journal article·2026-08

Weakly coordinating co-solvent design of chlorine-free electrolytes: Manipulating solvation structure and interfacial chemistry for highly reversible Mg metal anodes

Qi Sun, Shaohua Luo, Rui Huang, Jun Cong, Shengxue Yan

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Recent progress of magnesium electrolytes for rechargeable magnesium batteries10.1016/j.ccr.2024.215956 ↗
2. Evolution of coordinated chemical innovations: a road to chlorine-free magnesium electrolyte system
3. Exploiting a high-performance magnesium-fluoride battery prototype enabled by anion-receptor-mediated electrolyte10.1038/s41467-026-68903-5 ↗
4. Directional migration of Mg2+ in hexagonal Se cathode to unlock high-energy-density Mg metal batteries
5. Surface engineering of a Mg electrode via a new additive to reduce overpotential10.1021/acsami.1c07648 ↗
6. In-situ electrochemical activation accelerates the magnesium-ion storage10.1038/s41467-025-56556-9 ↗
7. Probing the effect of the stoichiometric ratio of Mg(CF3SO3)2/AlCl3 on optimizing the electrolyte performance10.1080/14328917.2022.2085004 ↗
8. Constructing efficient Mg(CF3SO3)2 electrolyte via tailoring solvation and interface chemistry for high-performance rechargeable magnesium batteries
9. Deeping insight of Mg(CF3SO3)2 and comprehensive modified electrolyte with ionic liquid enabling high-performance magnesium batteries10.1016/j.nanoen.2023.108257 ↗
10. Tailoring coordination in conventional ether-based electrolytes for reversible magnesium-metal anodes
11. Highly efficient non-nucleophilic Mg(CF3SO3)2-based electrolyte for high-power Mg/S battery10.1021/acsami.0c00196 ↗
12. Highly active electrolytes for rechargeable Mg batteries based on a [Mg2(μ-Cl)2]2+ cation complex in dimethoxyethane10.1039/C5CP00859J ↗
13. Customizing vertical electrodeposition orientation and interfacial solvation to endow magnesium metal anodes with ultrahigh areal capacity10.1039/D5EE01011J ↗
14. Construction of fluoride-rich interphase for sustained magnesiophilic site release toward high-stability chloride-free magnesium metal batteries10.1002/aenm.202401507 ↗
15. Boosting Mg deposition and dissolution from ionic liquids – the role of different additives for applications in Mg-ion batteries10.1016/j.est.2024.114636 ↗
16. Regulating electric double layer via self-assembled monolayer for stable solid/electrolyte interphase on Mg metal anode
17. Synergistic electrolyte engineering with TEABH4 additive: achieving oriented deposition and ultralong cycling in magnesium metal batteries10.1039/D5QI00609K ↗
18. Chloride-free electrolyte based on tetrabutylammonium triflate additive for extended anodic stability in magnesium batteries10.1021/acs.nanolett.3c03740 ↗
19. Electrolyte additive enabling conditioning-free electrolytes for magnesium batteries10.1021/acsami.8b13588 ↗
20. High-entropy electrolyte enables High reversibility and long lifespan for magnesium metal anodes
21. Strong solvent coordination effect inducing gradient solid-electrolyte-interphase formation for highly efficient Mg plating/stripping
22. Optimizing interfacial process of Mg metal anode by porphyrin adsorption layer in Cl-free conventional electrolyte10.1016/j.cej.2023.148170 ↗
23. In situ formation of a Bi/Mg-based hybrid interphase for highly reversible magnesium metal anodes10.1002/adma.202502098 ↗
24. Multiwfn: a multifunctional wavefunction analyzer10.1002/jcc.22885 ↗
25. Dipole–dipole interactions for inhibiting solvent co-intercalation into a graphite anode to extend the horizon of electrolyte design10.1039/D2EE03626F ↗
26. Fluorobenzene, A low-density, economical, and bifunctional hydrocarbon cosolvent for practical lithium metal batteries10.1002/adfm.202005991 ↗
27. Tailoring solvation structures via precise diluent engineering for high-rate 500 wh kg−1 lithium-metal batteries10.1002/adma.202509109 ↗
28. Rejuvenating propylene carbonate-based electrolyte through nonsolvating interactions for wide-temperature Li-ions batteries
29. High active magnesium trifluoromethanesulfonate-based electrolytes for magnesium–sulfur batteries10.1021/acsami.8b20180 ↗
30. The origin of anode–electrolyte interfacial passivation in rechargeable Mg-metal batteries10.1039/D2EE03270H ↗
31. Solvation sheath reorganization enables divalent metal batteries with fast interfacial charge transfer kinetics10.1126/science.abg3954 ↗
32. Solvent molecule design enables excellent charge transfer kinetics for a magnesium metal anode10.1021/acsenergylett.2c02525 ↗
33. Reviving multivalent-metal anodes in simple salt electrolytes via component modifier design
34. Challenges and progress in rechargeable magnesium-ion batteries: materials, interfaces, and devices10.1002/adfm.202410406 ↗
35. Contact ion-pair-dominated electrolyte enabling inorganic-rich solid–electrolyte interphase for long-cycling magnesium metal anodes10.1021/acsenergylett.4c03504 ↗
36. Iodine boosted fluoro-organic borate electrolytes enabling fluent ion-conductive solid electrolyte interphase for high-performance magnesium metal batteries
37. Mg2+ solvation structures and diffusion properties in dimethoxyethane solutions using multimodal NMR analysis10.1149/MA2021-017415mtgabs ↗
38. The interfacial reactions of Mg battery anodes10.1016/j.jma.2025.04.031 ↗
39. Tailoring electrode–electrolyte interface using an electron-deficient borate-based additive in Mg(TFSI)2-MgCl2/DME electrolyte for rechargeable magnesium batteries10.1002/eem2.12792 ↗
40. Hybrid MgCl2/AlCl3/Mg(TFSI)2 electrolytes in DME enabling high-rate rechargeable Mg batteries10.1021/acsami.1c07567 ↗
41. Simultaneous optimization of solvation structure and water-resistant capability of MgCl2-based electrolyte using an additive combination of organic and inorganic lithium salts10.1016/j.ensm.2022.07.023 ↗
42. Dual-functional electrolyte additives to enhance magnesium plating/stripping performance for rechargeable magnesium metal batteries with pure amine solvents
43. Interphase self-optimization enables stable magnesium anode in hydrogel electrolyte
44. Breaking solvation dominance of ethylene carbonate via molecular charge engineering enables lower temperature battery10.1038/s41467-023-43163-9 ↗
45. High-voltage lithium-ion battery with a wide operating temperature range and fast-charging ability10.1039/D5EE05191F ↗
46. A universal fluorinated composite interphase with self-healing function enabling long-cycling rechargeable magnesium batteries
47. Co-regulating planar Mg deposition and bromine-rich Mg anode-electrolyte interface by multifunctional organic bromine additive10.1002/aenm.202500979 ↗
48. Regulating the interfacial solvation environment by a pyran-based polymer for high-areal-capacity and low-temperature-endurable magnesium metal batteries10.1021/acsnano.5c02206 ↗
49. A gradient structured SEI enabling record-high areal capacity anode for high-rate Mg metal batteries10.1016/j.cej.2023.148193 ↗
50. Building organic–inorganic robust interphases from deep eutectic solution for highly stable Mg metal anode in conventional electrolyte10.1002/smtd.202301109 ↗
51. Evolution and underlying mechanisms of MgH2 in amine-based electrolytes for magnesium metal batteries
52. Li+ additive accelerated structural transformation of MoS2 cathodes for performance-enhancing rechargeable Mg2+ batteries
53. Toward high-performance Mg/S batteries with M4-assisted Mg(AlCl4)2/PYR14TFSI/DME electrolyte and MoS2@CMK/S cathode