journal article·2018-02Open access

Electrochemical profiling of multi-clad aluminium sheets used in automotive heat exchangers

Kirill Bordo, Visweswara C. Gudla, Lionel Peguet, Andreas Afseth, Rajan Ambat

Corrosion Science· Volume 131

Abstract

A combination of glow discharge optical emission spectroscopy sputtering and local electrochemical measurements was used to determine electrochemical changes upon brazing in a multi-layered Aluminium sheet (AA4343/AA3xxx/AA4343) with an additional low-Cu (AA3xxx) interlayer. Ecorr values from potentiodynamic polarization, galvanic corrosion behaviour by ZRA, microstructure and composition by SEM and TEM were investigated and compared to those obtained for sheet without the interlayer. Inward diffusion of Si from clad, and outward diffusion of Cu from core are found to degrade the corrosion properties of conventional sheet, whereas presence of interlayer reduced outward diffusion of Cu and hence improved corrosion protection.
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Research context

OpenAlex topics: Non-Destructive Testing Techniques · Corrosion Behavior and Inhibition · Aluminum Alloy Microstructure Properties

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References (67)

Show source-provided references
1. Recent development in aluminium alloys for the automotive industry10.1016/S0921-5093(99)00653-X ↗
2. Structure of anodized Al-Zr sputter deposited coatings and effect on optical appearance10.1016/j.apsusc.2014.09.037 ↗
3. Accelerated growth of oxide film on aluminium alloys under steam: part I: effects of alloy chemistry and steam vapour pressure on microstructure10.1016/j.surfcoat.2015.06.059 ↗
4. Recent developments in advanced aircraft aluminium alloys10.1016/j.matdes.2013.12.002 ↗
5. Improving aluminum recycling: a survey of sorting and impurity removal technologies10.1016/j.resconrec.2011.10.010 ↗
6. Interface strength and degradation of adhesively bonded porous aluminum oxides10.1038/s41529-017-0007-0 ↗
7. Light weight materials for automotive applications10.1016/1044-5803(95)00063-1 ↗
8. Lumley · 2011 · 1
9. High Strength Al-Alloys: Microstructure, Corrosion and Principles of Protection, in: Recent Trends Process
10. Brazing aluminum
11. 10 – controlled atmosphere brazing of aluminum woodhead publ. Ser. weld. other join. technol
12. Recycling of automotive aluminum10.1016/S1003-6326(09)60417-9 ↗
13. 20 – Joining of aluminium and its alloys
14. Messler · 1993 · pp.. 283
15. Effects of environmental factors on atmospheric corrosion of aluminium and its alloys under constant dew point conditions10.1016/j.corsci.2011.12.038 ↗
16. Degradability of aluminum in acidic and alkaline solutions10.1016/j.corsci.2013.10.019 ↗
17. Intergranular corrosion propagation rateof 2024 alloy investigated via the one-​dimensional artificial pit technique10.1016/j.corsci.2016.05.033 ↗
18. Passivity breakdown, pit initiation and propagation of pits in metallic materials – review10.1016/j.corsci.2014.10.006 ↗
19. Microstructural control in an aluminum core alloy for brazing sheet applications10.1007/BF02666328 ↗
20. Effect of microstructure on the corrosion behaviour of extruded heat exchanger aluminium alloys10.1002/sia.5282 ↗
21. Development of improved aluminum vacuum brazing core alloy
22. Grain boundary penetration during brazing of aluminum
23. Electrochemical depth profiling of multilayer metallic structures: an aluminum brazing sheet10.1016/j.electacta.2012.06.023 ↗
24. Improved corrosion resistance of aluminum brazing sheet by a post-brazing heat treatment10.5006/2210 ↗
25. Scanning Kelvin probe force microscopy as a means of predicting the electrochemical characteristics of the surface of a modified AA4xxx/AA3xxx (Al alloys) brazing sheet10.1016/j.electacta.2012.10.051 ↗
26. Electrochemical behaviors of quad-layer aluminum brazing sheet composite for automotive applications10.5006/1.3299245 ↗
27. Radio-frequency glow discharge spectrometry: a critical review10.1016/j.sab.2004.02.013 ↗
28. Electrochemical characteristics of intermetallic phases in aluminum alloys: an experimental survey and discussion10.1149/1.1869984 ↗
29. Microelectrodes for studies of localized corrosion processes10.1016/S0013-4686(98)00025-5 ↗
30. Microelectrodes for corrosion studies in microsystems10.1016/S0013-4686(01)00551-5 ↗
31. Electrochemical capillary cells10.1179/147842204225016877 ↗
32. Localized corrosion inhibition by cerium species on clad AA2024 aluminium alloy investigated by means of electrochemical micro-cell10.1016/j.corsci.2012.08.053 ↗
33. Volta potential of clad AA2024 aluminium after exposure to CeCl3 solution10.1016/j.corsci.2014.05.008 ↗
34. Study of the microstructure resulting from brazed aluminum materials used in heat exchangers10.1016/j.msea.2005.08.187 ↗
35. Corrosion investigation of material combinations in a mobile phone dome–key pad system10.1016/j.corsci.2006.12.013 ↗
36. The effect of welding parameters on the corrosion behaviour of friction stir welded AA2024-T35110.1016/j.corsci.2006.05.038 ↗
37. Corrosion mechanisms in aluminium cladded sheets for automotive heat exchangers studied by electrochemical depth profiling
38. Peguet · 2016
39. 2013 · 1
40. FIB/SEM study of AA2024 corrosion under a seawater drop: part I10.1016/j.corsci.2010.12.004 ↗
41. FIB/SEM study of AA2024 corrosion under a seawater drop, part II10.1016/j.corsci.2011.10.012 ↗
42. In-situ TEM investigation of microstructural evolution in magnetron sputtered Al-Zr and Al-Zr-Si coatings during heat treatment10.1016/j.matdes.2015.10.081 ↗
43. Anodisation of sputter deposited aluminium – titanium coatings: effect of microstructure on optical characteristics10.1016/j.surfcoat.2014.05.073 ↗
44. Effect of high frequency pulsing on the interfacial structure of anodized aluminium-TiO210.1149/2.0311507jes ↗
45. Cross-section corrosion-potential profiles of aluminum-alloy brazing sheets observed by the flowing electrolyte scanning-droplet-cell technique10.1016/j.electacta.2007.10.044 ↗
46. Corrosion behaviour of brazing material AA434310.1016/j.electacta.2006.07.007 ↗
47. Corrosion behaviour of brazed multilayer material AA4343/AA3003/AA4343: Influence of coolant parameters10.1016/j.corsci.2007.04.013 ↗
48. Identification of intermetallic precipitates formed during re-solidification of brazed aluminium alloys10.1016/j.scriptamat.2006.03.038 ↗
49. 1992 · Volume 3
50. Quantitative study on the precipitation behavior of dispersoids in DC-cast AA3003 alloy during heating and homogenization10.1016/S1359-6454(03)00160-5 ↗
51. Manganese-induced ordering in the α-(Al-Mn-Fe-Si) approximant phase10.1080/09500839408240993 ↗
52. Parvizi · 2017
53. Solid-state intermetallic phase tranformations in 3XXX aluminium alloys10.1016/S1359-6454(02)00085-X ↗
54. Evolution of intermetallics, dispersoids, and elevated temperature properties at various Fe contents in Al-Mn-Mg 3004 alloys, metall. mater. trans. B process metall
55. The effect of brazing process on microstructure evolution and corrosion performance of a modified AA4XXX/AA3XXX brazing sheet10.1016/j.corsci.2012.01.030 ↗
56. Investigation of the de-alloying behaviour of θ-phase (Al2Cu) in AA2024-T351 aluminium alloy10.1016/j.corsci.2016.03.003 ↗
57. A closer look at constituent induced localised corrosion in Al-Cu-Mg alloys10.1016/j.corsci.2016.10.018 ↗
58. Size-dependent role of S phase in pitting initiation of 2024Al alloy10.1016/j.corsci.2016.01.016 ↗
59. Chapter B.1 − the corrosion of aluminium
60. Pitting corrosion of aluminum10.1016/S0010-938X(99)00012-8 ↗
61. The intergranular corrosion susceptibility of 2024 Al alloy during re?ageing after solution treating and cold?rolling10.1016/j.corsci.2016.11.013 ↗
62. Corrosion behaviour of friction stir-welded AA6005-T6 using a bobbin tool10.1016/j.corsci.2016.04.046 ↗
63. Electrochemical assessment of interfacial characteristics of intermetallic phases present in aluminium alloy 2024-T310.1016/j.corsci.2015.09.012 ↗
64. Quasi in situ analytical TEM to investigate electrochemically induced microstructural changes in alloys: AA2024-T3 as an example10.1016/j.corsci.2012.12.006 ↗
65. Multianalytical and In situ studies of localized corrosion of EN AW-3003 Alloy—Influence of intermetallic particles10.1149/1.2834454 ↗
66. The role of intermetallic particles in localized corrosion of an aluminum alloy studied by SKPFM and integrated AFM/SECM10.1149/1.2883737 ↗
67. An insight into the influence of morphological and compositional heterogeneity of an individual intermetallic particle on aluminium alloy corrosion initiation10.1002/maco.201106466 ↗