journal article·2026-05

Precision functional group engineering in solid-state polymer electrolytes for lithium-metal batteries

Tianyou Lan, Yupeng Feng, Miao He, Wang Xu, Yang Yin, Yuhan Li, Fei Li, Wei Xiang, Jianping Long, Anjun Hu

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OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Inorganic Chemistry and Materials

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References (100+)

Show source-provided references
1. Metrics for evaluating safe electrolytes in energy-dense lithium batteries10.1038/s41560-025-01887-6 ↗
2. Electrolyte reduction on cathodes to enhance the performance of high-energy batteries10.1038/s41557-025-02009-1 ↗
3. Electrolyte evolution for flexible energy Storage systems: from liquid to solid, from rigid to soft, and from organic to aqueous10.1021/acs.chemrev.5c00036 ↗
4. Grain boundary zirconia-modified garnet solid-state electrolyte10.1038/s41563-025-02374-9 ↗
5. Ultrafast thermo-responsive electrolyte for enhanced safety in lithium metal batteries10.1038/s41560-025-01905-7 ↗
6. A ductile solid electrolyte interphase for solid-state batteries10.1038/s41586-025-09675-8 ↗
7. Polymer electrolytes for lithium-based batteries: advances and prospects10.1016/j.chempr.2019.05.009 ↗
8. From liquid to solid-State lithium metal batteries: fundamental issues and recent developments
9. Unified affinity paradigm for the rational design of high-efficiency lithium metal electrolytes10.1038/s41560-025-01842-5 ↗
10. Mechanisms of the accelerated Li+ conduction in MOF-based solid-State polymer electrolytes for all-solid-State lithium metal batteries10.1002/adma.202314120 ↗
11. Coaxially MXene-confined solid-state electrolyte for flexible high-rate lithium metal battery10.1016/j.nanoen.2024.109312 ↗
12. In situ polymerization of solid-state polymer electrolytes for lithium metal batteries: a review10.1039/D4EE00822G ↗
13. Liquid–liquid interfacial tension stabilized Li-metal batteries10.1038/s41586-025-09293-4 ↗
14. Polymer-based electrolytes for high-voltage solid-state lithium batteries10.20517/energymater.2023.130 ↗
15. Improved interfacial li-ion transport in composite polymer electrolytes via surface modification of LLZO10.20517/energymater.2024.195 ↗
16. Tri-functional molecular motif-engineered polymer electrolytes for high-voltage lithium metal batteries
17. Interface engineering of inorganic solid-state lithium batteries via atomic and molecular layer deposition10.1002/inf2.12650 ↗
18. Suppression of CO2 induced lithium anode corrosion by fluorinated functional group in quasi-solid polymer electrolyte enabling long-cycle and high-safety Li-CO2 batteries10.1016/j.ensm.2023.02.006 ↗
19. Conjugated topologically confined composite electrolytes for robust high-voltage and high-temperature semi-solid-state lithium metal batteries10.1039/D5EE04892C ↗
20. Super SEI-forming anion for enhanced interfacial stability in solid-State lithium metal batteries10.1002/adma.202410954 ↗
21. Dendrite-accelerated thermal runaway mechanisms of lithium metal pouch batteries10.1002/sus2.74 ↗
22. Synergistic effect of dual-functional groups in MOF-modified separators for efficient lithium-ion transport and polysulfide management of lithium-sulfur batteries10.1002/advs.202515034 ↗
23. Nitrile-based solid polymer electrolytes for novel energy storage systems: a perspective from ion transport mechanism to applications in solid-state batteries
24. Synergistic effect of crosslinked organic–Inorganic composite protective layer for high performance lithium metal batteries10.1002/adfm.202300980 ↗
25. Molecular design of difluorinated polyether electrolyte for ultrastable high-voltage all-solid-State lithium metal batteries10.1002/advs.202508721 ↗
26. Polymer electrolytes shielded by 2D Li0.46Mn0.77PS3 Li+-conductors for all-solid-state lithium-metal batteries10.1016/j.ensm.2023.01.011 ↗
27. Combined ion-expressway and Li+-transit lane in asymmetric polymer electrolyte enables high-voltage solid-State lithium-metal-batteries10.1002/aenm.202505169 ↗
28. Advanced ether-based electrolytes for lithium-ion batteries10.1002/aenm.202401526 ↗
29. High-concentration ether electrolytes for stable High-voltage lithium metal batteries10.1021/acsenergylett.9b00381 ↗
30. Stabilizing residual monomers within In situ polymerized electrolytes for high-voltage lithium metal batteries10.1021/jacs.5c03911 ↗
31. Soft/hard interface design of bismuth nanodots embedded in Ti3C2Tx MXene for highly efficient dechlorination battery deionization10.1016/j.desal.2025.119183 ↗
32. In situ polymerized 1,3-dioxolane electrolyte for integrated solid-State lithium batteries10.1002/anie.202218621 ↗
33. In situ polymerization of 1,3-dioxane as a highly compatible polymer electrolyte to enable the stable operation of 4.5 V Li-metal batteries10.1039/D3EE02797J ↗
34. 10 μm-thick high-strength solid polymer electrolytes with excellent interface compatibility for flexible all-solid-State lithium-metal batteries10.1002/adma.202100353 ↗
35. Regulating anions in the solvation sheath of lithium ions for stable lithium metal batteries10.1021/acsenergylett.8b02376 ↗
36. Structural batteries: advances, challenges and perspectives10.1016/j.mattod.2022.12.001 ↗
37. Customizable solid-state batteries toward shape-conformal and structural power supplies10.1016/j.mattod.2022.06.007 ↗
38. Ionic conductivity in crystalline polymer electrolytes10.1038/35087538 ↗
39. Channel microenvironment-controlled pillared MOF as efficient triboelectric nanogenerator material for self-powered degradation of organic pollutants
40. Critical current densities for high-performance all-solid-State Li-metal batteries: fundamentals, mechanisms, interfaces, materials, and applications10.1021/acsenergylett.2c00003 ↗
41. Advances in application of sustainable lignocellulosic materials for high-performance aqueous zinc-ion batteries10.1016/j.nanoen.2024.109416 ↗
42. Yolk–shell nanoreactors with dual confinement and catalysis for high-performance lithium−sulfur batteries10.1002/cnl2.70101 ↗
43. Promising routes to a high Li+ transference number electrolyte for lithium ion batteries10.1021/acsenergylett.7b00792 ↗
44. Single lithium-ion conducting solid polymer electrolytes: advances and perspectives10.1039/C6CS00491A ↗
45. Developing single-ion conductive polymer electrolytes for high-energy-density solid State batteries10.1002/adfm.202305072 ↗
46. Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives10.1039/c0cs00081g ↗
47. Understanding the electrochemical window of solid-State electrolyte in full battery application10.1021/acs.chemrev.4c01012 ↗
48. The Li-ion rechargeable battery: a perspective10.1021/ja3091438 ↗
49. Expanding the electrochemical stability window: unraveling the role of solvent polarity and a WiSE-compatible strategy10.1021/jacs.5c04782 ↗
50. Achieving high-energy and high-safety lithium metal batteries with high-voltage-stable solid electrolytes10.1016/j.matt.2023.02.012 ↗
51. Research advances in interface engineering of solid-State lithium batteries10.1002/cnl2.188 ↗
52. Cryogenic X-ray photoelectron spectroscopy for battery interfaces10.1038/s41586-025-09618-3 ↗
53. The contrast between monovalent and multivalent metal battery anodes10.1126/science.adl5482 ↗
54. Stabilizing metal battery anodes through the design of solid electrolyte interphases10.1016/j.joule.2021.03.024 ↗
55. Ionization-targeted modulation enables fast-charging and high-temperature lithium-metal batteries10.1002/adfm.202513437 ↗
56. Constructing LiF-rich interfaces via lithiophobic dilution-induced solvation reconstruction for stable lithium metal batteries10.1016/j.jechem.2025.11.038 ↗
57. The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium10.1073/pnas.1911017116 ↗
58. Reallocation of active lithium by regulating electrochemical structural connectivity in anode-free lithium metal batteries10.1002/inf2.70067 ↗
59. Interphase design for lithium-metal anodes10.1021/jacs.4c15759 ↗
60. Dynamic evolution of cathode-electrolyte interphase in lithium metal batteries with ether electrolytes10.1016/j.joule.2025.101885 ↗
61. Assessing cathode–electrolyte interphases in batteries10.1038/s41560-024-01639-y ↗
62. Single-molecule dual-anchor design enables extreme-condition lithium metal batteries through solvation reconstruction and cathode polymerization10.1002/anie.202513321 ↗
63. Mesomorphic ceramic film fabricated via blade coating of a lyotropic nematic liquid crystal for high-power lasers10.1021/acsanm.2c01624 ↗
64. Tuning surface reconfiguration for durable cathode/electrolyte interphase of LiCoO2 at 45°C10.1002/aenm.202402223 ↗
65. Residual monomer-induced side reactions in gel polymer electrolytes: unveiled high-Ni cathode failure in lithium batteries10.1002/anie.202424568 ↗
66. Assessing cathode–electrolyte interphases in batteries. Nature energy.
67. Filler-integrated composite polymer electrolyte for solid-State lithium batteries10.1002/adma.202110423 ↗
68. A review of functional group selection and design strategies for gel polymer electrolytes for metal batteries10.1016/j.mser.2025.100973 ↗
69. Pseudo-trapezoidal fast factorized backprojection algorithm for near-field sparse MIMO array 3-D imaging10.1109/TAES.2025.3580015 ↗
70. Helical counter-directional migration-induced solvation sheaths for constructing reinforced electrode–electrolyte interphases for ultra-stable anode-free lithium metal batteries10.1039/D5EE06208J ↗
71. 3D-Printed pentahedral polarization-division transmissive metadevice with versatile wavefronts
72. Mechanically reinforced pseudosolid polyelectrolyte membranes via layer-by-layer assembly for high-performing lithium-metal batteries10.1002/adfm.202413966 ↗
73. An artificial hybrid interphase for an ultrahigh-rate and practical lithium metal anode10.1039/D1EE00508A ↗
74. When short-circuits fall short: the thermal consequences of lithium metal internal short-circuits10.1021/acsenergylett.5c01611 ↗
75. Unlocking the failure mechanism of solid State lithium metal batteries10.1002/aenm.202100748 ↗
76. Determining the limiting factor of the electrochemical stability window for PEO-based solid polymer electrolytes: main chain or terminal –OH group?10.1039/D0EE00342E ↗
77. Cell design for practical high-energy lithium metal battery10.1002/adfm.202511087 ↗
78. Design of composite coal reducing agents for cost reduction and efficiency enhancement in industrial silicon smelting: correlation mechanism between carbon structure evolution and resistivity10.1016/j.jaap.2026.107779 ↗
79. Fluorinating solid electrolyte interphase by regulating polymer–solvent interaction in lithium metal batteries
80. In situ dual crosslinked composite quasi-solid electrolytes enable multiple continuous ion transport channels for ultra-long cycle and high load lithium metal batteries10.1002/aenm.202501350 ↗
81. Li+-migration influencing factors and non-destructive life extension of quasi-solid-state polymer electrolytes10.1038/s41467-025-59020-w ↗
82. In situ polymerization of solid-state polymer electrolytes for lithium metal batteries: a review10.1039/D4EE00822G ↗
83. Unveiling the critical role of ion coordination configuration of ether electrolytes for high voltage lithium metal batteries10.1002/anie.202219310 ↗
84. Weakening lithium-ion coordination in poly(Ethylene Oxide)-based solid polymer electrolytes for high performance solid-State batteries10.1002/aenm.202405906 ↗
85. Regulating the solvation structure in polymer electrolytes for high-voltage lithium metal batteries10.1002/anie.202405802 ↗
86. Synergistic combination of ether-linkage and polymer-in-salt for electrolytes with facile Li+ conducting and high stability in solid-state lithium batteries
87. Ether-oxygen segment design and solvation structure regulation enabling in-situ copolymerized quasi-solid electrolyte for high-performance lithium metal battery10.1016/j.jechem.2025.07.068 ↗
88. Gene-editing” design upgrades eutectic-polymer electrolytes with ultra-high Li+ conductivity10.1002/anie.202508857 ↗
89. Polymer-ion interaction prompted quasi-solid electrolyte for room-temperature high-performance lithium-ion batteries10.1002/adma.202409838 ↗
90. Poly(vinyl butyrate) esters as stable polymer matrix for solid-State Li-metal batteries10.1021/acsenergylett.4c02527 ↗
91. In situ formed poly(ester-alt-acetal) electrolytes with high oxidation potential and electrode–Electrolyte interface stability10.1021/acsenergylett.3c01597 ↗
92. Influencing factors on Li-ion conductivity and interfacial stability of solid polymer electrolytes, exampled by polycarbonates, polyoxalates and polymalonates10.1002/anie.202218229 ↗
93. Ultrathin polymer electrolyte with fast ion transport and stable interface for practical solid-state lithium metal batteries10.1002/adma.202510376 ↗
94. Fluoroethylene carbonate-enabled gel polymer electrolyte for stable high-voltage lithium metal batteries10.1002/adma.202502076 ↗
95. Carbonyl-engineered acrylate-based solid polymer electrolyte for high-performance lithium metal batteries10.1002/aenm.202502815 ↗
96. Designing better electrolytes10.1126/science.abq3750 ↗
97. Formulating the electrolyte towards high-energy and safe rechargeable lithium–Metal batteries10.1002/anie.202103850 ↗
98. Anchoring side chains to carbonate groups for reviving stable polycarbonate-based solid-State lithium metal batteries10.1021/jacs.5c00760 ↗
99. Molecular design for In-situ polymerized solid polymer electrolytes enabling stable cycling of lithium metal batteries10.1002/aenm.202400428 ↗
100. Solvation-interphase synergistic regulation empowering high-temperature and fast-charging lithium metal batteries10.1016/j.jechem.2025.09.001 ↗