journal article·2025-11

Enhanced ablation/oxidation resistance of high‐entropy carbides: The role of SiC whiskers

Lenka Ďaková, Monika Hrubovčáková, Peter Tatarko, Michal Hičák, Richard Sedlák, Petra Hviščová, Alexandra Kovalčíková

Publisher page

Abstract

Abstract This study investigates the effect of SiC whiskers (SiC w ) on the ablation/oxidation resistance of high‐entropy carbides (TiZrHfNbTa)C. High‐entropy carbide‐SiC w composites were prepared by powder metallurgy and spark plasma sintering. The ablation resistance was evaluated in an oxyacetylene flame at 2100°C/60 s. It was found that increasing SiC w content significantly improved the ablation resistance, and the dynamic oxidation rate decreased by up to 84% for the sample with 10 wt.% SiC w . This improvement is linked to the formation of a protective interfacial layer, which effectively impedes the ingress of oxygen. Microstructural analysis confirmed a denser oxide layer with reduced porosity with higher SiC w content. These results underline the strategic importance of SiC w for the development of materials resistant to extreme conditions.
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Research context

OpenAlex topics: Advanced materials and composites · Advanced ceramic materials synthesis · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Slovak Academy of Sciences Institute of Materials Research Košice Slovakia

Slovak Academy of Sciences Institute of Inorganic Chemistry Bratislava Slovakia

Funding

Agentúra na Podporu Výskumu a Vývoja

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