Effect of cellulosic fillers addition on curing and adhesion strength of moisture-curing one-component polyurethane adhesives
Source abstract
Abstract
Abstract In this work, microcrystalline cellulose (MCC) and sawdust (SD) green fillers have been demonstrated as reactive fillers and moisture reservoirs for enhanced curing and adhesion strength of one-component moisture-curing polyurethane (PU) adhesives. The chemical reaction between the MCC or SD fillers and isocyanates present in the PU adhesives was tracked using Fourier-transform infrared spectroscopy (FTIR), while the joint strength was determined using lap-shear tests. The results showed that the addition of MCC or SD leads to an accelerated curing rate through the early consumption of isocyanates. The lap-shear strength of unreinforced PU adhesive joints was achieved in 12 hours. In turn, the curing time in MCC and SD reinforced joints was achieved in 5 hours. The addition of MCC and SD fillers also enhanced the lap-shear strength of the joints under full cure conditions. An autocatalytic growth model was used to describe the lap-shear strength variation with respect to curing time.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polymer composites and self-healing · Epoxy Resin Curing Processes · Lignin and Wood Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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