journal article·2009-01

Adhesion of modified polymers to fibres: Maxima on adhesive strength-modifier amount curves and the causes of their appearance

Yu.A. Gorbatkina, V.G. Ivanova-Mumjieva, O.V. Lebedeva

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Abstract

Adhesion of modified polymers to fibres is considered. The dependences of the shear adhesive strength of polymer/fibre joints on the modifier content are analysed. It is shown that an increase in the adhesive strength can often be achieved by adding a component with a lower adhesive ability to the basic adhesive. As a result, a maximum strength is observed for a certain concentration range of the minor component. This paradoxical phenomenon can be explained with the use of simple qualitative reasoning, which is based on the analysis of the concentration dependences of surface and bulk properties. By the example of the ED-20 epoxy resin (analog of DGEBA), competitive processes whose superposition produces such a maximum are shown to be different for one-phase and two-phase adhesives.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fiber-reinforced polymer composites · Epoxy Resin Curing Processes · Material Properties and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Andreevskaya GD, Gorbatkina YuA, Il’inskii AM, Khantsis RZ. In: Physical chemistry and mechanics of oriented glass-fiber-reinforced plastics. Moscow: Nauka, 1967; p. 95–100.
2. Properties of isocyanurate–elastomer copolymers and of the carbon fiber-reinforced plastics on their basis as dependent on the parameters of heterophase structure of these copolymers
3. Thermostable adhesives based on monomers with CN-multiple bonds
4. Modification of polysulfone matrix by the liquid-crystalline polymer: strength of the interface
5. Adhesion of epoxy–polysulfone blends10.1023/A:1010682108122 ↗
6. The effect of an active diluent on the properties of epoxy resin and unidirectional carbon-fiber-reinforced plastics10.1023/B:MOCM.0000010621.05492.bf ↗
7. Compatibility and phase structure evolution in polysulfone–curable epoxy oligomer blends
8. Adhesion of epoxy-poly(arylene ether ketone) blends to fibers
9. Brantseva TV, Antonov AV, Gorbatkina YuA, Dutschk V, Maeder E, Kerber ML. Properties of model adhesive systems and composites based on epoxy resin–polysulfone blends. In: Proceedings of 10th European conference on composite materials ECCV-10, Belgium, Brugge, 3–7 June 2002.
10. Modification of epoxy resin by polysulfone to improve the interfacial and mechanical properties in glass fibre composites. I. Study of processes during matrix/glass fibre interface formation
11. Modification of epoxy resin by polysulfone to improve the interfacial and mechanical properties in glass fibre composites. II. Adhesion of the epoxy–polysulfone matrices to glass fibres
12. Modification of epoxy resin by polysulfone to improve the interfacial and mechanical properties in glass fibre composites. III. Properties of the cured blends and their structures in the polymer/fibre interphase
13. Adhesion of epoxy–thermoplastic and polysulfone–LCP-polymer matrices to fibers10.1163/1568554053971524 ↗
14. Change in the adhesive properties of epoxy–polysulfone mixtures during the cure process
15. Gorbatkina · 1987
16. Gorbatkina · 1992
17. Variance of adhesive strength and fracture mechanism of fibre/matrix joints10.1016/S0143-7496(00)00026-9 ↗
18. Estimation of adhesive strength in the system thermoplastic—thin fiber
19. A microbond method for determination of the shear strength of a fiber/resin interface10.1016/0266-3538(87)90059-5 ↗
20. Microbond method for determination of the shear strength of a fiber/resin interface: evaluation of experimental parameters10.1016/0266-3538(89)90076-6 ↗
21. An instrument for testing interfacial shear strength in polymer matrix composites10.1088/0957-0233/6/7/023 ↗
22. The interface between glass and carbon fibers and thermosetting polymers10.1002/pc.750060409 ↗
23. The kinetics of thermal degradation and the structure of bisphenol-A epoxy binder modified by active plasticizer10.1134/S1560090406030109 ↗
24. The effect of aging in water on the strength of fiber–polymer systems10.1080/00218469108030449 ↗
25. The durability of adhesive joints in the presence of water10.1016/0143-7496(96)00001-2 ↗
26. Fracture toughness of polysulfone/epoxy semi-IPN with morphology spectrum10.1007/s002890050456 ↗
27. Toughened plastics I. Washington, DC
28. Phase separation in epoxy-resin containing polyethersulfone10.1016/0032-3861(83)90120-9 ↗
29. Addition of polyethersulfone to epoxy-resins10.1002/pi.4980150117 ↗
30. Phase separation in polysulfone–modified epoxy mixtures. Relationships between curing conditions, morphology and ultimate behavior10.1016/S0032-3861(99)00238-4 ↗