journal article·2019-07

Effect of apple cider vinegar agent on the microstructure, phase evolution, and magnetic properties of CoFe 2 O 4 magnetic nanoparticles

Mohammad Afshari, Amir‐Reza Rouhani Isfahani, Saeed Hasani, Fatemeh Davar, Khadijeh Jahanbani Ardakani

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Abstract

Abstract In the present study, spinel structure CoFe 2 O 4 nanoparticles were successfully synthesized by the sol‐gel auto‐combustion technique. The effect of apple cider vinegar (ACV) addition as an organic biocompatible agent on the size, morphology, and magnetic properties of CoFe 2 O 4 nanoparticles was investigated in detail. The phase evolution, particle size, and lattice parameter changes of the synthesized phase have been estimated by using Rietveld structure refinement analysis of X‐ray powder diffraction data. Also, Fourier transform infrared spectra (FT‐IR) of the samples verified the presence of two expected bands correspond to tetrahedral and octahedral metal‐oxygen complexes within the spinel structure. Furthermore, microstructural observations revealed that ultrafine particles have a semi‐spherical morphology. It was shown that the particles size decreased from ~45 to ~17 nm with an increase in the amount of ACV. Magnetic properties were carried out by vibrating sample magnetometer (VSM) at room temperature. Both the saturation magnetization ( M s ) and coercivity ( H c ) were found to be significantly dependent on the crystallite size and the amount of ACV.
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Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Multiferroics and related materials · Iron oxide chemistry and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mining and Metallurgical Engineering Yazd University Yazd Iran

Department of Mechanical, Industrial & Aerospace Engineering Concordia University Montreal Québec Canada

Department of Chemistry Isfahan University of Technology Isfahan Iran

Department of Industrial Engineering Meybod University Meybod Iran

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