in situ FTIR study of adhesive interactions of 4,4′-methylene diphenyl diisocyanate and native metals
Source abstract
Abstract
Abstract Native surfaces of Al, Cu and Au are exposed to diluted solutions of 4,4′-methylene diphenyl diisocyanate (4,4′-MDI). The resulting 4,4′-MDI adsorption state is characterised by in situ infrared external reflection absorption spectroscopy. On Au, the adsorbate state differs from bulk but the interactions are weak. On Al and Cu, rich spectral features and resistance against desorption indicate strong adhesion which is most likely chemical by nature. However, further quantum mechanical modelling is needed for final conclusions on the adhesion mechanism.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Molecular Junctions and Nanostructures · Force Microscopy Techniques and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. Wehlack · 2009 · 14
2. C. Wehlack, E. Mallandain, H. Ehbing, D.J. Dijkstra, W. Possart. In: Proceedings of the 33rd Annual Meeting Adh. Society, Daytona Beach, FL, USA, 21–24 February 2010, pp. 179–181.
3. C. Wehlack, W. Possart. In: Proceedings of the 4th World Congress on Adhesion and Related Phenomena (WCARP IV), Arcachon, France, 26–30 September 2010, p. 21.
4. C. Wehlack, H. Ehbing, D.J. Dijkstra, W. Possart. In: Proceedings of the 4th World Congress on Adhesion and Related Phenomena (WCARP IV), Arcachon, France, 26–30 September 2010, p. 212.
5. C. Wehlack, E. Mallandain, H. Ehbing, D.J. Dijkstra, W. Possart. In: Proceedings of the 4th World Congress on Adhesion and Related Phenomena (WCARP IV), Arcachon, France, 26–30 September 2010, p. 213.
6. Dillingham · J Adhes · 2003 · 79 · 26910.1080/00218460309554 ↗
7. Chehimi · J Adhes Sci Technol · 1992 · 6 · 37710.1163/156856192X00205 ↗
8. Shimizu · Surf Interface Anal · 2010 · 42 · 143210.1002/sia.3586 ↗
9. Eley · J Chem Soc, Faraday Trans · 1974 · 70 · 109910.1039/f19747001099 ↗
10. Harrison · J Chem Soc, Faraday Trans · 1975 · 71 · 246810.1039/f19757101013 ↗
11. Lay · 1996
12. Kim · J Mater Sci · 2005 · 40 · 278910.1007/s10853-005-2409-6 ↗
13. Tang · Surf Interface Anal · 2009 · 41 · 97410.1002/sia.3130 ↗
14. Garda · Surf Sci · 2005 · 598 · 5710.1016/j.susc.2005.09.024 ↗
15. Ferullo · J Mol Catal A · 2001 · 167 · 11510.1016/S1381-1169(00)00498-2 ↗
16. Belelli · Surf Sci · 2010 · 604 · 44210.1016/j.susc.2009.12.014 ↗
17. Nies · J Adhes · 2012 · 88 · 66510.1080/00218464.2012.682865 ↗
18. Wehlack · Soft Mater · 2007 · 5 · 8710.1080/15394450701554536 ↗
19. Wehlack · IOP Conf Ser: Mater Sci Eng · 2009 · 5 · 01200310.1088/1757-899X/5/1/012003 ↗
20. C. Nies. Chemische Adhäsionswechselwirkungen zwischen Polyurethan-Monomeren und Metallsubstraten [Diploma thesis] Saarbrücken, Germany: Saarland University; 2010.
21. C. Nies, C. Wehlack, H. Ehbing, D.J. Dijkstra, W. Possart. In: Proceedings of the 4th World Congress on Adhesion and Related Phenomena (WCARP IV), Arcachon, France, 26–30 September 2010, p. 23.
22. F. Fug. Chemische Adhäsionswechselwirkungen zwischen Isocyanaten und Metallsubstraten [Diploma thesis] Saarbrücken, Germany: Saarland University; 2011.
23. Elzein · J Adhes · 2013 · 89 · 41610.1080/00218464.2013.757521 ↗
24. Elzein · 2005 · 47
25. Ghorbal · Chem Phys Lett · 2007 · 443 · 35210.1016/j.cplett.2007.06.110 ↗
26. Elzein · Polymer · 2003 · 44 · 364910.1016/S0032-3861(03)00293-3 ↗
27. Elzein · Polymer · 2002 · 43 · 481110.1016/S0032-3861(02)00239-2 ↗
28. Brogly · Macromolecules · 1998 · 31 · 396710.1021/ma971408s ↗
29. Brogly · Macromol Theor Simul · 1998 · 7 · 6510.1002/(SICI)1521-3919(19980101)7:1<65::AID-MATS65>3.0.CO;2-P ↗
30. Bengu · J Adhes · 2006 · 82 · 113310.1080/00218460600998565 ↗
31. Hong · Surf Interface Anal · 1994 · 21 · 65010.1002/sia.740210909 ↗
32. Rosales · J Adhes · 2007 · 83 · 26710.1080/00218460701239125 ↗
33. Ondrus · J Adhes · 1989 · 29 · 2710.1080/00218468908026475 ↗
34. Boerio · Appl Spectrosc · 1979 · 33 · 12110.1366/0003702794926047 ↗
35. Wehlack · Macromol Symp · 2004 · 205 · 25110.1002/masy.200450123 ↗
36. Nies · Int J Adhes Adhes · 2014 · 52 · 1910.1016/j.ijadhadh.2014.03.006 ↗
37. B. Valeske. Mikrostruktur und thermo-chemisches Verhalten in adhäsiv gebundenen, ultradünnen Filmen aus vernetzenden Polycyanuraten [PhD thesis] Saarbrücken: Saarland University; 2003.
38. Possart · 2001
39. Dieckhoff · 2001
40. Meiser · 2005 · 445
41. Uhlig · 2006 · 159
42. Barthés-Labrousse · J Adhes · 2012 · 88 · 69910.1080/00218464.2012.682933 ↗