A low-temperature fast curing latent catalyst microencapsulated in a porous resin structure
Source abstract
Abstract
Abstract Low-temperature, fast curing latent catalysts for epoxides were prepared by microencapsulation of aluminum complexes through interfacial and radical polymerization. The resulting resin microcapsules were thermally responsive. Moreover, because the inside of the capsule had a porous structure, a highly active aluminum complex could be forced into the capsule by solvent penetration. The differential scanning calorimetric curve of the encapsulated complex showed an exothermic peak at 100 °C or less. In addition, after a mixture of bisphenol A epoxy resin, the curing catalyst, and triphenyl silanol was stored for 5000 h at 30 °C, the viscosity was only 1.6 times greater than the viscosity just after blending.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Epoxy Resin Curing Processes · Synthesis and properties of polymers · Injection Molding Process and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (22)
Show source-provided references
1. Development of resin stress buffer layer type wafer level chip size package with high reliability for board level test10.5104/jiep.11.84 ↗
2. Polymerization of cyclohexene oxide with Al(acac)3–silanol catalyst
3. Polymerization of cyclohexene oxide with aluminum complex-silanol catalysts. Part 3 dependence of catalytic activity on bulkiness of silanol and its intramolecular hydrogen bond
4. Polymerization of cyclohexene oxide with aluminum comlex/silanol catalysts. V. A catalytic activity dependence on the aluminum chelate structure
5. Polymerization of cyclohexene oxide with aluminum complex/silanol catalyst. 6. Oligomer and polymer effect
6. Polymerization of epoxide with aluminum complex/silanol catalyst. 7. Thermal and electrical properties of epoxy resin cured with the new catalyst10.1002/app.1984.070290125 ↗
7. Novel latent initiator for cationic polymerization of epoxides10.1002/1097-4628(20010411)80:2<181::AID-APP1085>3.0.CO;2-L ↗
8. Latent initiator for cationic polymerizations of epoxides: composite catalysts containing aluminum complexes phase-separated in epoxides10.1002/app.10035 ↗
9. Kondo · 1987
10. Kondo · 1991
11. Interfacial polycondensation. 2. Fundamentals of polymer formation at liquid interfaces10.1002/pol.1959.1204013702 ↗
12. Kondo · 1979
13. Gutcho · 1976
14. The development of direct thermal full color recording material
15. Mechanism of color development for UV-fixable thermal recording material
16. The structure of 1,2-epoxy-cyclohexane10.3891/acta.chem.scand.01-0283 ↗
17. Novel composite catalysts consisting of active organosilicon compounds and aluminum complexes for curing epoxy resins and other addition reactions10.1246/nikkashi.1993.1 ↗
18. Iwata · 1987
19. Study on the heat-recording material utilizing heat-responsive microcapsules(1)
20. Thermo-responsible microcapsule and the applications
21. UV-fixable diazo type thermal recording material
22. Takai · 2003 · vol. 1 · 76