journal article·2008-04

Compatibilization of hiPP/HDPE blends by a metallocene copolymer

R. Sonnier, V. Massardier, Ph. Cassagnau

Publisher page

Abstract

A high impact polypropylene / high density polyethylene 80/20 blend was compatibilized by incorporating 5wt% of different metallocene random copolymers ethylene-α-olefin (mPE). The comonomer (butene or octene) content is ranged from 8.3 to 19.2 wt%. In some cases, a great improvement of mechanical properties was obtained due to a better interfacial adhesion. For example, elongation at break could increase from 60 to 340%. The comonomer content has a strong effect on these results. On the contrary, viscosity, comonomer type or molecular weight are not influent parameters. The presence of 22wt% of EPR in high impact polypropylene has also a great impact on performances. EPR and metallocene copolymer are miscible.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer crystallization and properties · Polymer Nanocomposites and Properties · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (12)

Show source-provided references
1. L. Utracki, Commercial Polymer Blends, London:Chapman & Hall (1998)10.1007/978-1-4615-5789-0 ↗
2. I.H. Do, L.K. Yoon, B.K. Kim, H.M. Jeong, Effect of viscosity ratio and peroxide coagent treatment in PP/EPR/PE ternary blends, European Polymer Journal, vol. 32 (12), 199610.1016/S0014-3057(96)00106-1 ↗
3. R. Hettema, J. Van Tol, L.P.B.M. Janssen, In-Situ reactive Blending of Polyethylene and Propylene in Co-Rotating and Counter-Rotating Extruders, Polymer Engineering and Science, vol. 39 (9), 199910.1002/pen.11557 ↗
4. R. Sonnier, E. Leroy, A. Bergeret, J.M. Lopez-Cuetsa, Compatibilisation of polyethylene/ground tyre rubber blends by γ irradiation, Polymer Degradation and Stability, vol. 91, 200610.1016/j.polymdegradstab.2006.04.001 ↗
5. A. Colbeaux, F. Fenouillot, J.F. Gerard, M. Taha, H. Wautier, Compatibilization of a Polyolefin Blend through Covalent and Ionic Coupling of Grafted Polypropylene and Polyethylene. I. Rheological, Thermal, and Mechanical Properties, Journal of Applied Polymer Science, vol. 95, 200510.1002/app.21226 ↗
6. T. Kallel, V. Massardier-Nageotte, M. Jaziri, J-F. Gerard, B. Elleuch, Compatibilization of PE/PS abd PE/PP Blends. I. Effect of Processing Conditions and Formulation, Journal of Applied Polymer Science, vol. 90, 200310.1002/app.12873 ↗
7. C.H. Stephens, A. Hiltner, E. Baer, Phase Behavior of Partially Miscible Blends of Linear and Branched Polyethylenes, Macromolecules, vol. 36, 200310.1021/ma021621a ↗
8. G. Gorrasi, R. Pucciariello, V. Villani, V. Vittoria, S. Belviso, Miscibility in Crystalline Polymer Blends: Isotactic Polypropylene and Linear Low-Density Polyethylene, Journal of Applied Polymer Science, vol. 90, 200310.1002/app.13100 ↗
9. J. Li, R.A. Shanks, R.H. Olley, G.R. Greenway, Miscibility and isothermal crystallisation of polypropylene in polyethylene melts, Polymer, vol. 42, 200110.1016/S0032-3861(01)00248-8 ↗
10. M. Kontopoulou, W. Wang, T.G. Gopakumar, C. Cheung, Effect of composition and comonomer type on the rheology, morphology and properties of ethylen-α-olefin copolymer/polypropylene blends, Polymer, vol. 44, 200310.1016/j.polymer.2003.08.043 ↗
11. J. Li, R.A. Shanks, Y. Long, Mechanical Properties and Morphology of Polyethylene-Polypropylene Blends with Controlled Thermal History, Journal of Applied Polymer Science, vol. 76, 200010.1002/(SICI)1097-4628(20000516)76:7<1151::AID-APP19>3.0.CO;2-H ↗
12. D. Mileva, H-J. Radusch, C. Betchev, Study on the Phase Behavior of High Density Polyethylene –Ethylene Octene Copolymer Blends, Macromolecular Materials and Engineering, vol. 292, 200710.1002/mame.200600331 ↗