Detailed Structure Analysis of Atomic Positions and Defects in Zirconium Metal–Organic Frameworks
Source abstract
Abstract
We report the structure of the Zr metal–organic frameworks (MOFs) UiO-66 and UiO-67 to very fine detail using synchrotron single-crystal X-ray diffraction and the synthesis method used to obtain single crystals. Zr terephthalate MOF UiO-66 is known to have missing linkers, and the nature of these are shown to be coordinating water and solvent molecules. Single crystals of the isoreticular material UiO-67 does not show such missing linker defects.
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Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Radioactive element chemistry and processing · X-ray Diffraction in Crystallography
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, University of Oslo, N-0371 Oslo, Norway
Department of Chemistry, NIS and INSTM Reference Centre, Via Quarello 15, I-10135 Torino, Italy
Southern Federal University, Zorge Street 5, 344090 Rostov-on-Don, Russia
Funding
Norwegian Research Council
References (19)
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