journal article·2020-05

Phase formation and lattice distortion of Lu 2 O 3 ‐doped ZrO 2 in comparison with Y 2 O 3 ‐doped ZrO 2

Min‐sung Park, Buyoung Kim, Taewoo Kim, Eunpyo Hong, Heesoo Lee

Publisher page

Abstract

Abstract Lu 2 O 3 and Y 2 O 3 doping of 8, 11, and 18 mol% in ZrO 2 were prepared by solid solution reaction, aiming to study the phase stabilization of Lu 2 O 3 ‐doped ZrO 2 and Y 2 O 3 ‐doped ZrO 2 in terms of phase formation and lattice distortion. The Rietveld refinement results indicated that Lu 2 O 3 ‐doped ZrO 2 and Y 2 O 3 ‐doped ZrO 2 followed the same trend in terms of cubic phase fraction, increasing from 25%–30% (8 mol%) to 95%–100% (11 and 18 mol%). This phase formation was confirmed by observing the same diffraction ring pattern observed for the Lu 2 O 3 ‐doped ZrO 2 and Y 2 O 3 ‐doped ZrO 2 . The Vickers hardness of the Lu 2 O 3 ‐doped ZrO 2 was 4.3% higher than that of Y 2 O 3 ‐doped ZrO 2 at 8 mol%, but 9.7% and 14.8% lower at 11 and 18 mol%, respectively. This was likely caused by the lattice distortion effect of Y 2 O 3 doping overpowering the field strength difference between Lu 3+ and Y 3+ .
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Nuclear Materials and Properties · Nuclear materials and radiation effects · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering Pusan National University Busan Republic of Korea

HyMAR Corporation Busan Republic of Korea

References (14)

Show source-provided references
1. 10.1016/j.ssi.2004.06.01510.1016/j.ssi.2004.06.015 ↗
2. McColm I · 1983
3. Wiberg N · 2001
4. 10.1107/S056773947600155110.1107/S0567739476001551 ↗
5. 10.1111/j.1551-2916.2011.04710.x10.1111/j.1551-2916.2011.04710.x ↗
6. 10.1016/j.jct.2014.01.01410.1016/j.jct.2014.01.014 ↗
7. 10.1016/j.cossms.2004.03.00910.1016/j.cossms.2004.03.009 ↗
8. 10.1111/j.1151-2916.1990.tb06567.x10.1111/j.1151-2916.1990.tb06567.x ↗
9. 10.1088/0957-4484/20/24/24530310.1088/0957-4484/20/24/245303 ↗
10. 10.1016/j.ceramint.2012.07.03310.1016/j.ceramint.2012.07.033 ↗
11. 10.1007/978-1-4757-4732-410.1007/978-1-4757-4732-4 ↗
12. 10.1103/PhysRevMaterials.1.06360310.1103/PhysRevMaterials.1.063603 ↗
13. 10.1021/acs.jpcb.8b0290510.1021/acs.jpcb.8b02905 ↗
14. 10.1557/JMR.1996.009110.1557/JMR.1996.0091 ↗