New waste‐based clinkers for the preparation of low‐energy cements. A step forward toward circular economy
Source abstract
Abstract
Abstract This paper describes the use of industrial wastes arising from different production processes of the ceramic and marble industries as raw materials for the design and formulation of new cement clinkers with a high content of dicalcium silicate (Belite). The aim was to reintroduce these wastes in the industrial sector and take advantage of them for a greater environmental benefit, as indicated by the principles of the circular economy. Formulations containing 2.5, 5 and 10 wt% of chamotte and marble sludge, respectively, and a waste‐free formulation have been designed to obtain clinkers with a content of dicalcium silicate higher than 60 wt%. The different blends have been studied up to a maximum temperature of 1390°C by Thermal Analysis. Other techniques such as XRD, XRF, Modified Bogue Equation, Quality Indexes (LSF, AM, SM) and Optical Microscopy have been used for the study and characterization of industrial wastes, the raw materials and the high belite‐type cement dosages. The results indicate that this type of cements can be designed using different types of wastes and in this way reduce the environmental impacts caused by the extraction of raw materials and the deposition of the wastes in landfills, improving the circular economy of the construction industry.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Concrete and Cement Materials Research · Recycling and utilization of industrial and municipal waste in materials production · Recycled Aggregate Concrete Performance
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemical, Environmental and Materials Engineering University of Jaén Jaén Spain
The Institute of Materials Science (ICMS) Spanish Council of Scientific Research (CSIC) Sevilla Spain
Department of Chemical Engineering University of Patras Patras Greece
INVALOR: Research Infrastructure for Waste Valorization and Sustainable Management Patras Greece
References (49)
Show source-provided references
1. Van Oss HG · 2017
2. 10.5194/essd-10-195-201810.5194/essd-10-195-2018 ↗
3. España ralentizará el consumo de cemento en 2019 al 6% [homepage on the Internet]. c2019 [updated 2019 Mar 5]. Available from:https://www.eleconomista.es/empresas-finanzas/noticias/9740781/03/19/Espana-ralentizara-el-consumo-de-cemento-en-2019-al-6.html
4. Utilization of EAF metallurgical slag in “green” belite cement
5. The European Cement Association · 1998
6. Hellenic Cement Industry Association. Available from:www.hcia.gr
7. The European Cement Association. CEMBUREAU.Annual report 2001.
8. European Commission.Eurostat.Greenhouse gas emission statistics – emission inventories. Data from June 2018 [document on the Internet]. Available from:https://ec.europa.eu/eurostat/statistics-explained/index.php/Greenhouse_gas_emission_statistics
9. UchikawaH.Management strategy in cement technology for the next century: Part 3. World Cement.1994;47.
10. Lawrence CD · 2003 · 421
11. 10.1680/adcr.1999.11.1.310.1680/adcr.1999.11.1.3 ↗
12. 10.1016/j.conbuildmat.2011.03.03210.1016/j.conbuildmat.2011.03.032 ↗
13. 10.1016/S0958-9465(02)00097-510.1016/S0958-9465(02)00097-5 ↗
14. 10.1016/0008-8846(96)00099-310.1016/0008-8846(96)00099-3 ↗
15. Hewlett PC · 1998
16. European Commission.Eurostat.Circular economy – Overview [document on the Internet]. Available from:https://ec.europa.eu/eurostat/web/circular-economy
17. 10.1016/j.cemconres.2007.11.00810.1016/j.cemconres.2007.11.008 ↗
18. Estudio de las fases mineralógicas del clínker en una cementera española, utilizando el método de Rietveld
19. Martínez‐MartínezS Pérez‐VillarejoL Eliche‐QuesadaD Sánchez‐SotoPJ ChristogerouA KanellopoulouD et al.Desarrollo preliminar y estudio térmico de diferentes tipos de clínker de ecocemento sostenible con el medio ambiente utilizando residuos industriales y piedra caliza con alto porcentaje de óxido de magnesio en su composición. Paper presented at: Congreso Nacional del Medio Ambiente. CONAMA2018. Madrid Spain; 2018.
20. 2016 S Martínez‐Martínez D Eliche‐Quesada L Pérez‐Villarejo GN Angelopoulos PJ Sánchez‐Soto Valorización de chamota residual derivada de la producción de ladrillos de construcción cerámicos para el desarrollo de un nuevo tipo de clínker de cemento belítico
21. European Commission.Official Journal of the European Union. Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste and repealing certain Directives [document on the Internet]. 2008 Nov 22. Available from:https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:32008L0098&from=EN
22. European Commission.Official Journal of the European Union. Commission Decision 2000/532/EC on the list of waste pursuant to Directive 2008/98/EC of the European Parliament and of the Council [document on the Internet]. 2014 Dec 30. Available from:https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:32014D0955&from=EN
23. European Commission.Official Journal of the European Union. Commission notice on technical guidance on the classification of waste (2018/C 124/01) [document on the Internet]. 2018 Apr 9. Available from:https://eur-lex.europa.eu/legal-content/EN/TXT/PDF/?uri=CELEX:52018XC0409(01)&from=EN
24. Gobierno de España.Ministerio de Fomento.Ministerio de Agricultura Alimentación y Medio Ambiente. Centro de estudios y experimentación de obras públicas: Catálogo de residuos utilizables en construcción [homepage on the Internet]. Available fromhttp://www.cedexmateriales.es
25. Martínez‐MartínezS Pérez‐VillarejoL Eliche‐QuesadaD Garzón‐GarzónE Sánchez‐SotoPJ.Valorización de lodos rojos residuales de la producción de aluminio para la fabricación de cementos belíticos. Paper presented at: Congreso Nacional del Medio Ambiente. CONAMA2014. Madrid Spain; 2014.
26. 10.1016/j.jhazmat.2011.09.02410.1016/j.jhazmat.2011.09.024 ↗
27. 10.1016/j.jclepro.2019.02.12210.1016/j.jclepro.2019.02.122 ↗
28. 10.1016/j.conbuildmat.2018.09.14810.1016/j.conbuildmat.2018.09.148 ↗
29. 10.1016/j.conbuildmat.2019.04.03110.1016/j.conbuildmat.2019.04.031 ↗
30. 10.1016/j.promfg.2017.02.08110.1016/j.promfg.2017.02.081 ↗
31. 10.1016/j.wasman.2019.04.01810.1016/j.wasman.2019.04.018 ↗
32. 10.1016/j.conbuildmat.2016.06.02210.1016/j.conbuildmat.2016.06.022 ↗
33. 10.1016/j.jhazmat.2014.12.05310.1016/j.jhazmat.2014.12.053 ↗
34. 10.1016/j.wasman.2011.04.02210.1016/j.wasman.2011.04.022 ↗
35. 10.1177/0734242X1140765310.1177/0734242X11407653 ↗
36. 10.1016/j.jhazmat.2004.08.00210.1016/j.jhazmat.2004.08.002 ↗
37. 10.1016/S0956-053X(97)00004-410.1016/S0956-053X(97)00004-4 ↗
38. Pérez‐Villarejo L · 2018 · 109
39. Vázquez T · 2001
40. Güeto JM · 2005
41. 10.1007/s10973-007-8751-y10.1007/s10973-007-8751-y ↗
42. 10.1016/j.tca.2014.01.02610.1016/j.tca.2014.01.026 ↗
43. Influencia de la dilución de la muestra en los diagramas de ATD de reacciones reversibles e irreversibles de descomposición térmica de sólidos
44. 10.1016/j.apt.2013.08.00310.1016/j.apt.2013.08.003 ↗
45. Kinetic study of the thermal decomposition of calcium carbonate by isothermal methods of analysis
46. 10.1016/S0040-6031(99)00174-410.1016/S0040-6031(99)00174-4 ↗
47. Verein Deutscher Eisenhüttenleute (VDEH) · 1995
48. 10.3989/mc.1972.v22.i147.141610.3989/mc.1972.v22.i147.1416 ↗
49. Campbell DH · 1999