journal article·2025-12

Enthalpy-mediated local structural ordering stabilizes O3-type layered cathode for sodium-ion batteries

Yongcong Huang, Fangchang Zhang, Xin Xu, Yanfang Wang, Peisong Sun, Kuan Jing, Feng Wu, Zibing An, Xiaodong Han, Yulin Cao, Yan Liu, Xingqun Liao, Yingzhi Li, Zhenghe Xu, Zhouguang Lu

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advancements in Battery Materials · Semiconductor materials and devices · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Ternary-phase layered cathodes toward ultra-stable and high-rate sodium ion storage10.1007/s12598-023-02523-6 ↗
2. Lithium and niobium dual-mediated P2-layered cathode for low-temperature and ultralong lifespan sodium-ion batteries
3. K doping stabilizes three-dimensional K0.2Na1.3Mn0.5O2-δ as high-performance cathode for sodium-ion batteries10.1007/s12598-024-02814-6 ↗
4. Progress and perspective of Na1-δNixFeyMnzO2 cathode for high-energy-density and long-cycle-life sodium-ion batteries
5. Interfacial engineering of the layered oxide cathode materials for sodium-ion battery10.1007/s12274-023-6133-9 ↗
6. Study on the reversible electrode reaction of Na1–xNi0.5Mn0.5O2 for a rechargeable sodium-ion battery10.1021/ic300357d ↗
7. Understanding the capacity fading mechanisms of O3-type Na[Ni0.5Mn0.5]O2 cathode for sodium-ion batteries
8. In Operando XRD and TXM study on the metastable structure change of NaNi1/3Fe1/3Mn1/3O2 under electrochemical sodium-ion intercalation10.1002/aenm.201601306 ↗
9. A unique wide-spacing fence-type superstructure for robust high-voltage O3-type sodium layered cathode10.1002/anie.202404330 ↗
10. Decoupling the air sensitivity of Na-layered oxides
11. Fast Na+ kinetics and suppressed voltage hysteresis enabled by a high-entropy strategy for sodium oxide cathodes
12. Negative lattice expansion in an O3-type transition-metal oxide cathode for highly stable sodium-ion batteries
13. Tailoring planar strain for robust structural stability in high-entropy layered sodium oxide cathode materials10.1038/s41560-024-01616-5 ↗
14. Ti substitution facilitating oxygen oxidation in Na2/3Mg1/3Ti1/6Mn1/2O2 cathode10.1016/j.chempr.2019.08.003 ↗
15. Mitigating mechanical stress by the hierarchical crystalline domain for high-energy P2/O3 biphasic cathode materials10.1021/acsnano.4c09918 ↗
16. O3-Type Na0.95Ni0.40Fe0.15Mn0.3Ti0.15O2 cathode materials with enhanced storage stability for high-energy Na-ion batteries10.1021/acsami.3c02514 ↗
17. Negative enthalpy alloys and local chemical ordering: a concept and route leading to synergy of strength and ductility10.1093/nsr/nwae026 ↗
18. Negative mixing enthalpy solid solutions deliver high strength and ductility10.1038/s41586-023-06894-9 ↗
19. Negative enthalpy doping stabilizes P2-type oxides cathode for high-performance sodium-ion batteries
20. Zinc-doping strategy on P2-type Mn-based layered oxide cathode for high-performance potassium-ion batteries10.1002/smll.202302160 ↗
21. A novel Ni-rich O3-Na[Ni0.60Fe0.25Mn0.15]O2 cathode for Na-ion batteries10.1016/j.ensm.2020.05.013 ↗
22. Boron-doped high-entropy oxide toward high-rate and long-cycle layered cathodes for wide-temperature sodium-ion batteries10.1016/j.jechem.2024.03.055 ↗
23. A three-in-one strategy of high-entropy, single-crystal, and biphasic approaches to design O3-type layered cathodes for sodium-ion batteries
24. Influence of interlayer cation ordering on Na transport in P2-type Na0.67–xLiyNi0.33–zMn0.67+zO2 for sodium-ion batteries10.1021/jacs.4c00869 ↗
25. Long-range cationic disordering induces two distinct degradation pathways in Co-free Ni-rich layered cathodes
26. High-entropy Li-rich layered cathodes with negligible voltage decay through migration retardation effect10.1002/adma.202505189 ↗
27. Elucidating the structural evolution of O3-type NaNi1/3Fe1/3Mn1/3O2: a prototype cathode for Na-ion battery10.1021/jacs.4c11049 ↗
28. Enhancing the reversibility of lattice oxygen redox through modulated transition metal-oxygen covalency for layered battery electrodes10.1002/adma.202201152 ↗
29. Four-In-one strategy to boost the performance of Nax[Ni, Mn]O2
30. Rational design of high-entropy cathodes to optimize fast charging performance in sodium-ion batteries10.1002/adfm.202422106 ↗
31. A high-rate, durable cathode for sodium-ion batteries: sb-doped O3-type Ni/Mn-based layered oxides10.1021/acsnano.2c04702 ↗
32. Refining O3-type Ni/Mn-based sodium-ion battery cathodes via “Atomic knife” achieving high capacity and stability
33. In situ plastic-crystal-coated cathode toward high-performance Na-ion batteries10.1021/acsenergylett.3c00009 ↗
34. Regulating phase transition and restraining Fe distortion at high potential window via rare Earth metal incorporation on O3-type layered cathodes10.1002/adfm.202402398 ↗
35. Boron-doped sodium layered oxide for reversible oxygen redox reaction in Na-ion battery cathodes10.1038/s41467-021-25610-7 ↗
36. Halting oxygen evolution to achieve long cycle life in sodium layered cathodes
37. Regulating the local chemical environment in layered O3-NaNi0.5Mn0.5O2 achieves practicable cathode for sodium-ion batteries10.1016/j.ensm.2023.02.001 ↗
38. High-entropy Co-free O3-type layered oxyfluoride: a promising air-stable cathode for sodium-ion batteries10.1002/adma.202304440 ↗
39. Ribbon-ordered superlattice enables reversible anion redox and stable high-voltage Na-ion battery cathodes10.1021/jacs.4c02782 ↗
40. High-entropy and superstructure-stabilized layered oxide cathodes for sodium-ion batteries10.1002/aenm.202201989 ↗
41. High-entropy configuration regulating interlayer oxygen charge toward High-voltage and air-stability layered cathode in High-loading sodium ion full batteries10.1002/adfm.202500158 ↗
42. Enabling high-voltage and long lifespan sodium batteries via single-crystal layer-structured oxide cathode material10.1021/acsnano.4c15734 ↗
43. Regulation of coordination chemistry for ultrastable layered oxide cathode materials of sodium-ion batteries
44. Thermodynamically stable low-Na O3 cathode materials driven by intrinsically high ionic potential discrepancy10.1039/D4EE02359E ↗
45. Ultra-uniform interfacial matrix via high-temperature thermal shock for long-cycle stability cathodes of sodium-ion batteries10.1039/D5EE00217F ↗
46. Suppression of adverse phase transition of layered oxide cathode via local electronic structure regulation for high-capacity sodium-ion batteries10.1021/acsnano.4c04847 ↗
47. Phase transition induced cracking plaguing layered cathode for sodium-ion battery10.1016/j.nanoen.2018.09.073 ↗
48. Charge tuning and anchor effect achieving stable high-voltage layered metal oxides for sodium-ion battery10.1002/anie.202500715 ↗
49. Boosting electrochemical reaction and suppressing phase transition with a high-entropy O3-type layered oxide for sodium-ion batteries10.1039/D2TA02451A ↗
50. Inhomogeneous coordination in high-entropy O3-type cathodes enables suppressed slab gliding and durable sodium storage
51. Fast-charge high-voltage layered cathodes for sodium-ion batteries10.1038/s41893-024-01266-1 ↗
52. An O3-type oxide with low sodium content as the phase-transition-free anode for sodium-ion batteries10.1002/anie.201801923 ↗
53. Co-free layered oxide cathode material with stable anionic redox reaction for sodium-ion batteries10.1002/aenm.202301471 ↗
54. Impact of Ti and Zn dual-substitution in P2 type Na2/3Ni1/3Mn2/3O2 on Ni–Mn and Na-vacancy ordering and electrochemical properties10.1002/adma.202300714 ↗
55. High-energy earth-abundant cathodes with enhanced cationic/anionic redox for sustainable and long-lasting Na-ion batteries