journal article·2014-10

Synthesis and microstructure analysis of aligned carbon nanotube/pyrocarbon composites

Harshad Patel, L M Manocha, S Manocha

New Carbon Materials· Volume 29· Issue 5
Publisher page

Abstract

A two-step preparation of aligned CNT (ACNT)/pyrolytic carbon composites was carried out with chemical vapor deposition and chemical vapor infiltration by filling the space within the ACNT film with pyrolytic carbon, using methane as carbon precursor. The structure of the composites was investigated by scanning electron microscopy and Raman spectroscopy. Results showed that the CNTs were coated unevenly with densely-packed carbon spheres at 950 °C. At 1050 °C, the CNTs were uniformly coated which increased their diameters from 20-60 nm to 400-500 nm and closed pores were formed as a result of the fast formation and a slow diffusion of carbonaceous nuclei during the latter stages of deposition. At both temperatures, the density of the film increased more than four fold when the pyrolytic carbon was graphitized.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Diamond and Carbon-based Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Large-scale synthesis of aligned carbon nanotubes [J]10.1126/science.274.5293.1701 ↗
2. Growth of vertically aligned single-walled carbon nanotube films on quartz substrates and their optical anisotropy [J]10.1016/j.cplett.2003.12.095 ↗
3. Vertically aligned carbon nanotubes grown by plasma enhanced chemical vapor deposition [J]10.1116/1.1627332 ↗
4. Growth process conditions of vertically aligned carbon nanotubes using plasma enhanced chemical vapor deposition [J]10.1063/1.1410322 ↗
5. Fabrication of vertically aligned carbon nanotubes patterns by chemical vapor deposition for field emitters [J]10.1016/S0925-9635(02)00110-3 ↗
6. Aligned millimeter-long carbon nanotube arrays grown on single crystal magnesia [J]10.1016/j.carbon.2005.10.015 ↗
7. Fabrication and electrical integration of robust carbon nanotube micropillars by self-directed elastocapillary densification [J]10.1088/0960-1317/21/4/045033 ↗
8. Graphene coating makes carbon nanotube aerogels superelastic and resistant to fatigue [J]10.1038/nnano.2012.118 ↗
9. Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes [J]10.1038/nmat1782 ↗
10. Thermal transport measurements of individual multiwalled nanotubes [J]10.1103/PhysRevLett.87.215502 ↗
11. Unusually high thermal conductivity of carbon nanotubes [J]10.1103/PhysRevLett.84.4613 ↗
12. The reinforcement and toughening of pyrocarbon-based carbon/carbon composite by controlling carbon nanotube growth position in carbon felt [J]10.1016/j.msea.2012.11.074 ↗
13. Densification kinetics and matrix microstructure of carbon fiber/carbon nanofiber/pyrocarbon composites prepared by electrophoresis and thermal gradient chemical vapor infiltration [J]10.1016/j.carbon.2010.09.011 ↗
14. Effect of in situ grown carbon nanotubes on the structure and mechanical properties of unidirectional carbon/carbon composites [J]10.1016/j.msea.2010.11.067 ↗
15. Synthesis and characterization of in situ grown carbon nanofiber/nanotube reinforced carbon/carbon composites [J]10.1016/j.carbon.2005.04.024 ↗
16. The effect of carbon nanotube growing on carbon fibers on the microstructure of the pyrolytic carbon and the thermal conductivity of carbon/carbon composites [J]10.1016/j.matchemphys.2009.02.044 ↗
17. Densified aligned carbon nanotube films via vapor phase infiltration of carbon [J]10.1016/j.carbon.2006.11.010 ↗
18. Multi-walled carbon nanotube-based carbon/carbon composites with three-dimensional network structures [J]10.1039/c3nr01069d ↗
19. Chemical vapor deposition of pyrolytic carbon on carbon nanotubes: Part 1. Synthesis and morphology [J]10.1016/S0008-6223(03)00329-4 ↗
20. Thermal properties of aligned carbon nanotube/carbon nanocomposites [J]10.1016/j.msea.2004.06.006 ↗
21. Enhanced thermal conductivity of carbon nanotube arrays by carbonizing impregnated phenolic resins [J]10.4236/msa.2013.48055 ↗
22. Development of carbon/carbon composites with carbon nanotubes as reinforcement and CVI carbon as matrix [J]
23. Raman spectroscopy of carbon nanotubes [J]10.1016/j.physrep.2004.10.006 ↗
24. Raman spectrum of graphite [J]10.1063/1.1674108 ↗
25. Microstructures of isotropic pyrolytic carbons [J]10.1016/0008-6223(75)90258-4 ↗