Evaluation of tribological behavior of silicon carbide and silicon nitride ceramics under different conditions

Abstract A comparative analysis of the tribological behavior of commercially available sintered silicon carbide (SiC) and three different types of silicon nitride (Si ₃ N ₄ ) ceramics have been carried out using the ball‐on‐disk method in dry and lubrication (deionized [DI] water and ethanol) environment. Scanning electron microscopy (SEM) was used to understand the morphology and chemical composition of the tribo‐surfaces. Sintered SiC (Hexoloy‐SA) had the highest friction coefficient during dry sliding with an average of ∼0.34. Deionized water showed a minor improvement in friction (∼0.27) while ethanol reduced the friction greatly to ∼0.18 compared to dry sliding. During dry sliding, the presence of an abrasive third body was responsible for the high wear rates (WRs) in these compositions. Hexoloy‐SA showed a lower WR during ethanol and DI water lubrication due to the formation of stable tribofilms as well as higher hardness which resisted the formation of third bodies. In comparison, Si ₃ N ₄ samples showed a lower WR in DI water and ethanol. The samples also showed composition‐dependent behavior which indicates that grain structure and grain boundary chemistry are playing a vital role in the tribological process.