Refining Pourbaix diagram via distinct Cr–Mn passivation pathways in a multi-principal element alloy
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · High Entropy Alloys Studies · High Temperature Alloys and Creep
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (85)
Show source-provided references
1. Pourbaix · 1966
2. Electrochemical phase diagrams for Ti oxides from density functional calculations10.1103/PhysRevB.92.245126 ↗
3. Ahmad · 2006
4. Reliable electrochemical phase diagrams of magnetic transition metals and related compounds from high-throughput ab initio calculations10.1038/s41529-019-0088-z ↗
5. The role of corrosion-resistant alloying elements in passivity10.1016/j.corsci.2006.05.003 ↗
6. Achieving electrochemical and mechanical stability in a lightweight titanium alloy10.1038/s41467-025-64875-0 ↗
7. Understanding the corrosion behavior by passive film evolution in Zn-containing Al-Si-Cu cast alloy10.1016/j.corsci.2022.110468 ↗
8. Passivation-induced physicochemical alterations of the native surface oxide film on 316L austenitic stainless steel10.1149/2.0321911jes ↗
9. Cr, Mo and W alloying additions in Ni and their effect on passivity10.1016/j.electacta.2004.01.061 ↗
10. Molybdenum effects on the stability of passive films unraveled at the nanometer and atomic scales10.1038/s41529-023-00418-6 ↗
11. Effects of Cu addition on the corrosion behavior of NiCoCrMo alloys in neutral chloride solution10.1039/C7RA05617F ↗
12. Revisiting the influence of Sn in Cu-Al alloys: A third element effect enabling stainless steel type corrosion behavior10.1149/1945-7111/ae0eb6 ↗
13. The contribution of Cr and Mo to the passivation of Ni22Cr and Ni22Cr10Mo alloys in sulfuric acid10.1016/j.corsci.2020.109015 ↗
14. Understanding multi-element alloy passivation in acidic solutions using operando methods10.1016/j.elecom.2017.05.015 ↗
15. The Third Element Effect during Aqueous Corrosion of FeCrAl Alloys: Effect of Al Content10.1149/1945-7111/ae20c9 ↗
16. Passivity and pitting of single-phase FeCoNi-Cr-Al compositionally complex alloys: An Al-Cr Third Element Effect in sulfuric acid containing chloride
17. Factors governing passivation behavior of Fe-Cr-Al-Ti alloys in sulfate containing acidified solutions: Uncovering the many roles of Ti10.1016/j.mtla.2025.102370 ↗
18. Elemental partitioning and corrosion resistance of Ni–Cr alloys revealed by accurate ab-initio thermodynamic and electrochemical calculations10.1038/s41529-023-00414-w ↗
19. Study of the surface oxides and corrosion behaviour of an equiatomic CoCrFeMnNi high entropy alloy by XPS and ToF-SIMS10.1016/j.corsci.2020.108507 ↗
20. Passivation of a corrosion resistant high entropy alloy in non-oxidizing sulfate solutions10.1016/j.actamat.2018.10.026 ↗
21. Computational materials design of a corrosion resistant high entropy alloy for harsh environments10.1016/j.scriptamat.2018.04.040 ↗
22. The role of chromium content in aqueous passivation of a non-equiatomic Ni38Fe20CrxMn21-0.5 xCo21-0.5 x multi-principal element alloy (x= 22, 14, 10, 6 at%) in acidic chloride solution10.1016/j.actamat.2022.118607 ↗
23. Unmasking chloride attack on the passive film of metals10.1038/s41467-018-04942-x ↗
24. Observation of passive films on Fe–20Cr–xNi (x= 0, 10, 20 wt%) alloys using TEM and Cs-corrected STEM–EELS10.1016/j.corsci.2013.10.023 ↗
25. Corrosion resistance and passive film stability of laser direct energy deposited TiVZrNbAl lightweight multi-principal element alloy10.1016/j.corsci.2024.112391 ↗
26. Counterintuitive passivation role of manganese in stainless steel under high potential in neutral NaCl solution10.1016/j.corsci.2025.112756 ↗
27. Potential-pH diagrams considering complex oxide solution phases for understanding aqueous corrosion of multi-principal element alloys10.1038/s41529-020-00141-6 ↗
28. Ab initio-based metric for predicting the protectiveness of surface films in aqueous media10.1038/s41529-023-00385-y ↗
29. Evolution of passivity for the multi-principal element alloy CoCrFeNi with potential, pH, and exposure in chloride solution10.5006/3902 ↗
30. The thermodynamic scale of inorganic crystalline metastability10.1126/sciadv.1600225 ↗
31. A critical review of high entropy alloys and related concepts10.1016/j.actamat.2016.08.081 ↗
32. Thermodynamic descriptors to predict oxide formation in aqueous solutions10.1021/acs.jpclett.2c01173 ↗
33. Efficient Pourbaix diagrams of many-element compounds10.1039/C9CP04799A ↗
34. Passive films on stainless steels—chemistry, structure and growth10.1016/S0013-4686(02)00841-1 ↗
35. The history of the point defect model for the passive state: a brief review of film growth aspects10.1016/j.electacta.2010.11.005 ↗
36. Effects of alloying elements and microstructure on stainless steel corrosion: a review10.1002/srin.202100450 ↗
37. A sequential dual-passivation strategy for designing stainless steel used above water oxidation10.1016/j.mattod.2023.07.022 ↗
38. Element-resolved electrochemical analysis of transpassive dissolution and repassivation behavior of the multi-principal element alloy AlTiVCr10.1016/j.electacta.2020.137104 ↗
39. Controlling the corrosion resistance of multi-principal element alloys10.1016/j.scriptamat.2020.06.065 ↗
40. Thermodynamics of corrosion: Pourbaix diagrams
41. Stable potential windows for long-term electrocatalysis by manganese oxides under acidic conditions10.1002/anie.201813361 ↗
42. Synthesis and corrosion behavior of Mo15Nb20Ta10Ti35V20 refractory high entropy alloy10.1016/j.matdes.2023.111820 ↗
43. Growth kinetics of multi-oxide passive film formed upon the multi-principal element alloy AlTiVCr: Effect of transpassive dissolution of V and Cr10.1149/1945-7111/ac0018 ↗
44. Corrosion resistance of weight reduced AlxCrFeMoV high entropy alloys10.1016/j.apsusc.2019.03.173 ↗
45. Enhanced corrosion resistance of FeCoCrNiMn high-entropy alloy in aqueous H2SO4 solutions by N and Si alloying
46. Distinctive transpassivation behavior and characteristics of passive films of laser powder bed fusion produced and annealed Ti–6Al–4V in Hank's solution
47. Improving anti-corrosion properties of CoCrFeMnNi high entropy alloy by introducing Si into nonmetallic inclusions10.1016/j.corsci.2022.110616 ↗
48. Design of corrosion-resistant alloys for preventing oxidation-induced nanoscale Cr-depletion by inclusion engineering
49. Bard · 2022
50. Electrochemical noise at passive iron10.1016/0013-4686(88)85022-9 ↗
51. Stable potential windows for long-term electrocatalysis by manganese oxides under acidic conditions10.1002/ange.201813361 ↗
52. The transpassive dissolution mechanism of 316L stainless steel10.1016/j.electacta.2009.01.040 ↗
53. The transpassive dissolution mechanism of highly alloyed stainless steels: I. Experimental results and modelling procedure10.1016/S0010-938X(02)00073-2 ↗
54. Element-resolved corrosion analysis of stainless-type glass-forming steels10.1126/science.1230081 ↗
55. On the influence of Mn on the phase stability of the CrMnxFeCoNi high entropy alloys10.1016/j.intermet.2017.09.011 ↗
56. Effects of Mn on the electrochemical corrosion and passivation behavior of CoFeNiMnCr high-entropy alloy system in H2SO4 solution10.1016/j.jallcom.2019.152943 ↗
57. The spontaneous passivation of multi principal element alloys II: The effect of Mn in the CoCrFeNiMn family10.1016/j.corsci.2024.112642 ↗
58. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni10.1016/j.apsusc.2010.10.051 ↗
59. XPS determination of Mn oxidation states in Mn (hydr) oxides10.1016/j.apsusc.2015.12.159 ↗
60. Aqueous passivation of multi-principal element alloy Ni38Fe20Cr22Mn10Co10: Unexpected high Cr enrichment within the passive film10.1016/j.actamat.2020.07.024 ↗
61. Corrosion behavior of an equiatomic CoCrFeMnNi high-entropy alloy compared with 304 stainless steel in sulfuric acid solution10.1016/j.corsci.2018.02.031 ↗
62. Corrosion behavior of CoCrNi medium-entropy alloy compared with 304 stainless steel in H2SO4 and NaOH solutions10.1016/j.corsci.2020.108973 ↗
63. Non-equilibrium crystallization pathways of manganese oxides in aqueous solution
64. Manganese oxide minerals: Crystal structures and economic and environmental significance10.1073/pnas.96.7.3447 ↗
65. Mechanism of anodic dissolution of iron-chromium alloys investigated by electrode impedances—I. Experimental results and reaction model10.1016/0013-4686(86)80127-X ↗
66. Modelling of the passivation mechanism of Fe-Cr binary alloys from ac impedance and frequency resolved rrde—I. Behaviour of Fe-Cr alloys in 0.5 M H2SO410.1016/0013-4686(95)00463-7 ↗
67. A percolation theory for designing corrosion-resistant alloys10.1038/s41563-021-00920-9 ↗
68. A point defect model for anodic passive films: I. Film growth kinetics10.1149/1.2127591 ↗
69. The point defect model for the passive state10.1149/1.2069096 ↗
70. A point defect model for anodic passive films: II. Chemical breakdown and pit initiation10.1149/1.2127592 ↗
71. On some fundamental factors in the effect of alloying elements on passivation of alloys10.1016/0010-938X(94)90013-2 ↗
72. Insights into the passivity and electrochemistry of CoCrFeMnNi high entropy alloy fabricated by underwater laser direct metal deposition10.1016/j.corsci.2024.112289 ↗
73. Insights into the degradation mechanisms of cost-effective bipolar plate in PEMWE environment under photovoltaic fluctuating inputs
74. Enhance corrosion resistance via passivation treatment for CrMnFeCoNi high-entropy alloy prepared by hot isostatic pressing10.1016/j.intermet.2025.108846 ↗
75. Corrosion behavior of ultrafine-grained CoCrFeMnNi high-entropy alloys fabricated by high-pressure torsion10.3390/ma15031007 ↗
76. Roles of alloying elements in the corrosion resistance of equiatomic CoCrFeMnNi high-entropy alloy and application to corrosion-resistant alloy design10.2320/matertrans.MT-M2021136 ↗
77. Structure–property relationship of bifunctional MnO2 nanostructures: highly efficient, ultra-stable electrochemical water oxidation and oxygen reduction reaction catalysts identified in alkaline media10.1021/ja505186m ↗
78. Acid-stable manganese oxides for proton exchange membrane water electrolysis
79. Robust mesoporous manganese oxide catalysts for water oxidation10.1021/cs501739e ↗
80. Study of stainless steels corrosion in a strong acid mixture. Part 1: cyclic potentiodynamic polarization curves examined by means of an analytical method10.1016/j.corsci.2017.10.012 ↗
81. Electrochemical impedance spectroscopy─ a tutorial10.1021/acsmeasuresciau.2c00070 ↗
82. EQCM investigation of the electrodeposition of MnO2 and its capacitance behavior10.1149/1.3152327 ↗
83. A perspective on corrosion of multi-principal element alloys10.1038/s41529-021-00163-8 ↗
84. Corrosion behaviour of type 316L stainless steel in hot caustic aqueous environments10.1007/s12540-019-00403-2 ↗
85. Evaluating the corrosion performance of a Al2Cr5Cu5Fe53Ni35 multi-principal element alloy (MPEA) in NS4 simulated soil via electrochemical characterization and thermodynamic predictions