journal article·2026-06Open access

Enhancing corrosion resistance of Mg-Zn-Ca alloys via constrained friction processing

Ting Chen, Banglong Fu, Bahram Vaghefinazari, Uceu F.H.R. Suhuddin, Yulong Wu, Tong Shen, Emad Maawad, Sviatlana V. Lamaka, Jorge F. dos Santos, Mikhail L. Zheludkevich, Jean Pierre Bergmann, Benjamin Klusemann

Corrosion Science· Volume 265

Abstract

Magnesium (Mg) alloys are promising lightweight structural materials due to their excellent mechanical properties and high specific strength. However, their relatively high corrosion rates, susceptibility to localized corrosion, and potential for stress corrosion cracking pose significant challenges for engineering applications. This study investigates the corrosion resistance of Mg-Zn-Ca (ZX) alloys processed by a constrained friction processing (CFP) technique. CFP significantly refines the microstructure, reduces the size and volume of secondary phases, and enhances the mechanical properties of ZX alloys. The results show that CFP ZX alloys exhibit improved corrosion resistance in NaCl solution, with ZX10 alloy demonstrating the best performance due to the formation of a dense corrosion product and a protective Zn-rich layer on the surface. The study reveals that the severe shear deformation and extensive recrystallization during CFP accelerate the dissolution of secondary phases into the matrix, leading to a more homogeneous microstructure and reduced localized micro-galvanic corrosion. These findings highlight the potential of CFP for producing high-performance Mg alloys with enhanced corrosion resistance for structural applications.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Metallurgy and Material Science · Advanced Welding Techniques Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (74)

Show source-provided references
1. General and localized corrosion of magnesium alloys: a critical review10.1361/10599490417533 ↗
2. Development and application of magnesium alloy parts for automotive OEMs: A review10.1016/j.jma.2022.12.015 ↗
3. Corrosion of metallic biomaterials: A review10.3390/ma12030407 ↗
4. Recent developments in coatings on biodegradable Mg alloys: A review10.1016/j.jma.2025.01.027 ↗
5. vitro degradation and mechanical integrity of calcium-containing magnesium alloys in modified-simulated body fluid10.1016/j.biomaterials.2008.02.003 ↗
6. Corrosion-fatigue: a review of damage tolerance models10.1080/09506608.2017.1375644 ↗
7. Enhancing the mechanical properties and osteogenic differentiation of Mg-1 wt% Ho alloy by tailoring microstructures through extrusion temperatures10.1016/j.jmrt.2024.05.094 ↗
8. Recent advances using equal-channel angular pressing to improve the properties of biodegradable Mg-Zn alloys10.1016/j.jma.2023.07.009 ↗
9. Mechanical properties, degradation performance and cytotoxicity of Mg-Zn-Ca biomedical alloys with different compositions10.1016/j.msec.2011.07.015 ↗
10. Preparation and characterization of a new biomedical magnesium–calcium alloy10.1016/j.matdes.2008.04.017 ↗
11. The role of zinc in the biocorrosion behavior of resorbable Mg-Zn-Ca alloys10.1016/j.actbio.2019.09.021 ↗
12. A comprehensive comparison of the corrosion performance, fatigue behavior and mechanical properties of micro-alloyed MgZnCa and MgZnGe alloys10.1016/j.matdes.2019.108285 ↗
13. Improving both strength and ductility of a Mg alloy through a large number of ECAP passes10.1016/j.msea.2009.01.040 ↗
14. Corrosion behavior of AZ91 Mg alloy with a heterogeneous structure produced by ECAP10.1016/j.corsci.2021.109517 ↗
15. Influence of ultra-fine grain structure on corrosion behaviour of biodegradable Mg-1Ca alloy10.1016/j.corsci.2019.108303 ↗
16. High-pressure torsion of pure magnesium: Evolution of mechanical properties, microstructures and hydrogen storage capacity with equivalent strain10.1016/j.scriptamat.2011.01.023 ↗
17. Improvement of mechanical properties and corrosion resistance of biodegradable Mg–Nd–Zn–Zr alloys by double extrusion10.1016/j.mseb.2012.05.020 ↗
18. Development of novel grain morphology during hot extrusion of magnesium AZ21 alloy10.1016/j.actamat.2009.10.056 ↗
19. Analysing the combined effect of crystallographic orientation and grain refinement on mechanical properties and corrosion behaviour of ECAPed ZE41 Mg alloy10.1016/j.jma.2020.08.015 ↗
20. Effect of grain refinement and crystallographic texture produced by friction stir processing on the biodegradation behavior of a Mg-Nd-Zn alloy10.1016/j.jmst.2018.11.025 ↗
21. vitro and in vivo study on fine-grained Mg–Zn–RE–Zr alloy as a biodegradeable orthopedic implant produced by friction stir processing
22. Application of novel constrained friction processing method to produce fine grained biomedical Mg-Zn-Ca alloy10.1016/j.jma.2023.10.007 ↗
23. Microstructural development of as-cast AM50 during Constrained Friction Processing: Grain refinement and influence of process parameters10.1016/j.jmatprotec.2023.118018 ↗
24. Effect of thermo-mechanical conditions during constrained friction processing on the particle refinement of AM50 Mg-alloy phases10.1016/j.jma.2024.04.002 ↗
25. Improving mechanical properties of constrained friction processing Mg-Zn-Ca alloys by modifying texture using multiple pass processing10.1016/j.jmst.2025.01.026 ↗
26. FIT2D: a multi-purpose data reduction, analysis and visualization program10.1107/S1600576716000455 ↗
27. The effect of small-molecule bio-relevant organic components at low concentration on the corrosion of commercially pure Mg and Mg-0.8 Ca alloy: An overall perspective10.1016/j.corsci.2019.03.039 ↗
28. Revisited precipitation process in dilute Mg-Ca-Zn alloys10.1016/j.actamat.2023.119072 ↗
29. High rate oxygen reduction reaction during corrosion of ultra-high-purity magnesium10.1038/s41529-020-00146-1 ↗
30. Galvanic corrosion of magnesium alloy AZ91D in contact with an aluminium alloy, steel and zinc10.1016/S0010-938X(03)00190-2 ↗
31. Effects of Ca on microstructure, mechanical and corrosion properties and biocompatibility of Mg–Zn–Ca alloys10.1007/s10856-013-4856-y ↗
32. Enhancement of mechanical properties and corrosion resistance of Mg–Ca alloys through microstructural refinement by indirect extrusion10.1016/j.corsci.2014.01.041 ↗
33. Revealing physical interpretation of time constants in electrochemical impedance spectra of Mg via Tribo-EIS measurements10.1016/j.electacta.2021.139582 ↗
34. Non-stationarity in electrochemical impedance measurement of Mg-based materials in aqueous media10.1016/j.electacta.2023.143140 ↗
35. Electrophoretic deposition of MXene coating on Mg alloy 2, 5 PDCA-LDH film for enhanced anticorrosion/wear10.1016/j.colsurfa.2024.135043 ↗
36. Influence of electrolyte temperature on morphology and properties of composite anodic film on titanium alloy Ti-10V-2Fe-3Al10.3390/coatings10111109 ↗
37. Insight into physical interpretation of high frequency time constant in electrochemical impedance spectra of Mg10.1016/j.corsci.2021.109501 ↗
38. Micro-alloyed Mg-Ca: Corrosion susceptibility to heating history and a plain problem-solving approach10.1016/j.jma.2022.12.014 ↗
39. Characterization of filiform corrosion of Mg–3Zn Mg alloy10.1149/2.1221709jes ↗
40. Microstructural influence on corrosion behavior of MgZnGe alloy in NaCl solution10.1016/j.jallcom.2018.12.296 ↗
41. Property profile development during wire extrusion and wire drawing of magnesium alloys AZ31 and ZX1010.1016/j.matdes.2022.111355 ↗
42. Influence of solid-solution treatment on microstructure, mechanical property and corrosion behavior of biodegradable Mg-Zn-Ca alloy10.1088/1757-899X/182/1/012054 ↗
43. Density and Thermal Expansion of Magnesium–Calcium Alloys in Solid and Liquid States10.1007/s10765-023-03187-1 ↗
44. Microstructure and corrosion behavior of thermo-mechanically processed rare earth Mg alloy: Effect of friction stir processing
45. Microstructure and tensile properties of rapid-cooling friction-stir-welded AZ31B Mg alloy along thickness direction10.1016/S1003-6326(20)65458-9 ↗
46. Biocorrosion zoomed in: evidence for dealloying of nanometric intermetallic particles in magnesium alloys10.1002/adma.201903080 ↗
47. Mechanistic understanding of the corrosion behavior of Mg4Zn0. 2Sn alloys: From the perspective view of microstructure10.1016/j.corsci.2020.108863 ↗
48. Achieving ultra-high corrosion-resistant Mg-Zn-Sc alloys by forming Sc-assisted protective corrosion product film10.1016/j.jmst.2023.08.068 ↗
49. Enhancing corrosion resistance of Mg-Nd-Zr-In alloys via the development of a triple-layered In (Indium) rich corrosion product film10.1016/j.corsci.2025.112905 ↗
50. Regulating degradation in MgZnCa metallic glass: Formation of zinc-rich amorphous layer through internal zinc migration10.1016/j.jma.2024.08.015 ↗
51. Effects of crystallization on the corrosion resistance of Fe-based amorphous coatings10.1016/j.corsci.2012.02.003 ↗
52. Stainless magnesium alloy based on self-healing amorphous surface10.1016/j.mattod.2025.11.015 ↗
53. Initial micro-galvanic corrosion behavior between Mg2Ca and α-Mg via quasi-in situ SEM approach and first-principles calculation10.1016/j.jma.2021.06.017 ↗
54. As-cast and extruded MgZnCa systems for biodegradable implants: characterization and corrosion behavior10.1016/j.jma.2023.02.001 ↗
55. A review—Pitting corrosion initiation investigated by TEM10.1016/j.jmst.2019.01.013 ↗
56. Haynes · 2014
57. Localized corrosion behavior and surface corrosion film microstructure of a commercial dual-phase LZ91 Mg alloy10.1038/s41529-025-00567-w ↗
58. Transmission electron microscopy study of aqueous film formation and evolution on magnesium alloys10.1149/2.024406jes ↗
59. Characterization of localized filament corrosion products at the anodic head on a model Mg-Zn-Zr alloy surface10.5006/2268 ↗
60. Approaching “stainless magnesium” by Ca micro-alloying10.1039/D0MH01380C ↗
61. Effect of processing history on corrosion behaviours of high purity Mg10.1016/j.corsci.2021.109357 ↗
62. Corrosion behavior of equal-channel-angular-pressed pure magnesium in NaCl aqueous solution10.1016/j.corsci.2009.10.004 ↗
63. The role of second phases in the corrosion behavior of Mg–5Zn alloy10.1016/j.corsci.2012.03.030 ↗
64. Corrosion behaviour in salt spray and in 3.5% NaCl solution saturated with Mg (OH)2 of as-cast and solution heat-treated binary Mg–X alloys: X= Mn, Sn, Ca, Zn, Al, Zr, Si, Sr10.1016/j.corsci.2013.06.030 ↗
65. Microstructures, mechanical properties and corrosion resistances of extruded Mg–Zn–Ca–xCe/La alloys10.1016/j.jmbbm.2016.04.038 ↗
66. Limitations in the use of the potentiodynamic polarisation curves to investigate the effect of Zn on the corrosion behaviour of as-extruded Mg–Zn binary alloy10.1016/j.corsci.2013.06.027 ↗
67. Microstructure and corrosion behavior of Mg–Zn–Ag alloys10.1016/j.msea.2006.07.109 ↗
68. The role of Mg2Si on the corrosion behavior of wrought Mg–Zn–Mn alloy10.1016/j.intermet.2008.03.003 ↗
69. Corrosion behavior of Mg–2.4 Zn alloy micro-alloyed with Ag and Ca10.1016/j.corsci.2013.09.012 ↗
70. Effect of Al Addition on Microstructure, Mechanical, and Corrosion Properties of Hot Extruded Mg-2.0 Zn-0.4 Mn Alloy10.1007/s11665-023-08252-2 ↗
71. Corrosion behavior of Mg–Ca–Zn alloys with high Zn content10.1016/j.jpcs.2021.109952 ↗
72. Corrosion behavior of Mg–Mn–Ca alloy: influences of Al, Sn and Zn10.1016/j.jma.2018.11.004 ↗
73. Effect of Sn on corrosion properties of homogenized Mg-6Zn-0.25 Ca magnesium alloy
74. The corrosion performance and mechanical properties of Mg-Zn based alloys—a review10.3390/cmd1010007 ↗