journal article·2017-09

Synthesis of Calcium-Phosphate Powder from Calcium Formiate and Ammonium Hydrophosphate for Obtaining Biocompatible Resorbable Biphase Ceramic Materials

T. V. Safronova, V. I. Putlyaev, Ya. Yu. Filippov, S. A. Vladimirova, D. M. Zuev, G. S. Cherkasova

Glass and Ceramics· Volume 74· Issue 5-6
Publisher page

Abstract

Calcium phosphate powder was synthesized from calcium formiate Ca(CHO2)2 and ammonium hydrophosphate (NH4)2 HPO4 with Ca/P ratio in the initial water solutions equal to 1. The phase composition of the powders synthesized from 0.5M solutions was represented by brushite CaHPO4 · 2H2O and octacalcium phosphate Ca8(HPO4)2 (PO4)6 · 6H2O. After firing at 1100°C the phase composition of the powder was represented by calcium pyrophosphate β-Ca2P2O7 and tricalcium phosphate β-Ca3 (PO4)2. The synthesized powder can be used to obtain biocompatible resorbable biphase ceramic materials and composites with a polymer matrix.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Bone Tissue Engineering Materials · biodegradable polymer synthesis and properties · Chemical Synthesis and Characterization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (19)

Show source-provided references
1. S. M. Barinov, “Ceramic and composite materials based on calcium phosphates for medicine,” Usp. Fiz. Nauk, 79(1), 15 – 32 (2010).
2. T. V. Safronova and V. I. Putlyaev, “Medical inorganic materials science in Russia: calcium phosphate material,” Nanosistemy: Fiz., Khim., Matematika, 4(1), 24 – 47 (2013).
3. A. V. Belyakov, E. V. Zharikov, and A. A. Malygin, Chemical Principles of the Nanotechnology of Solid Phase Material with Different Functional Purpose [in Russian], SPbSTI (TU), St. Petersburg (2006).
4. T. V. Safronova, “The phase composition of ceramic based on calcium hydroxyapatite containing byproducts of the synthesis reaction,” Steklo Keram., No. 4, 21 – 24 (2006); T. V. Safronova, “The phase composition of ceramic based on calcium hydroxyapatite containing byproducts of the synthesis reaction,” Glass Ceram., 66(3 – 4), 136 – 139 (2006).
5. T. V. Safronova, M. A. Shekhirev, V. I. Putlyaev, and Yu. D. Tret’yakov, “Ceramic materials based on hydroxyapatite synthesized from solutions of varying concentrations,” Neorg. Mater., 43(8), 1005 – 1014 (2007).10.1134/S0020168507080158 ↗
6. T. V. Safronova, V. I. Putlyaev, G. K. Kazakova, and S. A. Korneichuk, “Biphase CaO–P2O5 ceramic based on powder synthesized from calcium acetate and ammonium hydrophophate,” Steklo Keram., No. 2, 34 – 41 (2013); T. V. Safronova, V. I. Putlyaev, G. K. Kazakova, and S. A. Korneichuk, “Biphase CaO–P2O5 ceramic based on powder synthesized from calcium acetate and ammonium hydrophophate,” Glass Ceram., 70(1 – 2), 65 – 70 (2013).
7. T. V. Safronova, G. K. Kazakpova, P. V. Evdokimov, et al., “Ceramic based on calcium phosphate powder synthesized from calcium saccharate and ammonium hydrophosphate,” Materialovedenie, No. 3, 46 – 50 (2016).
8. A. A. Stepuk, A. A. Veresov, V. I. Putlyaev, and Yu. D. Tret’yakov, ”Effect the anions NO3 –, CH3 COO– and Cl– on the morphology of calcium hydroxyapatite crystals,” Dokl. Akad. Nauk, 412(1), 11 – 14 (2007).
9. T. Safronova, S. A. Kurbatova, T. B. Shatalova, et al., “Calcium pyrophosphate powder synthesized from calcium pyrophosphate and acetate for obtaining bioceramics,” Materialovedenie, No. 8, 45 – 50 (2016).
10. T. Safronova, V. I. Putlyaev, P. V. Evdokimov, et al., “Black calcium phosphate powders for stereolithography,” in: Proc. 13th Russian-Chinese Symposium on New Materials and Technologies [in Russian], Interkontakt Nauka, Moscow (2015), Vol. 2, pp. 604 – 606.
11. T. V. Safronova, A. V. Kuznetsov, S. Korneychuk, et al., “Calcium phosphate powders synthesized from solutions with [Ca2+]/[PO4 3–] = 1 for bioresorbable ceramics,” Cent. Eur. J. Chem., 7(2), 184 – 191 (2009).
12. T. Kanazawa, Inorganic Phosphate Materials [Russian translation], Naukova Dumka, Kiev (1998).
13. V. I. Putlyaev, T. V. Safronova, E. V. Kukueva, and Yu. D. Tret’yakov, A Method for Preparing Batches for Obtaining Biodegradable Ceramic Material, RF Pat. 2456253 [in Russian], publ. July 20, 2012.
14. V. I. Kuznetsov, R. L. Globus, T. N. Karskaya, et al., Handbook of Chemical Reagents and Preparations [in Russian], Goskhimizdat, Moscow (1953).
15. V. F. Janas and K. S. TenHuisen, Relic Process for Producing Bioresorbable Ceramic Tissue Scaffolds, US Pat. 6667049, publ. December 23, 2003.
16. T. Motoshiro and K. Sukezo, Method for Production of Porous Spheres of Calcium, US Pat. 4752457, publ. June 21, 1988.
17. A. Yasukawa, H. Takase, K. Kandori, and T. Ishikawa, “Preparation of calcium hydroxyapatitie using amides,” Polyhedron, 13(22), 3071 – 3078 (1994).10.1016/S0277-5387(00)83673-6 ↗
18. R. M.Wilson, J. C. Elliott, and S. E. P. Dowker, “Formate incorporation in the structure of Ca-deficient apatite: Rietveld structure refinement,” J. Solid State Chem., 174, 132 – 140 (2003).10.1016/S0022-4596(03)00188-9 ↗
19. V. I. Putlyaev, E. V. Kukueva, T. Safronova, et al., “Particulars of thermolysis octacalcium phosphate,” Novye Ogneup., No. 10, 52 – 56 (2013).