journal article·2022-09

Study on synthesizing new urethane epoxy adhesives and their adhesive properties on different substrates

Sepideh Ranji, Myung Cheon Lee

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Abstract

In this work, we prepared urethane epoxy adhesives from the reaction of glycidol and aliphatic diisocyanate, 4, 4-methylene bis (cyclohexyl isocyanate) (HMDI). We modified diglycidyl ether of bisphenol A (DGEBA) with this urethane epoxy and cured by maleic anhydride. We used Fourier-transform infrared (FTIR) for monitoring the reaction progress and confirming the unique structure. We measured the lap shear strength of joints, bonded with different weight ratios of urethane epoxy and DGEBA, on three different substrates aluminum, stainless steel, and glass fiber reinforced epoxy . The effect of substrates with varied materials was studied by scanning electron microscopy (SEM) combined with energy-dispersive X-ray spectroscopy (EDX) with comparisons with X-ray photoelectron spectroscopy (XPS) results from other studies. The novel urethane-epoxy adhesive exhibited improvements in mechanical properties such as shear strength and elongation in comparison to common DGEBA-based epoxy adhesives.
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Research context

OpenAlex topics: Polymer composites and self-healing · Epoxy Resin Curing Processes · Photopolymerization techniques and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Influence of artificial aging on structural adhesive connections for façade applications10.1016/j.ijadhadh.2018.02.022 ↗
2. Solvent presence and its impact on the lap-shear strength of SDS-decorated graphene hybrid electrically conductive adhesives10.1016/j.ijadhadh.2017.06.012 ↗
3. Preparation and properties of novel poly(urethane-imide)s via blending of reactive polyimide and epoxy-terminated urethane prepolymers10.1177/0954008307082743 ↗
4. Phase-separated thiol-epoxy-acrylate hybrid polymer networks with controlled cross-link density synthesized by simultaneous thiol-acrylate and thiol-epoxy click reactions10.1021/acs.macromol.6b00141 ↗
5. ZnS/Bacterial cellulose/epoxy resin (ZnS/BC/E56) nanocomposites with good transparency and flexibility10.1016/j.jmst.2015.08.014 ↗
6. Impact property of flexible epoxy treated natural fiber reinforced PLA composites10.1016/j.egypro.2013.06.820 ↗
7. Functional dendritic curing agent for epoxy resin: processing, mechanical performance and curing/toughening mechanism10.1016/j.compositesb.2017.09.073 ↗
8. Curing of epoxy-urethane copolymers in a heated mold: effect of the curing conditions on the phase-separation process10.1002/app.1508 ↗
9. Syntheses of epoxyurethane polymers from isocyanate free oligo-polyhydroxyurethane10.1016/j.eurpolymj.2015.12.017 ↗
10. Identification of the reaction mechanism between phenyl methacrylate and epoxy and its application in preparing low-dielectric epoxy thermosets with flexibility
11. Enhancement of the mechanical and thermal properties of injection-molded polylactide parts by the addition of acrylated epoxidized soybean oil10.1016/j.matdes.2017.11.031 ↗
12. Properties of networks obtained by internal plasticization of epoxy resin with aromatic and aliphatic glycidyl compounds10.1002/app.1989.070370913 ↗
13. Novel thermally-reversible epoxy-urethane networks10.1163/156855511X606155 ↗
14. Coatings of PDMS-modified epoxy via urethane linkage: segmental correlation length, phase morphology, thermomechanical and surface behavior10.1016/j.porgcoat.2009.02.007 ↗
15. Cure kinetics study of two epoxy systems with Fourier tranform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC)10.1080/10601325.2012.696995 ↗
16. Recent advancement in plant oil derived polyol-based polyurethane foam for future perspective: a review10.1002/ejlt.201900225 ↗
17. Green fabrication of ultraviolet curable epoxy acrylate-silica hybrid coatings
18. Preparation and properties of UV-cured epoxy acrylate/glycidyl-POSS coatings10.1007/s11998-016-9886-1 ↗
19. Multi-functional urethane epoxy acrylates (UEAs) and their visible-light cured UEA/MSMA-colloid silica nanocomposite films as reinforcement on polycarbonate matrix
20. Interaction of epoxy model molecules with aluminium, anodised titanium and copper surfaces: an XPS study10.1016/S0169-4332(97)00789-7 ↗
21. The failure mode of adhesively bonded aluminium following aqueous exposure10.1002/sia.740160150 ↗
22. Bonding of a simulated epoxy resin to aluminium surfaces studied by XPS10.1016/0378-5963(83)90036-3 ↗
23. Inelastic electron tunneling spectroscopic studies of adsorption of a simulated epoxy resin10.1016/0378-5963(83)90088-0 ↗
24. Study of dextrin-derived curing agent for waterborne epoxy adhesive
25. Comparative study on the adhesive properties of different epoxy resins10.1016/j.ijadhadh.2005.02.004 ↗
26. Study on the curing reaction kinetics of a novel epoxy system10.1039/C6RA25120J ↗
27. Synthesis of rosin-based flexible anhydride-type curing agents and properties of the cured epoxy10.1002/pi.2680 ↗
28. The durability of clear polyurethane coil coatings studied by FTIR peak fitting10.1016/j.polymdegradstab.2012.12.003 ↗
29. Application of high-strength biodegradable polyurethanes containing different ratios of biobased isomannide and poly (Ïμ-caprolactone) diol10.1177/0883911513484572 ↗
30. Fourier transform infrared spectroscopic analysis of protein secondary structures10.1111/j.1745-7270.2007.00320.x ↗
31. An FTIR investigation of isocyanate skin absorption using in vitro Guinea pig skin10.1039/b517948c ↗
32. Reaction of a diepoxide with a diisocyanate in bulk10.1007/BF00298317 ↗
33. Cho D, Drzal LT. Ft-Ir studies on Imidization and End group reaction behaviors of a Phenylethynyl terminated imide Oligomer. ICCM12 Conf Paris July 99th 1999;Paper 684:1–10.
34. Polyurethane coatings used in twentieth century outdoor painted sculptures. Part I: comparative study of various systems by means of ATR-FTIR spectroscopy
35. Synthesis of novel phosphorus-containing cyanate esters and their curing reaction with epoxy resin10.1016/j.polymer.2004.09.023 ↗
36. High transition temperature shape memory polymers (SMPs) by telechelic oligomer approach10.1016/j.reactfunctpolym.2014.02.008 ↗
37. Comparison of fracture behavior between acrylic and epoxy adhesives10.1016/j.ijadhadh.2017.02.011 ↗
38. On adhesive properties of nano-silica/epoxy bonded single-lap joints10.1016/j.matdes.2016.01.055 ↗