journal article·2011-06

A comparative study of nitrogen-doped hierarchical porous carbon monoliths as electrodes for supercapacitors

Guang-ping HAO, Juan MI, Duo LI, Wen-hui QU, Ting-jun WU, Wen-cui LI, An-hui LU

New Carbon Materials· Volume 26· Issue 3
Publisher page

Abstract

Two nitrogen-doped carbon monoliths with hierarchical porosity over a large size range were prepared by polymerization of resorcinol and formaldehyde in the presence of an organic amine, L-lysine, and an inorganic base, ammonium hydroxide under ambient conditions. Their physical and chemical features were characterized by N2 sorption, transmission and scanning electron microscopy, and elemental analysis. Their electrochemical properties as the electrodes of supercapacitors were evaluated under both a three-electrode system and a two-electrode system. Results show that the two types of nitrogen-doped carbon possess similar pore structures, but have distinct electrochemical performances. The L-lysine incorporated carbon monolith has a high nitrogen content, a high specific capacitance of 199 F·g−1, and a 1.6% loss in the specific capacitance after 1000 charge-discharge cycles, indicating a long-term cycling stability.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Electrocatalysts for Energy Conversion · Electrochemical sensors and biosensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (27)

Show source-provided references
1. Materials for electrochemical capacitors[J]10.1038/nmat2297 ↗
2. Conway · 1999
3. Superior electric double layer capacitors using ordered mesoporous carbons[J]10.1016/j.carbon.2005.07.029 ↗
4. Electrochemical capacitor performance of N-doped mesoporous carbons prepared by ammoxidation[J]10.1016/j.jpowsour.2008.01.055 ↗
5. An activated carbon monolith as an electrode material for supercapacitors[J]10.1016/j.carbon.2008.09.048 ↗
6. Studies and characterisations of various activated carbons used for carbon/carbon supercapacitors[J]10.1016/S0378-7753(01)00707-8 ↗
7. Cresol-formaldehyde based carbon aerogel as electrode material for electrochemical capacitor[J]10.1016/j.jpowsour.2006.06.049 ↗
8. Carbon aerogels derived from cresol-resorcinol-formaldehyde for supercapacitors [J]10.1016/S0008-6223(02)00243-9 ↗
9. Hierarchical porous carbons with controlled micropores and mesopores for supercapacitor electrode materials[J]10.1016/j.carbon.2008.07.018 ↗
10. Structure and electrochemical properties of carbon aerogels synthesized at ambient temperatures as supercapacitors[J]10.1016/j.jnoncrysol.2007.07.024 ↗
11. Hierarchical porous carbons with high performance for supercapacitor electrodes[J]10.1016/j.carbon.2009.02.024 ↗
12. Syntheses of polyaniline/ordered mesoporous carbon composites with interpenetrating framework and their electrochemical capacitive performance in alkaline solution[J]10.1016/j.jpowsour.2010.09.005 ↗
13. Improved capacitance of SBA-15 templated mesoporous carbons after modification with nitric acid oxidation [J]10.1016/S1872-5805(08)60002-5 ↗
14. Design and synthesis of hierarchical nanowire composites for electrochemical energy storage[J]10.1002/adfm.200900971 ↗
15. Textural and electrochemical characterization of porous carbon nanofibers as electrodes for supercapacitors[J]10.1016/j.jpowsour.2007.07.009 ↗
16. Flexible Zn2SnO4/MnO2 core/shell nanocable-carbon microfiber hybrid composites for high-performance supercapacitor electrodes[J]10.1021/nl104205s ↗
17. Anomalous increase in carbon capacitance at pore sizes less than 1 nanometer[J]10.1126/science.1132195 ↗
18. Carbon materials for the electrochemical storage of energy in capacitors[J]10.1016/S0008-6223(00)00183-4 ↗
19. Mesoporous carbon materials as electrodes for electrochemical supercapacitors[J]10.1016/S1452-3981(23)15331-4 ↗
20. Electrochemical performance of nitrogen-enriched carbons in aqueous and non-aqueous supercapacitors[J]10.1021/cm060146i ↗
21. Optimisation of supercapacitors using carbons with controlled nanotexture and nitrogen content[J]10.1016/j.electacta.2005.04.080 ↗
22. Combined effect of nitrogen- and oxygen-containing functional groups of microporous activated carbon on its electrochemical performance in supercapacitors[J]10.1002/adfm.200801236 ↗
23. Nitrogen-enriched nanocarbons with a 3-D continuous mesopore structure from polyacrylonitrile for supercapacitor application[J]10.1021/jp101255d ↗
24. Functionalization of porous carbon materials with designed pore architecture[J]10.1002/adma.200801492 ↗
25. Rapid synthesis of nitrogen-doped porous carbon monolith for CO2 capture[J]10.1002/adma.200903765 ↗
26. A three-dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors[J]10.1002/adma.201001029 ↗
27. Optimisation of supercapacitors using carbons with controlled nanotexture and nitrogen content[J]10.1016/j.electacta.2005.04.080 ↗