journal article·2018-10

Improvement of the unconfined compressive strength of 3D-printed model rock via silica sand functionalization using silane coupling agents

Kevin J. Hodder, John A. Nychka, Rick J. Chalaturnyk

Publisher page

Abstract

Abstract Model rock is being explored for use in geotechnical research due to the ability to customize the design and production of specimens for a variety of testing techniques. However, a current limitation of model rock manufacture is that the mechanical properties are not similar enough to natural rock, such as Berea sandstone. In this study, silane coupling agents (SCAs) were used to functionalize the surface of silica sand to test the feasibility of increasing the unconfined compressive strength (UCS) of model rock fabricated using furfuryl alcohol as a binder. Observations of the wetting angle of furfuryl alcohol on functionalized glass slides and the adhesive strength on steel tensile stubs were used to select possible candidates for UCS sample fabrication. UCS testing of samples fabricated with bare and functionalized silica sand showed that there is a significant improvement of the UCS of model rock when (3-glycidoxypropyl)trimethoxysilane (GPTMS) is used to functionalize the sand prior to fabrication. The following study provides a possible approach to increase the UCS of model rock via SCAs, providing a strength closer to natural rock for geotechnical testing.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Bone Tissue Engineering Materials · Innovations in Concrete and Construction Materials · Tunneling and Rock Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. The point-load strength test10.1016/0148-9062(72)90030-7 ↗
2. Interlaboratory testing program for rock properties, round one - longitudinal and transverse pulse velocities, unconfined compressive strength, uniaxial modulus, and splitting tensile strength10.1520/GTJ10279J ↗
3. Addendum to interlaboratory testing program for rock properties, round one10.1520/GTJ10099J ↗
4. Hodder · 2017
5. Process limitations of 3D printing model rock10.1007/s40964-018-0042-6 ↗
6. 3D printed sandstone strength: curing of furfuryl alcohol resin-based sandstone, 3D print
7. Osinga S, Zambrano-Narvaez G, Chalaturnyk R. , Study of geomechanical properties of 3D printed sandstone analogue, In: Proceedings of the American Rock Mechanics Association: ARMA; 2015. pp.15-547.
8. Standard test methods for compressive strength and elastic moduli of intact rock core specimens under varying states of stress and temperatures, ASTM D7012-14. 2014 pp.1–9.
9. Boggs · 2006
10. Quartz cementation in oil field sandstones: a review of the key controversies
11. McKillip William J. , Chemistry of furan polymers, In: Proceedings of the adhesives from renewable resources: 1989. pp. 408–423. https://www.doi.org/10.1021/bk-1989-0385.ch029.10.1021/bk-1989-0385.ch029 ↗
12. Mechanical properties and loss on ignition of phenolic and furan resin bonded sand casting
13. Acid-catalyzed polycondensation of furfuryl alcohol: mechanisms of chromophore formation and cross-linking10.1021/ma951522f ↗
14. A study of furfuryl alcohol resin components by gel permeation chromatography10.1016/S0021-9673(01)80242-9 ↗
15. Characterization of silica particles modified with γ-methacryloxypropyltrimethoxysilane10.1016/j.apsusc.2016.11.075 ↗
16. Effects of silanes and silane derivatives on cement hydration and mechanical properties of mortars10.1016/j.conbuildmat.2016.11.004 ↗
17. Surface modification of inorganic nanoparticles for development of organic-inorganic nanocomposites - A review10.1016/j.progpolymsci.2013.02.003 ↗
18. Plueddemann · 1982
19. Surface characterization of iron and steel prior to coating10.1016/0033-0655(87)80003-1 ↗
20. Semiconductor-half metal transition at the Fe3O4(001) surface upon hydrogen adsorption
21. Hydroxyl groups on silica surface10.1016/0022-3093(75)90095-2 ↗
22. Kinloch · 1987
23. Wettability of porous surfaces10.1039/tf9444000546 ↗
24. Reaction of (3-aminopropyl)dimethylethoxysilane with amine catalysts on silica surfaces10.1006/jcis.2000.7224 ↗
25. An introduction to silanes and their clinical applications in dentistry
26. The polymeric materials encyclopedia
27. Chemically activated furfuryl alcohol-based wood adhesives. I. The role of furfuryl alcohol10.1515/hfsg.1996.50.5.470 ↗
28. Sustainable phenolic fractions as basis for furfuryl alcohol-based co-polymers and their use as wood adhesives10.3390/polym8110396 ↗
29. On the interaction of lignins, furan resins and furfuryl alcohol in adhesive systems
30. The behavior of furan derivatives in polymerization reactions10.1007/3-540-08389-8_6 ↗
31. Kinetics and products of the acid-catalyzed ring-opening of atmospherically relevant butyl epoxy alcohols10.1021/jp103907c ↗
32. Rock failure modes under uniaxial compression, Brazilian, and point load tests10.1007/s10064-013-0505-4 ↗