Unprecedented (3,9)-Connected (42.6)3(46.621.89) Net Constructed by Trinuclear Mixed-Valence Cobalt Clusters
Source abstract
Abstract
A solvothermal reaction of Co 2 O 3, CoSO 4, pyridine-3,5-dicarboxylic acid, and H 2 O 2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co 3 (OH)(pdc) 3 ]·H 2 O ( 1 ) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (4 2 .6) 3 (4 6 .6 21 .8 9 ) topology in which hydroxycentered mixed-valence Co 3 (OH)(CO 2 ) 6 clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Metal complexes synthesis and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Chemistry & Material Science, Shanxi Normal University, Linfen, Shanxi 041004, China, and MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China
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