Unlocking the potential of lignin for sodium-ion battery anodes: From biorefining to hard carbon engineering
Source abstract
Abstract
The rising demand for sustainable and cost-effective energy storage solutions has intensified interest in sodium-ion batteries (SIBs) as a promising alternative to lithium-ion batteries (LIBs). Among potential anode materials, hard carbon (HC) offers advantageous sodium storage characteristics, with lignin emerging as a highly sustainable and economical precursor due to its abundance, high carbon yield, aromatic structure and tuneable physicochemical properties. This review comprehensively addresses the latest advancements in lignin-derived HC for SIBs. Initially, the overview of SIBs and different types of anode materials is outlined and subsequently, the structural properties of HC and mechanisms of sodium storage are systematically presented. Following the introduction of various precursors for HC, the significance of lignin structure and extraction methods is discussed, emphasizing the benefits of utilizing lignin for HC production and various advanced synthesis approaches. Challenges associated with lignin-based HC are then discussed alongside opportunities for material engineering, including morphological design, microstructural property regulation, heteroatom doping and functional group modification, are comprehensively elaborated. Finally, the review outlines future perspectives and identifies pathways to unlock the full potential of lignin-derived HC as high-performance and sustainable anodes for next-generation SIB technology.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Catalysis for Biomass Conversion · Supercapacitor Materials and Fabrication · Lignin and Wood Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Renewable energy potential towards attainment of net-zero energy buildings status–a critical review10.1016/j.jclepro.2023.136942 ↗
2. Rice husk lignin-derived porous carbon anode material for lithium-ion batteries10.1002/slct.201900401 ↗
3. Lignin-based materials for sustainable rechargeable batteries10.3390/polym14040673 ↗
4. Rechargeable batteries: technological advancement, challenges, current and emerging applications10.1016/j.energy.2022.126408 ↗
5. S.R. Department, Average lithium carbonate price from 2010 to 2023, 2024. https://www.statista.com/statistics/606350/battery-grade-lithium-carbonate-price/. (Accessed 28.02.2025).
6. Sodium-ion batteries: present and future10.1039/C6CS00776G ↗
7. Sodium-ion batteries10.1002/adfm.201200691 ↗
8. Hard carbon anodes for sodium-ion batteries: dependence of the microstructure and performance on the molecular structure of lignin10.1016/j.jpowsour.2023.233475 ↗
9. Lignin: recent advances and emerging applications10.1016/j.cocis.2014.08.004 ↗
10. Molecular-scale controllable conversion of biopolymers into hard carbons towards lithium and sodium ion batteries: a review10.1016/j.jechem.2022.05.006 ↗
11. Valorizing low cost and renewable lignin as hard carbon for Na-ion batteries: impact of lignin grade10.1016/j.carbon.2019.07.026 ↗
12. Pretreatment for biorefineries: a review of common methods for efficient utilisation of lignocellulosic materials10.1186/s13068-019-1634-1 ↗
13. Lignin-derived advanced carbon materials10.1002/cssc.201500692 ↗
14. The catalytic valorization of lignin for the production of renewable chemicals10.1021/cr900354u ↗
15. Advances in carbon materials for sodium and potassium storage10.1002/adfm.202203117 ↗
16. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage10.1039/c3ee40847g ↗
17. Recent advances on sodium-ion batteries and sodium dual-ion batteries: state-of-the-art Na+ host anode materials10.1002/smsc.202100014 ↗
18. Plant-derived hard carbon as anode for sodium-ion batteries: a comprehensive review to guide interdisciplinary research10.1016/j.cej.2022.137468 ↗
19. The progress of cobalt-based anode materials for lithium ion batteries and sodium ion batteries10.3390/app10093098 ↗
20. Research development on sodium-ion batteries10.1021/cr500192f ↗
21. Progress towards efficient phosphate-based materials for sodium-ion batteries in electrochemical energy storage10.1007/s11581-023-04936-w ↗
22. Sodium-ion batteries: applications and properties10.3390/batteries11020061 ↗
23. Unleashing the potential of sodium-ion batteries: current State and future directions for sustainable energy storage
24. Toward reliable values of electrochemical stability limits for electrolytes10.1149/1.1392609 ↗
25. Linden · Handbook of batteries, Fuel and energy abstracts · 1995 · 265
26. Advances of lithium-ion batteries anode materials—A review10.1016/j.ceja.2023.100569 ↗
27. Recent status, key strategies, and challenging prospects for fast charging silicon-based anodes for lithium-ion batteries10.1016/j.carbon.2024.119615 ↗
28. Prospects in anode materials for sodium ion batteries-A review10.1016/j.rser.2019.109549 ↗
29. Wu · 2015
30. A review on biomass-derived hard carbon materials for sodium-ion batteries10.1039/D1MA00315A ↗
31. Probing the mechanism of sodium ion insertion into copper antimony Cu2Sb anodes10.1021/jp501032d ↗
32. High capacity, reversible alloying reactions in SnSb/C nanocomposites for Na-ion battery applications10.1039/c2cc17129e ↗
33. Iron phosphide as negative electrode material for Na-ion batteries10.1016/j.elecom.2016.05.005 ↗
34. Extraordinary performance of carbon-coated anatase TiO2 as sodium-ion anode10.1002/aenm.201501489 ↗
35. 3D porous γ-Fe2O3@ C nanocomposite as high-performance anode material of Na-ion batteries10.1002/aenm.201401123 ↗
36. A review of carbon materials and their composites with alloy metals for sodium ion battery anodes10.1016/j.carbon.2015.09.091 ↗
37. Carbon anode materials for advanced sodium-ion batteries10.1002/aenm.201602898 ↗
38. Structural design of anode materials for sodium-ion batteries10.1039/C7TA10823K ↗
39. Recent development on anodes for Na-ion batteries10.1002/ijch.201400118 ↗
40. Hard-carbon anodes for sodium-ion batteries: recent status and challenging perspectives
41. Hard carbon anodes for next-generation Li-ion batteries: review and perspective10.1002/aenm.202101650 ↗
42. Carbon electrodes for K-ion batteries10.1021/jacs.5b06809 ↗
43. Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors10.1016/j.elecom.2015.09.002 ↗
44. Graphitic carbon materials for advanced sodium-ion batteries10.1002/smtd.201800227 ↗
45. Slope-dominated carbon anode with high specific capacity and superior rate capability for high safety Na-ion batteries10.1002/anie.201900005 ↗
46. Advanced sodium-ion batteries using superior low cost pyrolyzed anthracite anode: towards practical applications10.1016/j.ensm.2016.07.006 ↗
47. Hard carbon as sodium-ion battery anodes: progress and challenges10.1002/cssc.201801879 ↗
48. Hard carbon anodes: fundamental understanding and commercial perspectives for Na-ion batteries beyond Li-ion and K-ion counterparts10.1002/aenm.202002704 ↗
49. Structural analysis of sucrose-derived hard carbon and correlation with the electrochemical properties for lithium, sodium, and potassium insertion10.1021/acs.chemmater.9b05235 ↗
50. High capacity anode materials for rechargeable sodium-ion batteries10.1149/1.1393348 ↗
51. Hard carbons for sodium-ion batteries: structure, analysis, sustainability, and electrochemistry10.1016/j.mattod.2018.12.040 ↗
52. From charge storage mechanism to performance: a roadmap toward high specific energy sodium-ion batteries through carbon anode optimization10.1002/aenm.201703268 ↗
53. Intergrowth of graphite-like crystals in hard carbon for highly reversible Na-ion storage10.1002/adfm.202106980 ↗
54. A SAXS outlook on disordered carbonaceous materials for electrochemical energy storage10.1016/j.ensm.2019.05.007 ↗
55. Tuning microstructures of hard carbon for high capacity and rate sodium storage10.1016/j.cej.2020.128104 ↗
56. Carbon anodes for nonaqueous alkali metal-ion batteries and their thermal safety aspects10.1002/aenm.201900550 ↗
57. Rational design of carbon nanomaterials for electrochemical sodium storage and capture
58. Recent progress in hard carbon anodes for sodium-ion batteries
59. Predicting capacity of hard carbon anodes in sodium-ion batteries using porosity measurements10.1016/j.carbon.2014.04.064 ↗
60. In situ observation of solid electrolyte interphase formation in ordered mesoporous hard carbon by small-angle neutron scattering10.1021/jp3012393 ↗
61. Revealing sodium ion storage mechanism in hard carbon10.1016/j.carbon.2018.12.112 ↗
62. Recent advances of tailoring defects and pores in hard carbon for sodium storage10.1016/j.mtener.2024.101501 ↗
63. Fullerene-like models for microporous carbon10.1007/s10853-012-6788-1 ↗
64. Phosphorus-doped porous biomass carbon with ultra-stable performance in sodium storage and lithium storage10.1016/j.electacta.2019.134698 ↗
65. Defects in hard carbon: where are they located and how does the location affect alkaline metal storage?10.1002/smll.202007652 ↗
66. Role of defects, pores, and interfaces in deciphering the Alkali metal storage mechanism in hard carbon10.1021/acsaem.2c02591 ↗
67. Heteroatom-doped carbon materials: synthesis, mechanism, and application for sodium-ion batteries10.1002/smtd.201800323 ↗
68. Reconfiguring hard carbons with emerging sodium-ion batteries: a perspective
69. Sodium ion insertion in hollow carbon nanowires for battery applications10.1021/nl3016957 ↗
70. Boost sodium-ion batteries to commercialization: strategies to enhance initial coulombic efficiency of hard carbon anode10.1016/j.nanoen.2020.105738 ↗
71. Understanding of sodium storage mechanism in hard carbons: ongoing development under debate10.1002/aenm.202200715 ↗
72. The mechanisms of lithium and sodium insertion in carbon materials10.1149/1.1379565 ↗
73. An in situ small-angle X-ray scattering study of sodium insertion into a nanoporous carbon anode material within an operating electrochemical cell10.1149/1.1394081 ↗
74. Tracking sodium cluster dynamics in hard carbon with a low specific surface area for sodium-ion batteries10.1002/aenm.202304300 ↗
75. Influence of hard carbon materials structure on the performance of sodium-ion batteries10.1021/acs.energyfuels.3c02406 ↗
76. Precursor screening of fruit shell derived hard carbons for low-potential sodium storage: a low lignin content supports the formation of closed pores10.1016/j.carbon.2024.119038 ↗
77. Fabrication of lignin-derived high-rate hard carbon anodes for sodium-ion batteries10.1016/j.ces.2025.122343 ↗
78. Carbon nanosheet frameworks derived from peat moss as high performance sodium ion battery anodes10.1021/nn404640c ↗
79. Mechanism of Na-ion storage in hard carbon anodes revealed by heteroatom doping10.1002/aenm.201602894 ↗
80. Extended plateau capacity of phosphorus-doped hard carbon used as an anode in Na-and K-ion batteries10.1016/j.cej.2019.123576 ↗
81. Correlation between microstructure and Na storage behavior in hard carbon10.1002/aenm.201501588 ↗
82. Hard carbon microtubes made from renewable cotton as high-performance anode material for sodium-ion batteries10.1002/aenm.201600659 ↗
83. Elucidation of the sodium-storage mechanism in hard carbons10.1002/aenm.201703217 ↗
84. Elucidation of the sodium-ion storage behaviors in hard carbon anodes through pore architecture engineering10.1021/acsnano.5c03700 ↗
85. New mechanistic insights on Na-ion storage in nongraphitizable carbon10.1021/acs.nanolett.5b01969 ↗
86. Mechanism of sodium storage in hard carbon: an X-ray scattering analysis10.1002/aenm.201903176 ↗
87. Improved sodium storage performance via regulating surface oxygen containing functional groups and microstructure of lignin-derived hard carbon10.1016/j.est.2024.114969 ↗
88. Free radicals trigger the closure of open pores in lignin-derived hard carbons toward improved sodium-storage capacity10.1016/j.jechem.2024.02.048 ↗
89. New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores10.1016/j.cclet.2023.109266 ↗
90. Self-activated micropores tailor carbon layer stacking and graphitic microstructures for high-performance sodium storage
91. High performance sulphur-doped pitch-based carbon materials as anode materials for sodium-ion batteries10.1016/S1872-5805(20)60499-1 ↗
92. Retarding graphitization of soft carbon precursor: from fusion-state to solid-state carbonization10.1016/j.ensm.2019.11.031 ↗
93. C.d.M.S. Rios, A. Beda, L. Simonin, C.M. Ghimbeu, Hard carbon for Na-ion batteries: from synthesis to performance and storage mechanism, 2021.
94. A high-performance hard carbon for Li-ion batteries and supercapacitors application10.1016/j.jpowsour.2012.09.047 ↗
95. Hierarchical porous hard carbon derived from rice husks for high-performance sodium ion storage10.1016/j.colsurfa.2023.130927 ↗
96. Ultra-stable sodium ion storage of biomass porous carbon derived from sugarcane10.1016/j.cej.2022.136344 ↗
97. High-density sodium and lithium ion battery anodes from banana peels10.1021/nn502045y ↗
98. Peanut shell derived hard carbon as ultralong cycling anodes for lithium and sodium batteries10.1016/j.electacta.2015.07.059 ↗
99. Tailored carbon anodes derived from biomass for sodium-ion storage10.1021/acssuschemeng.7b01497 ↗
100. Recent advances in biomass-derived carbon materials for sodium-ion energy storage devices10.3390/nano12060930 ↗