Exploring the Effect of Temperature on a Mechanochemical Reaction by in Situ Synchrotron Powder X-ray Diffraction
Source abstract
Abstract
We describe the first in situ and real-time study of a mechanochemical reaction by variable-temperature synchrotron powder X-ray diffraction. Using the dry milling synthesis of a coordination polymer as a model system, we reveal a change in reaction mechanism if temperature is increased, and a strong dependence of the reaction rate on temperature, with a ca. 6-fold increase of the rate of reactant depletion for a 45 °C rise in temperature. These experiments provide also the first direct evidence how a formally dry milling reaction is facilitated by water released from a hydrated reactant.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: X-ray Diffraction in Crystallography · Crystallography and molecular interactions · High-pressure geophysics and materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Ruđer Bošković Institute, Bijenička cesta 54, HR-10000, Zagreb, Croatia
Department of Chemistry and FRQNT Centre for Green Chemistry and Catalysis, McGill University, Montreal, H3A 0B8 Canada
Funding
NSERC Discovery Grant, the FRQNT Nouveaux Chercheurs program · Ruder Boškovic Insitute · FP7-PEOPLE-2011-COFUND program NEWFELPRO
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