Primer system for bonding conventional adhesives and coatings to silicone rubber
Source abstract
Abstract
Abstract This research examines a novel, two-part primer system that allows almost any adhesive or coating to adhere strongly to silicone rubber. Based on cyanoacrylate, the system forms a thin coating that binds tightly to silicone and provides a porous, nanostructured surface to which adhesives and coatings can bond well. Crucial to the effectiveness of the primer layer is the solvent used in the second part of the primer system. The layer׳s polycyanoacrylate forms as a gel in the presence of that solvent and is subject to the solvent׳s chemical and physical influences. When the solvent has little affinity for the polycyanoacrylate, as well as a small surface tension, the gel is able to withstand capillary stresses exerted by the evaporating solvent and become a xerogel with extensive porosity and nanostructure.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Synthesis and properties of polymers · Photopolymerization techniques and applications · Manufacturing Process and Optimization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (21)
Show source-provided references
1. Polysiloxane elastomers10.1021/ie50455a601 ↗
2. Noll · 1968
3. Wu S. Surface and interfacial tensions of polymers, oligomers, plasticizers, and organic pigments. In: Polymer handbook. New York: Wiley; 1989. p. 422–3.
4. Nitzsche S and Wick M. Silicone elastomers. United States Patent 3,032,528; 1 May 1962.
5. Packham · 2005
6. Silicone copolymer networks and interpenetrating polymer networks
7. Brockmann · 2009
8. Fukuda K, Okuma A and Ota M. Primer for alpha-cyanoacrylate-base resin compositions. United States Patent 4,814,427; 21 Mar 1989.
9. Henkel Corporation · 2011
10. Primers for adhesive bonding to polyolefins10.1002/app.1993.070480220 ↗
11. In situ pore structure studies of xerogel drying10.1021/cm00001a011 ↗
12. von Bramer PT. Method of bonding using solutions as catalysts with alpha-cyanoacrylate adhesives. United States Patent 3,260,637; 12 July 1966.
13. Ito K and Kimura K. Primer composition useful for application to non-polar on highly crystalline resin substrates. United States Patent 4,822,426; 18 April 1989.
14. Reaction of alpha-cyanoacrylic acid catalyzed by tertiary amines10.1007/BF01168106 ↗
15. Overhults WC. Cross-linked cyanoacrylate adhesive compositions. United States Patent 3,940,362; 24 February 1976.
16. McDonnell PF and Kneafsey BJ. Diazabicyclo and triazabicyclo primer compositions and use thereof in bonding non-polar substrates. United States Patent 4,869,772; 26 September 1989.
17. Reichardt · 2003 · 418
18. The surface tension of pure liquid compounds10.1063/1.3253106 ↗
19. Surface tension of diethyl carbonate, 1,2-dimethoxyethane and diethyl adipate10.1016/j.fluid.2010.03.040 ↗
20. Ito K and Kimura K. Primer composition containing an organometallic compound for binding substrates with a cyanoacrylate adhesive. United States Patent 5,110,392; 5 May 1992.
21. Hiraiwa A, Ito K and Kimura K. Primer composition. United States Patent 5,292,364; 8 March 1994.