. Challenges and recent advances in high capacity Li-rich cathode materials for high energy density lithium-ion batteries[J]
48. Persistent and partially mobile oxygen vacancies in Li-rich layered oxides[J]10.1038/s41560-021-00832-7 ↗
49. Speciation of transition metal dissolution in electrolyte from common cathode materials[J]10.1002/anie.202317109 ↗
50. Lithium/oxygen incorporation and microstructural evolution during synthesis of Li-rich layered Li[Li0.2Ni0.2Mn0.6]O2 oxides[J]
51. Interphase engineering by electrolyte additives for lithium-rich layered oxides: advances and perspectives[J]10.1021/acsenergylett.1c00750 ↗
52. Voltage fade of layered oxides: Its measurement and impact on energy density[J]10.1149/2.034311jes ↗
53. Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study[J]10.1039/c1ee01131f ↗
54. Evolution of lattice structure and chemical composition of the surface reconstruction layer in Li1.2Ni0.2Mn0.6O2 cathode material for lithium ion batteries[J]10.1021/nl5038598 ↗
55. Origin of structural degradation in Li-rich layered oxide cathode[J]10.1038/s41586-022-04689-y ↗
56. Dynamic imaging of crystalline defects in lithium-manganese oxide electrodes during electrochemical activation to high voltage[J]
57. Gradient Li-rich oxide cathode particles immunized against oxygen release by a molten salt treatment[J]10.1038/s41560-019-0508-x ↗
58. Metal-oxygen decoordination stabilizes anion redox in Li-rich oxides[J]10.1038/s41563-018-0276-1 ↗
59. Inhibiting oxygen release from Li-rich Mn based layered oxides at the surface with a solution processable oxygen scavenger polymer[J]10.1002/aenm.202100552 ↗
60. A universal strategy toward the precise regulation of initial coulombic efficiency of Li-rich Mn-based cathode materials[J]10.1002/adma.202103173 ↗
61. Selecting substituent elements for LiMnPO4 cathode materials combined with density functional theory (DFT) calculations and experiments[J]
62. Hierarchical Li1.2Ni0.2Mn0.6O2 nanoplates with exposed 010 planes as high-performance cathode material for lithium-ion batteries[J]10.1002/adma.201402541 ↗
63. A new spinel-layered Li-rich microsphere as a high-rate cathode material for Li-ion batteries[J]10.1002/aenm.201400062 ↗
64. Hierarchical Li1.2Ni0.2Mn0.6O2 nanoplates with exposed 010 planes as high-performance cathode material for lithium-ion batteries[J]10.1002/adma.201402541 ↗
65. Optimized temperature effect of Li-ion diffusion with layer distance in Li(NixMnyCoz)O2 cathode materials for high performance Li-ion battery[J]10.1002/aenm.201501309 ↗
66. Synthesis of Ni-rich layered-oxide nanomaterials with enhanced Li-ion diffusion pathways as high-rate cathodes for Li-ion batteries[J]10.1021/acsaem.0c00765 ↗
67. Optimized temperature effect of Li-ion diffusion with layer distance in Li (NixMnyCoz) O2 cathode materials for high performance Li-ion battery[J]10.1002/aenm.201501309 ↗
68. Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode[J]
69. Effect of surface modifications on the layered solid solution cathodes (1-z)Li[Li1/3Mn2/3]O2(z) Li[Mn0.5yNi0.5yCo2y]O2[J]10.1016/j.ssi.2008.11.002 ↗
70. Evolution of lattice structure and chemical composition of the surface reconstruction layer in Li1.2Ni0.2Mn0.6O2 cathode material for lithium-ion batteries[J]10.1021/nl5038598 ↗
71. Highly reversible Li2RuO3 cathodes in sulfide-based all solid-state lithium batteries[J]10.1039/D2EE01067D ↗
72. Ti-based surface integrated layer and bulk doping for stable voltage and long life of Li-Rich layered cathodes[J]10.1002/adfm.202009310 ↗
73. Building homogenous Li2TiO3 coating layer on primary particles to stabilize Li-rich Mn-based cathode materials[J]10.1002/smll.202106337 ↗
74. Zn/Ti dual concentrationgradients surface doping to improve the stability and kinetics for Li-rich layered oxides cathode[J]10.1016/j.cej.2022.138678 ↗
75. Cation and polyanion co-doping synergy to improve electrochemical performances of Li-rich manganese-based cathode materials[J]10.1016/j.jallcom.2022.166527 ↗
76. A gradient doping strategy toward superior electrochemical performance for Li-rich Mn-based cathode materials[J]10.1002/smll.202207797 ↗
77. Surface yttrium-doping induced by element segregation to suppress oxygen release in Li-rich layered oxide cathodes[J]10.1007/s42864-022-00165-2 ↗
78. Cation/anion codoped and cobalt-free Li-rich layered cathode for high-performance Li-ion batteries[J]10.1021/acs.nanolett.1c02923 ↗
79. Enhanced cycling stability in 4. 6 V LiCoO2 for high energy density lithium-ion batteries through Al and Y co-doping[J]10.1016/j.ensm.2024.103459 ↗
80. Electrochemical in situ Na doping to construct high-performance lithium-rich cathode[J]10.1021/acsenergylett.4c00066 ↗
81. Decreasing Li/Ni disorder and improving the electrochemical performances of Ni-rich LiNi0.8Co0.1Mn0.1O2 by Ca doping[J]10.1021/acs.inorgchem.7b01035 ↗
82. Cation ordered Li-rich layered cathode for ultra-long battery life[J]10.1039/D0EE03774E ↗
83. Sn-doped Li1.2Mn0.54Ni0.13Co0.13O2 cathode materials for lithium-ion batteries with enhanced electrochemical performance[J]10.1007/s10008-017-3688-y ↗
84. Yttrium modified Ni-rich LiNi0.8Co0.1Mn0.1O2 with enhanced electrochemical performance as high energy density cathode material at 4.5V high voltage[J]10.1016/j.jallcom.2018.09.281 ↗
85. Synthesis and electrochemical characterizations of nano-scaled Zn doped LiMn2O4 cathode materials for rechargeable lithium batteries[J]10.1016/j.electacta.2010.07.033 ↗
86. Improved stability of Ni-rich cathode by the substitutive cations with stronger bonds[J]10.1016/j.electacta.2018.01.119 ↗
87. Electron-deficient sites on boron-doped graphite enable air-stable and durable red phosphorus anode for lithium-ion batteries[J]10.1039/D4EE00970C ↗
88. Tailoring bulk Li+ diffusion kinetics and surface lattice oxygen activity for high-performance lithium-rich manganese-based layered oxides[J]10.1016/j.ensm.2021.02.025 ↗
89. High-energy W-doped Li[Ni0.95Co0.04Al0.01]O2 cathodes for next-generation electric vehicles[J]10.1016/j.ensm.2020.08.013 ↗
90. Efficient plasma-enhanced method for layered LiNi1/3Co1/3Mn1/3O2 cathodes with sulfur atom-scale modification for superior-performance Li-ion batteries[J]10.1039/C6NR02589G ↗
91. Boosting the electrochemical performance of Li-and Mn-rich cathodes by a three-in-one strategy[J]10.1007/s40820-021-00725-0 ↗
92. A three in one strategy to achieve zirconium doping, boron doping, and interfacial coating for stable LiNi0.8Co0.1Mn0.1O2 cathode[J]10.1002/advs.202001809 ↗
93. Improving the oxygen redox reversibility of Li-rich battery cathode materials via coulombic repulsive interactions strategy[J]
94. Regulation of anion redox activity via solid-acid modification for highly stable Li-rich Mn-based layered cathodes[J]10.1002/adfm.202307583 ↗
95. High performance flexible lithium-ion battery electrodes: Ion exchange assisted fabrication of carbon coated nickel oxide nanosheet arrays on carbon cloth[J]10.1002/adfm.202101199 ↗
96. An in situ near-surface reconstruction strategy endowing lithium-rich oxides with Li/O dual vacancies and spinel-carbon dual coating layers toward high energy density cathode[J]10.1002/adfm.202401249 ↗
97. Superiorhybrid cathode material containing lithium-excess layered material and graphene for lithium-ion batteries[J]10.1021/am301202a ↗
98. Ionic-electronic dual-conductor interface engineering and architecture design in layered lithium-rich manganese-based oxides[J]10.1002/cey2.642 ↗
99. Uniform amorphous MgxByOz coating combined with Vo for highly stable Li-rich Mn-based cathode material[J]10.1016/j.cej.2024.150315 ↗
100. Grafting a polymer coating layer onto Li1.2Ni0.13Co0.13Mn0.54O2 cathode by benzene diazonium salts to facilitate the cycling performance and high-voltage stability[J]10.1002/smll.202305606 ↗