journal article·2015-12

Preparation of graphene/metal-organic composites and their adsorption performance for benzene and ethanol

Guo-qiang Liu, Ming-xi Wan, Zheng-hong Huang, Fei-yu Kang

New Carbon Materials· Volume 30· Issue 6
Publisher page

Abstract

Graphene/metal-organic composites were synthesized by a solvothermal method and characterized by nitrogen adsorption, SEM and IR and their adsorption properties for benzene and ethanol were investigated. It was found that the surface area and pore volume both have maximum values for a graphene oxide (GO) percentage of 5.25 wt%. The composites have high adsorption capacities for both benzene and ethanol, and the maximum uptakes reach 72 and 77 cm3/g, respectively. The adsorption capacities of volatile organic compounds are determined by both the pore structure and the surface properties. The maximum ethanol adsorption capacity for the composite with a GO percentage of 3.5 wt% is due to its abundant oxygen-containing functional groups.
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Research context

OpenAlex topics: Graphene research and applications · Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Characterization of carbon cryogel microspheres as adsorbents for VOC[J]10.1016/j.jhazmat.2009.12.036 ↗
2. Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations[J]10.1016/j.carbon.2005.02.023 ↗
3. Adsorption equilibrium of methane and carbon dioxide on porous metal-organic framework Zn-BTB[J]10.1007/s10450-011-9328-4 ↗
4. Adsorption of volatile organic compounds onto carbon nanotubes, carbon nanofibers, and high-surface-area graphites[J]10.1016/j.jcis.2006.09.036 ↗
5. Surface modification of coconut shell based activated carbon for the improvement of hydrophobic VOC removal[J]10.1016/j.jhazmat.2011.05.069 ↗
6. Noble-metal-based catalysts supported on zeolites and macro-mesoporous metal oxide supports for the total oxidation of volatile organic compounds[J]10.1002/cssc.201100282 ↗
7. Reutilization of Cr-Y zeolite obtained by biosorption in the catalytic oxidation of volatile organic compounds[J]10.1016/j.jhazmat.2011.05.056 ↗
8. Adsorption of organic compounds in vapor, liquid, and aqueous solution phases on hydrophobic aerogels[J]10.1021/ie201301n ↗
9. Adsorption of methyl ethyl ketone and trichloroethene from aqueous solutions onto silicalite fixed-bed adsorbers[J]10.1016/j.seppur.2004.06.007 ↗
10. Preparation and application of organo-minerals as sorbents of phenol, benzene and toluene[J]10.1016/S0169-1317(00)00040-5 ↗
11. Adsorption equilibrium and kinetics of p-xylene on chromium-based metal organic framework MIL-101[J]10.1016/j.cej.2011.07.051 ↗
12. Functional porous coordination polymers[J]10.1002/anie.200300610 ↗
13. Ultrahigh Porosity in Metal-Organic Frameworks[J]10.1126/science.1192160 ↗
14. MOF-graphite oxide composites: combining the uniqueness of graphene layers and metal-organic frameworks[J]10.1002/adma.200901581 ↗
15. MOF-graphite oxide nanocomposites: surface characterization and evaluation as adsorbents of ammonia[J]10.1039/b908862h ↗
16. Enhanced adsorption of ammonia on metal-organic framework/graphite oxide composites: Analysis of surface interactions[J]10.1002/adfm.200900880 ↗
17. Reactive adsorption of ammonia on Cu-based MOF/graphene composites[J]10.1021/la1021092 ↗
18. Synthesis, characterization, and ammonia adsorption properties of mesoporous metal-organic framework (MIL(Fe))-graphite oxide composites: exploring the limits of materials fabrication[J]10.1002/adfm.201002517 ↗
19. Toward understanding reactive adsorption of ammonia on Cu-MOF/graphite oxide nanocomposites[J]10.1021/la202924y ↗
20. Hydrogen sulfide adsorption on MOFs and MOF/graphite oxide composites[J]10.1002/cphc.201000689 ↗
21. Reactive adsorption of NO2 on copper-based metal-organic framework and graphite oxide/metal-organic framework composites[J]10.1021/am100790v ↗
22. Metal-organic frameworks with high capacity and selectivity for harmful gases[J]10.1073/pnas.0804900105 ↗
23. Adsorption and separation of xylene isomers and ethylbenzene on two Zn-terephthalate metal-organic frameworks[J]10.1021/jp9063017 ↗
24. Noble-metal-promoted three-dimensional macroassembly of single-layered graphene oxide[J]10.1002/anie.201000270 ↗
25. Glucose-promoted Zn-based metal-organic framework/graphene oxide composites for hydrogen sulfide removal[J]10.1021/am3013104 ↗
26. Rouquerol · 1999 · 18
27. Effect of activation temperature on the textural and chemical properties of potassium hydroxide activated carbon prepared from pistachio-nut shell[J]10.1016/j.jcis.2003.10.001 ↗
28. Alcohol-assisted hydrothermal carbonization to fabricate spheroidal carbons with a tunable shape and aspect ratio[J]10.1016/j.carbon.2009.11.045 ↗
29. Chemical and structural properties of carbonaceous products obtained by hydrothermal carbonization of saccharides[J]10.1002/chem.200802097 ↗
30. Infrared and computational studies of the adsorption of methanol and ethanol on single-walled carbon nanotubes[J]10.1021/jp0763432 ↗
31. Graphite oxides obtained from porous graphite: the role of surface chemistry and texture in ammonia retention at ambient conditions[J]10.1002/adfm.201000061 ↗
32. Self-assembled graphene hydrogel via a one-step hydrothermal process[J]10.1021/nn101187z ↗
33. The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities[J]10.1021/ja0675447 ↗