Effect of the Glycine Treatment on Synthesis and Physicochemical Characteristics of Nanosized Ni-Mn Mixed Oxides
Source abstract
Abstract
Magnetic Ni-Mn mixed oxides based on nanoparticles (NPs) have been developed at 700 °C using a ceramic method and a glycine-assisted auto combustion path. The thermogravimetry–derivative thermogravimetry (TG—DTG), infrared radiation (IR), X-ray powder diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX) and high resolution transmittance electron micrographs (HRTEM) techniques have been used to characterize as synthesized nanomaterials by evaluating their thermal behavior, structure, distinguishing the components and establishing the morphology. A vibrating sample magnetometer has been used to estimate the magnetic properties of the materials (VSM). The analyses indicate that using a glycine-assisted auto combustion method resulted in formation of cubic spinel NiMn2O4 NPs as a single phase. The ceramic process, from the other side, led to the development of Mn2O3/NiMnO3/NiMn2O4 nanocomposite. The resulting particles being polycrystalline, including average sizes ranging from 10 to 80 nanometers. The prepared NiMn2O4 NPs showed room-temperature ferromagnetism, with an optimal saturation magnetization value of 5.0216 emu/g, according to the magnetic measurement.
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Research context
OpenAlex topics: Electrical and Thermal Properties of Materials · Transition Metal Oxide Nanomaterials · Magnetic Properties and Synthesis of Ferrites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia
Physics and Astronomy Department, Science College, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
Physics Division, Electron Microscope and Thin Films Department, National Research Centre, El Behooth St., Giza 12622, Egypt
Physical Chemistry Department, National Research Centre, Dokki, El Behooth St., Giza 12622, Egypt
Funding
Princes Nourah Bint Abdulrahman University
References (50)
Show source-provided references
1. Novel Preparation and Physicochemical Characterization of a Nanocrystalline Cobalt Ferrite System10.1260/0263-6174.27.8.797 ↗
2. Tailoring the Physicochemical and Magnetic Properties of an Mn Substituted Cobalt Ferrite System
3. Nanostructured CuCo2O4 cathode for intermediate temperature solid oxide fuel cells via an impregnation technique10.1016/j.jpowsour.2017.01.053 ↗
4. Oxygen evolution reaction on Ni-substituted Co3O4 nanowire array electrodes10.1016/j.ijhydene.2010.09.056 ↗
5. Microstructure and phase development in NiMn2O4 spinel ceramics during isothermal sintering10.1016/0955-2219(90)90002-W ↗
6. Small polaron hopping in spinel manganates10.1103/PhysRevB.72.115101 ↗
7. Preparation and characterization of single-phase NiMn2O4 NTC ceramics by two-step sintering method10.1007/s10854-017-6361-4 ↗
8. Tsuda, N., Nasu, K., Fujimori, A., and Siratori, K. (2000). Electronic Conduction in Oxides, Springer. [2nd ed.].10.1007/978-3-662-04011-9 ↗
9. NiMn2O4 as an efficient cathode catalyst for rechargeable lithium–air batteries10.1039/C7CC01995E ↗
10. Electrical conductivity and cation valencies in nickel manganite10.1002/pssa.2210690132 ↗
11. Interaction between the d shells in the transition metals10.1103/PhysRev.81.440 ↗
12. Negative temperature coefficient resistance (NTCR) ceramic thermistors: An industrial perspective10.1111/j.1551-2916.2009.02990.x ↗
13. Nanocrystalline AMn2O4 (A = Co, Ni, Cu) spinels for remediation of volatile organic compounds—Synthesis, characterization and catalytic performance10.1016/j.ceramint.2011.09.057 ↗
14. Modified magnetic ground state in NiMn2O4 thin films10.1103/PhysRevB.82.144419 ↗
15. Sintering of soft magnetic material under microwave magnetic field
16. Hierarchical NiMn2O4@CNT nanocomposites for high-performance asymmetric supercapacitors10.1039/C5RA00979K ↗
17. Synthesis, characterization and physicochemical properties of nanosized Zn/Mn oxides system10.1016/j.jallcom.2010.04.180 ↗
18. Preparation and characterization of NiMn2O4 films10.1016/S1466-6049(01)00131-3 ↗
19. Magnetic properties of spinel-type oxides NiMn2−xMexO410.4067/S0717-97072005000300016 ↗
20. Preparation and sintering behaviour of spinel-type CoxNiMn2−xO4(0.2 ≤ x ≤ 1.2) by the ethylene glycol–metal nitrate polymerized complex process
21. Deraz, N.M., Abd-Elkader, O.H., and Yassin, M. (2020). Impacts of egg white assisted combustion and ceramic methods on structural, morphological and magnetic properties of Nickel Manganite system. Crystals, 10.10.3390/cryst10060489 ↗
22. Cullity, B.D. (1976). Elements of X-Ray Diffraction, Addison-Wesly Publishing Co. Inc.
23. Sánchez-España, J., and Yusta, I. (2019). Coprecipitation of Co2+, Ni2+ and Zn2+ with Mn(III/IV) Oxides Formed in Metal-Rich Mine Waters. Minerals, 9.10.3390/min9040226 ↗
24. First-principles study of electronic structure and photocatalytic properties of MnNiO3 as an alkaline oxygen-evolution photocatalyst10.1039/C4CC08111K ↗
25. Preparation and catalytic activity of nickel–manganese oxide catalysts in the reaction of partial oxidation of methane10.1016/j.crci.2008.12.002 ↗
26. Infrared Spectra of Ferrites10.1103/PhysRev.99.1727 ↗
27. Structural and electrical properties of Ni1−xMgxFe2O4 synthesized by citrate gel process10.1016/j.jmmm.2004.01.073 ↗
28. Nakamoto, K. (1986). Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley and Sons, Ltd.
29. Hydrothermal synthesis and nanostructure of carbonated calcium hydroxyapatite10.1007/s10856-006-8937-z ↗
30. Graphene synthesis via hydrogen induced low temperature exfoliation of graphite oxide10.1039/c0jm01876g ↗
31. FT-Raman and FT-IR spectroscopic study of synthetic Mg/Zn/Al-hydrotalcites10.1002/jrs.1244 ↗
32. Solid-phase equilibria in the system NiO-Mn2O3-O210.1016/0022-1902(64)80116-0 ↗
33. Synthesis and Characterization of Structural and Electrical Properties of Mg0.25xCu0.25xZn1−0.5xFe2O4 Ferrites by sol Gel Method10.15407/ujpe64.9.861 ↗
34. Optimization of catalytic, surface and magnetic properties of nanocrystalline manganese ferrite10.1016/j.jaap.2009.05.005 ↗
35. Coprecipitation mechanisms and products in manganese oxidation in the presence of cadmium
36. Structural, morphological and magnetic properties of NiFe2O4 nano-particles10.1016/j.jallcom.2009.06.192 ↗
37. Electrical conductivity and cation distribution in nickel manganite10.1016/0022-3697(86)90074-0 ↗
38. Structural, electrical and X-ray spectroscopic investigations of MnNi2O4 spinel10.1088/0022-3719/15/5/009 ↗
39. Preparation and electrical properties of nickel manganite Ni0.79Mn2.21O4 ceramics for NTC thermistors
40. On surface stress and surface tension: II. Determination of the surface stress of gold10.1016/0039-6028(68)90119-2 ↗
41. Lattice relaxation of monosize CeO2−x nanocrystalline particles10.1016/S0169-4332(99)00298-6 ↗
42. Origin of anomalous lattice expansion in oxide nanoparticles10.1103/PhysRevLett.85.3440 ↗
43. Nanostructured ceria-based materials: Synthesis, properties, and applications10.1039/c2ee22310d ↗
44. Shape-selective synthesis and oxygen storage behavior of ceria nanopolyhedra, nanorods, and nanocubes10.1021/jp055584b ↗
45. Investigation of size dependency on lattice strain of nanoceria particles synthesized by wet chemical methods10.1007/s40089-014-0122-7 ↗
46. Oxygen stoichiometry effects in spinel-type NiMn2O4−δ samples10.1016/j.jpcs.2005.03.001 ↗
47. Magnetic phase transition and physical properties of spinel-type nickel manganese oxide10.1016/S0022-3697(02)00017-3 ↗
48. Structural, electrical and magnetic properties of nickel manganite obtained by a complex polymerization method10.1016/j.ceramint.2014.07.024 ↗
49. Antiferromagnetic Arrangements in Ferrites10.1103/PhysRev.87.290 ↗
50. Magnetocaloric effect in perovskite manganites La0.7−xNdxCa0.3MnO3 and La0.7Ca0.3MnO310.1016/S0304-8853(00)00582-5 ↗