DataVXCrystal Growth & DesignPaper
journal article·2016-04-06

Assembly of Two Novel Cd3/(Cd3 + Cd5)-Cluster-Based Metal–Organic Frameworks: Structures, Luminescence, and Photocatalytic Degradation of Organic Dyes

Ya-Pan Wu, Xue-Qian Wu, Jian-Fang Wang, Jun Zhao, Wen-Wen Dong, Dong-Sheng Li, Qi-Chun Zhang

Crystal Growth & Design· Volume 16· Issue 4
Publisher page
Source abstract

Abstract

Two new three-dimensional (3D) multinodal Cd(II)–organic frameworks, [Cd 3 (dccpa)(bipy) 0.5 (H 2 O) 4 ]·5H 2 O ( 1 ) and [(CH 3 ) 2 NH 2 ] 2 [Cd 11 (dccpa) 4 (DMF) 4 (H 2 O) 8 ]·4H 2 O ( 2 ) (H 6 dccpa = 3,4-di(3,5-dicarboxyl phenyl) phthalic acid, bipy = 4,4′-bipyridine), have been prepared and fully characterized. Compound 1 possesses a 3D neutral framework with a new (6,6,7)-connected topology based on a single trinuclear cluster, while 2 features a 3D anionic framework with a new (5,6,6,10)-connected topology containing mixed trinuclear and pentanuclear clusters. Remarkably, 1 and 2 show promising photocatalytic activities toward the degradation of rhodamine B and methyl blue, which suggests that different kinds of cluster units may exert different impacts on the decomposition of organic dyes.
Source: openalex_inverted_index · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Nanocluster Synthesis and Applications · Magnetism in coordination complexes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Materials and Chemical Engineering, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, Key laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, 443002, P. R. China

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi’an 710069, P. R. China

School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore

Funding

Natural Science Foundation of Hubei Province · National Natural Science Foundation of China · Key Laboratory of Synthetic and Natural Functional Molecular Chemistry, Northwest University

References (54)

Show source-provided references
1. 10.1021/ja512311a10.1021/ja512311a ↗
2. 10.1021/cr200205j10.1021/cr200205j ↗
3. 10.1021/acs.chemrev.5b0022110.1021/acs.chemrev.5b00221 ↗
4. 10.1002/chem.20150045710.1002/chem.201500457 ↗
5. 10.1039/C5CC06162H10.1039/C5CC06162H ↗
6. 10.1016/j.ccr.2013.11.00410.1016/j.ccr.2013.11.004 ↗
7. 10.1002/anie.20150227710.1002/anie.201502277 ↗
8. 10.1039/C0CS00009D10.1039/C0CS00009D ↗
9. 10.1016/j.ccr.2012.02.00210.1016/j.ccr.2012.02.002 ↗
10. 10.1016/j.ccr.2014.12.00910.1016/j.ccr.2014.12.009 ↗
11. 10.1021/cr200179u10.1021/cr200179u ↗
12. 10.1021/cr300282410.1021/cr3002824 ↗
13. 10.1039/C5CC01732G10.1039/C5CC01732G ↗
14. 10.1002/adfm.20140206110.1002/adfm.201402061 ↗
15. 10.1021/ic501113310.1021/ic5011133 ↗
16. 10.1021/ic402692p10.1021/ic402692p ↗
17. 10.1016/j.micromeso.2015.04.03510.1016/j.micromeso.2015.04.035 ↗
18. 10.1039/C5TA00256G10.1039/C5TA00256G ↗
19. 10.1016/j.jssc.2013.07.03110.1016/j.jssc.2013.07.031 ↗
20. 10.1021/cs501953d10.1021/cs501953d ↗
21. 10.1021/jacs.5b0882610.1021/jacs.5b08826 ↗
22. 10.1039/C2TA00635A10.1039/C2TA00635A ↗
23. 10.1039/C5CC02598B10.1039/C5CC02598B ↗
24. 10.1039/b802583p10.1039/b802583p ↗
25. 10.1038/nchem.68110.1038/nchem.681 ↗
26. 10.1021/ja803846z10.1021/ja803846z ↗
27. 10.1002/anie.20070573110.1002/anie.200705731 ↗
28. 10.1021/ic101278w10.1021/ic101278w ↗
29. 10.1039/c3cc38714c10.1039/c3cc38714c ↗
30. 10.1021/ja402630g10.1021/ja402630g ↗
31. 10.1021/ja412667t10.1021/ja412667t ↗
32. 10.1021/ja300539p10.1021/ja300539p ↗
33. 10.1039/c3cc44133d10.1039/c3cc44133d ↗
34. 10.1021/cg401589810.1021/cg4015898 ↗
35. 10.1021/cg900579s10.1021/cg900579s ↗
36. 10.1039/C2DT31536J10.1039/C2DT31536J ↗
37. 10.1002/ejic.20060018910.1002/ejic.200600189 ↗
38. 10.1039/C4CE01959H10.1039/C4CE01959H ↗
39. 10.1039/c2dt12170k10.1039/c2dt12170k ↗
40. 10.1021/ic400771810.1021/ic4007718 ↗
41. 10.1039/C4TA06537A10.1039/C4TA06537A ↗
42. 10.1039/C4DT01086H10.1039/C4DT01086H ↗
43. 10.1021/cg100090h10.1021/cg100090h ↗
44. CrystalClear, version 2.0;Rigaku Corporation:Tokyo, Japan, 2009.
45. Sheldrick, G. M.SHELXS-97, Program for the Solution of Crystal Structures;University of Göttingen:Germany, 1997.
46. Sheldrick, G. M.SHELXL, Program for the Refinement of Crystal Structures;University of Göttingen:Germany, 1997.
47. 10.1021/cg900566v10.1021/cg900566v ↗
48. 10.1021/cg500295r10.1021/cg500295r ↗
49. 10.1007/s11224-012-0013-310.1007/s11224-012-0013-3 ↗
50. 10.1021/cg201564410.1021/cg2015644 ↗
51. 10.1039/c3cc42241k10.1039/c3cc42241k ↗
52. 10.1021/ic302273h10.1021/ic302273h ↗
53. 10.1002/anie.20100591710.1002/anie.201005917 ↗
54. 10.1039/c2jm34349e10.1039/c2jm34349e ↗