Investigation of mechanical and thermo-mechanical characteristics of silane-treated cellulose nanofibers from agricultural waste reinforced epoxy adhesive composites
Source abstract
Abstract
The issue of deforestation has been of considerable concern in recent years. So as to contribute to a solution to this problem a major aim of this study has been to develop a sustainable environment by using agricultural industry waste in structural applications rather than wood. By this way, the study employed cellulose nanofibers (CNFs) derived from red banana empty fruit bunches to solve issues related to landfill gas emissions and the simultaneous utilization of organic wastes. The impact of silane treatment on the physicochemical, thermal, and morphological properties of CNFs was examined. Compression moulding was utilized to make different loading levels of silane-treated CNFs (SCNFs) reinforced epoxy nanocomposites. The resultant nanocomposites were evaluated by using various physical, mechanical, thermal, and micro-structural characterization tests. Properties such as tensile strength, flexural strength, impact strength, glass transition temperature, micro-hardness, thermal stability, and so forth, were evaluated under controlled laboratory conditions. Field emission scanning electron microscopy revealed the size and distribution patterns of the SCNFs in an epoxy matrix. Coefficient of effectiveness, cole-cole plots, and cross-link density studies confirmed the adhesion behavior of SCNFs with epoxy resin as a function of SCNF loading. All the findings led to the conclusion that the SCNF reinforced epoxy composites would make suitable materials for lightweight structural applications.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Natural Fiber Reinforced Composites · Advanced Cellulose Research Studies · Electrospun Nanofibers in Biomedical Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (51)
Show source-provided references
1. Experimental investigation on the mechanical properties of green hybrid sisal and glass fiber reinforced polymer composites10.1080/15440478.2015.1029192 ↗
2. A facile one-step way for extraction of nanocellulose with high yield by ball milling with ionic liquid10.1007/s10570-017-1238-5 ↗
3. Recycle used paper egg carton boxes as a source to produce hybrid AgNPs-carboxyl nanocellulose through bio-synthesis and its application in active food packaging10.1016/j.ijbiomac.2023.126119 ↗
4. A comprehensive review on cellulose nanocrystals and cellulose nanofibers: pretreatment, preparation, and characterization10.1002/pc.25929 ↗
5. Processing nanocellulose to bulk materials: a review10.1007/s10570-019-02642-3 ↗
6. Cellulose nanocrystals vs. Cellulose nanofibrils: a comparative study on their microstructures and effects as polymer reinforcing agents10.1021/am302624t ↗
7. Nanocellulose: extraction and application
8. On the use of nanocellulose as reinforcement in polymer matrix composites10.1016/j.compscitech.2014.08.032 ↗
9. Tensile properties and wear resistance of epoxy nanocomposites reinforced with cellulose nanofibers10.1007/s00289-017-2142-8 ↗
10. Extraction of cellulose nanofibers from cocos nucifera var aurantiaca peduncle by ball milling combined with chemical treatment10.1016/j.carbpol.2019.02.063 ↗
11. Mechanical, morphological and structural properties of cellulose nanofibers reinforced epoxy composites10.1016/j.ijbiomac.2017.01.029 ↗
12. Silane coupling agents used for natural fiber/polymer composites: a review10.1016/j.compositesa.2010.03.005 ↗
13. Hydrophobic esterification of cellulose nanocrystals for epoxy reinforcement10.1016/j.polymer.2018.08.076 ↗
14. Recent studies on modified cellulose/nanocellulose epoxy composites: a systematic review10.1016/j.carbpol.2020.117366 ↗
15. Preparation and characterization of cellulose laurate ester by catalyzed transesterification10.1016/j.carbpol.2017.03.074 ↗
16. Surface hydrophobization of TEMPO-oxidized cellulose nanofibrils (CNFs) using a facile, aqueous modification process and its effect on properties of epoxy nanocomposites10.1007/s10570-019-02762-w ↗
17. Evaluation of a new processing method for improved nanocomposite dispersions10.1179/2055033215Y.0000000009 ↗
18. Silylation and characterization of microcrystalline cellulose isolated from Indonesian native oil palm empty fruit bunch10.1016/j.carbpol.2017.12.060 ↗
19. Cellulose nanocrystal: a promising toughening agent for unsaturated polyester nanocomposite10.1016/j.polymer.2014.11.054 ↗
20. Surface-modified cellulose nanocrystals for biobased epoxy nanocomposites10.1016/j.polymer.2017.11.051 ↗
21. Cellulose nanostructures from wood waste with low input consumption10.1016/j.jclepro.2018.11.099 ↗
22. Preparation of cellulose nanofiber from softwood pulp by ball milling10.1007/s10570-015-0582-6 ↗
23. Extraction of cellulose nanocrystals from red banana peduncle agro‐waste and application in environmentally friendly biocomposite film
24. Modification of bacterial cellulose with organosilanes to improve attachment and spreading of human fibroblasts10.1007/s10570-015-0651-x ↗
25. Isolation and characterization of cellulose nanocrystals from Saharan aloe vera cactus fibers10.1080/1023666X.2018.1478366 ↗
26. Preparation and characterization of alkali treated cocos nucifera var aurantiaca peduncle fibers reinforced epoxy composites10.1088/2053-1591/ab54ff ↗
27. A novel approach for extracting cellulose nanofibers from lignocellulosic biomass by ball milling combined with chemical treatment10.1002/app.42990 ↗
28. Surface chemical functionalization of cellulose nanocrystals by 3-aminopropyltriethoxysilane10.1016/j.ijbiomac.2017.08.136 ↗
29. Effects of silane surface treatment of cellulose nanocrystals on the tensile properties of cellulose-polyvinyl chloride nanocomposite10.17576/jsm-2015-4406-05 ↗
30. Surface-modified nano-cellulose as reinforcement in poly(lactic acid) to conform new composites10.1016/j.indcrop.2015.03.075 ↗
31. Preparation and characterization of pva composites with cellulose nanofibers obtained by ultrasonication10.15376/biores.6.1.487-512 ↗
32. Surface modification of banana fibers using organosilanes: an IGC insight10.1007/s10570-019-02329-9 ↗
33. Effect of reaction conditions on the surface modification of cellulose nanofibrils with aminopropyl triethoxysilane10.3390/coatings8040139 ↗
34. Enhancement of the physical, mechanical, and thermal properties of epoxy-based bamboo nanofiber nanocomposites10.15376/biores.13.4.7709-7725 ↗
35. Development and characterization of epoxy nanocomposites based on nano-structured oil palm ash10.1016/j.compositesb.2013.04.013 ↗
36. Evaluation of elastic modulus and hardness of crop stalks cell walls by nano-indentation10.1016/j.biortech.2009.10.074 ↗
37. Thermal and dynamic mechanical properties of cellulose nanofibers reinforced epoxy composites10.1016/j.ijbiomac.2017.04.074 ↗
38. Mechanical, morphological and structural properties of cellulose nanofibers reinforced epoxy composites10.1016/j.ijbiomac.2017.01.029 ↗
39. Mechanical, physical and tribological characterization of nano-cellulose fibers reinforced bio-epoxy composites: an attempt to fabricate and scale the ‘Green’ composite10.1016/j.carbpol.2016.03.097 ↗
40. Effect of cross-link density on interphase creation in polymer nanocomposites10.1021/ma800830p ↗
41. Toughened bioepoxy blends and composites based on poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol) triblock copolymer and sisal fiber fabrics: a new approach10.1016/j.conbuildmat.2020.121843 ↗
42. Physical, tribological and viscoelastic behavior of machining wear debris powder reinforced epoxy composites10.1016/j.jclepro.2020.122786 ↗
43. Effect of cellulose nano fibers and nano clays on the mechanical, morphological, thermal and dynamic mechanical performance of kenaf/epoxy composites10.1016/j.carbpol.2020.116248 ↗
44. Dynamic mechanical properties of oil palm nano filler/kenaf/epoxy hybrid nanocomposites10.1016/j.conbuildmat.2016.07.059 ↗
45. Thermal and dynamic mechanical characterization of thermoplastic polyurethane/organoclay nanocomposites prepared by melt compounding10.1016/j.msea.2009.10.063 ↗
46. Dynamic mechanical analysis of banana fiber reinforced polyester composites10.1016/S0266-3538(02)00254-3 ↗
47. Dynamic mechanical analysis of randomly oriented intimately mixed short banana/sisal hybrid fibre reinforced polyester composites10.1016/j.compscitech.2004.10.023 ↗
48. Koleske, J. V Paint and coating testing manual: fifteenth edition of the gardner-sward handbook, PA: ASTM International, [West Conshohocken]..
49. Reinforcement of stearic acid treated egg shell particles in epoxy thermosets: structural, thermal, and mechanical characterization10.3390/ma11101872 ↗
50. Mechanical and thermal properties of waterborne epoxy composites containing cellulose nanocrystals10.1016/j.polymer.2013.10.011 ↗
51. Effect of nanocellulose isolation techniques on the formation of reinforced poly(vinyl alcohol) nanocomposite films10.3144/expresspolymlett.2012.85 ↗