journal article·2026-08

Surface passivation and structural stabilization of Ni-rich and Co-free single-crystal cathodes to improve high-voltage performance in sulfide solid-state batteries

Wengao Zhao, Yong Cheng, Zhengfeng Zhang, Fucheng Ren, Yuan Ma, Jing Lin, Yizhong Guo, Xing Ou, Leonhard Karger, Ruizhuo Zhang, Ziyan Zhang, Ming-Sheng Wang, Aleksandr Kondrakov, Yong Yang, Yu Tang, Torsten Brezesinski

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Extraction and Separation Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Building ultraconformal protective layers on both decondary and primary particles of layered lithium transition metal oxide cathodes10.1038/s41560-019-0387-1 ↗
2. A reflection on lithium-ion battery cathode chemistry10.1038/s41467-020-15355-0 ↗
3. Restraining planar gliding in single-crystalline LiNi0.9Co0.05Mn0.05O2 cathodes by combining bulk and surface modification strategies
4. Supramolecular interaction chemistry in polymer electrolytes towards stable lithium metal batteries10.1016/j.jechem.2025.03.025 ↗
5. Data-driven electrolyte design for advanced rechargeable lithium batteries10.1002/cjoc.70321 ↗
6. Understanding Co roles towards developing Co-free Ni-rich cathodes for rechargeable batteries10.1038/s41560-021-00776-y ↗
7. Crack-free single-crystalline Co-free Ni-rich LiNi0.95Mn0.05O2 layered cathode10.1016/j.esci.2022.02.006 ↗
8. Unraveling and suppression of multi-directional planar slipping and microcracking in single-crystal Co-free, Ni-rich cathodes10.1002/anie.202512232 ↗
9. Intrinsic weaknesses of Co-free Ni–Mn layered cathodes for electric vehicles10.1016/j.mattod.2022.03.005 ↗
10. Long-life lithium-ion batteries realized by low-Ni, Co-free cathode chemistry10.1038/s41560-023-01267-y ↗
11. Understanding the failure mechanism towards developing high-voltage single-crystal Ni-rich Co-free cathodes10.1016/j.gee.2022.11.006 ↗
12. High-entropy doping promising ultrahigh-Ni Co-free single-crystalline cathode toward commercializable high-energy lithium-ion batteries10.1126/sciadv.ado4472 ↗
13. Intralattice-bonded phase-engineered ultrahigh-Ni single-crystalline cathodes suppress strain evolution10.1038/s41560-025-01827-4 ↗
14. Facile solid-state synthesis of a layered Co-free, Ni-rich cathode material for all-solid-state batteries10.1039/D3CC03172A ↗
15. Cycling performance and limitations of LiNiO2 in solid-state batteries10.1021/acsenergylett.1c01447 ↗
16. Challenges in speeding up solid-state battery development10.1038/s41560-023-01208-9 ↗
17. Protective coating of single-crystalline Ni-rich cathode enables fast charging in all-solid-state batteries10.1021/acsnano.4c14322 ↗
18. Advanced nanoparticle coatings for stabilizing layered Ni-rich oxide cathodes in solid-state batteries
19. Waxing bare high-voltage cathode surfaces to enable sulfide solid-state batteries10.1021/acsenergylett.3c01717 ↗
20. Lithium metal anodes: advancing our mechanistic understanding of cycling phenomena in liquid and solid electrolytes10.1021/jacs.3c05715 ↗
21. Benchmarking the performance of all-solid-state lithium batteries10.1038/s41560-020-0565-1 ↗
22. A solid future for battery development10.1038/nenergy.2016.141 ↗
23. Fluorinated carbon nitride-assisted solvation-regulation engineering toward polyvinylidene fluoride-based electrolytes for long-lifespan solid-state lithium batteries10.1039/D5EE03323C ↗
24. Implanting non-lithiated metal into fluoride/nitride hybrid matrix enabling tailored lithium/garnet interface chemistry for durable solid-state lithium batteries10.1002/adfm.202512506 ↗
25. Electrochemo-mechanical effects of Co-free layered cathode on interfacial stability in all-solid-state batteries under high-voltage operation10.1039/D5EB00136F ↗
26. Tuning the lithium diffusion kinetics in Co-free layered cathodes for high-performance all-solid-state batteries10.1021/acsenergylett.5c00961 ↗
27. High-energy all-solid-state lithium batteries enabled by Co-free LiNiO2 cathodes with robust outside-in structures10.1038/s41565-023-01519-8 ↗
28. Computational screening of cathode coatings for solid-state batteries10.1016/j.joule.2019.02.006 ↗
29. LiNbO3-coated LiNi0.7Co0.1Mn0.2O2 and chlorine-rich argyrodite enabling high-performance solid-state batteries under different temperatures10.1016/j.ensm.2021.08.028 ↗
30. Cobalt-free cathodes and silicon thin-film anodes towards high-capacity solid-state batteries10.1016/j.est.2024.113329 ↗
31. In-depth analysis of the degradation mechanisms of high-nickel, low/no-cobalt layered oxide cathodes for lithium-ion batteries10.1002/aenm.202100858 ↗
32. High-nickel NMA: a cobalt-free alternative to NMC and NCA cathodes for lithium-ion batteries
33. Optimized Al doping improves both interphase stability and bulk structural integrity of Ni-rich NMC cathode materials10.1021/acsaem.9b02372 ↗
34. Constructing an oxyhalide interface for 4.8 V-tolerant high-nickel cathodes in all-solid-state lithium-ion batteries
35. Surface engineering strategy enables 4.5 V sulfide-based all-solid-state batteries with high cathode loading and long cycle life10.1021/acsenergylett.3c01047 ↗
36. Enabling high energy lithium metal batteries via single-crystal Ni-rich cathode material Co-doping strategy10.1038/s41467-022-30020-4 ↗
37. Correlation between long range and local structural changes in Ni-rich layered materials during charge and discharge process10.1016/j.jpowsour.2018.11.053 ↗
38. The origin of high-voltage stability in single-crystal layered Ni-rich cathode materials10.1002/anie.202207225 ↗
39. Stable cycling of high-voltage lithium metal batteries in ether electrolytes10.1038/s41560-018-0199-8 ↗
40. Quantifying degradation parameters of single-crystalline Ni-rich cathodes in lithium-ion batteries
41. Suppress moisture sensitivity of Ni-rich cathode materials by bioinspired self-assembly hydrophobic layer10.1016/j.cej.2023.146850 ↗
42. Surface regulation enables high stability of single-crystal lithium-ion cathodes at high voltage10.1038/s41467-020-16824-2 ↗
43. The working principle of a Li2CO3/LiNbO3 coating on NCM for thiophosphate-based all-solid-state batteries10.1021/acs.chemmater.0c04660 ↗
44. Electrochemical stability of Li10GeP2S12 and Li7La3Zr2O12 solid electrolytes10.1002/aenm.201501590 ↗
45. The nature and suppression strategies of interfacial reactions in all-solid-state batteries10.1039/D3EE00870C ↗
46. Extending the high-voltage operation of graphite/NCM811 cells by constructing a robust electrode/electrolyte interphase layer
47. (Electro)chemical expansion during cycling: monitoring the pressure changes in operating solid-state lithium batteries10.1039/C7TA02730C ↗
48. Tailoring the LiNbO3 coating of Ni-rich cathode materials for stable and high-performance all-solid-state batteries10.26599/NRE.2022.9120016 ↗
49. The interplay between (electro)chemical and (chemo)mechanical effects in the cycling performance of thiophosphate-based solid-state batteries10.1088/2752-5724/ac3897 ↗
50. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set10.1103/PhysRevB.54.11169 ↗
51. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
52. Improved adsorption energetics within density-functional theory using revised perdew-burke-ernzerhof functionals10.1103/PhysRevB.59.7413 ↗
53. The Li intercalation potential of LiMPO4 and LiMSiO4 olivines with M=Fe, Mn, Co, Ni10.1016/j.elecom.2004.09.007 ↗
54. Special points for brillouin-zone integrations10.1103/PhysRevB.13.5188 ↗
55. Python materials genomics (pymatgen): a robust, open-source python library for materials analysis10.1016/j.commatsci.2012.10.028 ↗