journal article·2021-08

Reconsideration of Viscosity Variation Mechanism in Calcium Ferrite Melt During Isothermal Melting Process

Sohei Sukenaga, Koji Ohara, Hiroki Yamada, Toru Wakihara, Hiroyuki Shibata

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Abstract

Two hypotheses exist to explain the viscosity decrease mechanism of calcium ferrite (CF) melts during isothermal melting in air: variations in either the short-range structure near Fe3+ or the Fe redox state. Here, the synchrotron X-ray total scattering pattern of an aerodynamically levitated CF droplet was monitored during isothermal melting. No variations were observed in the short-range structure of the melt for 1800 seconds, indirectly suggesting that redox state variations dominate the viscosity.
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OpenAlex topics: Metallurgical Processes and Thermodynamics · nanoparticles nucleation surface interactions · Iron and Steelmaking Processes

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