journal article·2010-05-05

An Unprecedented Eight-Connected Self-Penetrating Coordination Framework Based on Cage-Shaped [Pb6(μ4-O)2(O2C)8] Clusters

Dong-Sheng Li, Ya-Pan Wu, Peng Zhang, Miao Du, Jun Zhao, Cheng-Peng Li, Yao-Yu Wang

Crystal Growth & Design· Volume 10· Issue 5
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Abstract

A unique self-penetrating coordination framework with (4 24 .6 4 ) network topology is constructed from cage-shaped [Pb 6 (μ 4 -O) 2 (O 2 C) 8 ] clusters as eight-connected nodes and long V-shaped dicarboxylate backbones as spacers, which interestingly can be regarded as the cross-linking of two interpenetrating six-connected pcu networks.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Lanthanide and Transition Metal Complexes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Mechanical & Material Engineering, Functional Materials Research Institute, China Three Gorges University, Yichang 443002, China

College of Chemistry and Life Science, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387, China

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry, Northwest University, Xi'an 710069, China

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