High gas permeability and directional channels of mullite porous ceramics prepared by pectin‐based freeze‐drying method

Abstract New gel system for preparing mullite porous ceramics by gel‐casting freeze‐drying was proposed, using pectin as gel source and alumina and silica as raw materials. Directional channels were formed due to sublimation of water during freeze‐drying and decomposition of pectin during high temperature sintering to prepare porous mullite ceramic membranes. Effects of solid content on the properties of mullite ceramics in terms of phase composition, microstructure, apparent porosity, bulk density, pore size distribution, compressive strength, thermal conductivity, pressure drop, and gas permeability were investigated. It was found that prepared porous mullite possessed high apparent porosity (56.04%–75.34%), low bulk density (.77–1.37 g/cm ³ ), uniform pore size distribution, relatively high compressive strength (.61–3.03 MPa), low thermal conductivity (.224–.329 W/(m·K)), high gas permeability coefficient (1.11 × 10 ⁻¹⁰ –4.73 × 10 ⁻¹¹ m ² ), and gas permeance (2.18 × 10 ⁻² –9.32 × 10 ⁻³ mol⋅m ⁻² ⋅s ⁻¹ ⋅Pa ⁻¹ ). These properties make prepared lightweight mullite ceramic membranes promising for application in high temperature flue gas filtration. Proposed gel system is expected to provide a new route to prepare porous ceramics with high porosity and directional channels.