journal article·2018-07

Rapid colorimetric analysis of graphene on copper

Aaditya A. Candadai, Anurag Kumar, Majed A. Alrefae, Dimitry Zemlyanov, Timothy S. Fisher

Corrosion Science· Volume 138
Publisher page

Abstract

Abstract This work presents a facile method based on colorimetric analysis using optical microscopy to rapidly screen large-area graphene on copper. The colorimetric technique exploits the oxidation protection offered by graphene on copper surfaces exposed to air at moderate temperatures (180 °C). Image processing using an RGB color model is employed to assess the level of protection. The analysis generates quantifiable results that match well with visual observations as well as Raman spectroscopy and XPS measurements. The reported method addresses a bottleneck for rapid, large-area characterization of graphene that can be integrated with scaled up roll-to-roll manufacturing processes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Graphene and Nanomaterials Applications · Advanced Memory and Neural Computing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. The rise of graphene10.1038/nmat1849 ↗
2. A roadmap for graphene10.1038/nature11458 ↗
3. Roll-to-roll production of 30-inch graphene films for transparent electrodes10.1038/nnano.2010.132 ↗
4. Water desalination using nanoporous single-layer graphene10.1038/nnano.2015.37 ↗
5. Oxidation resistance of graphene-coated Cu and Cu/Ni alloy10.1021/nn103028d ↗
6. Graphene: an effective oxidation barrier coating for liquid and two-phase cooling systems10.1016/j.corsci.2012.12.014 ↗
7. Large-area synthesis of high-quality and uniform graphene films on copper foils10.1126/science.1171245 ↗
8. Large Area, few-layer graphene films on arbitrary substrates by chemical vapor deposition10.1021/nl801827v ↗
9. Review of chemical vapor deposition of graphene and related applications10.1021/ar300203n ↗
10. A review of chemical vapour deposition of graphene on copper10.1039/C0JM02126A ↗
11. High-speed roll-to-roll manufacturing of graphene using a concentric tube CVD reactor10.1038/srep10257 ↗
12. A roll-to-roll microwave plasma chemical vapor deposition process for the production of 294mm width graphene films at low temperature10.1016/j.carbon.2012.02.020 ↗
13. Production of a 100-m-long high-quality graphene transparent conductive film by roll-to-roll chemical vapor deposition and transfer process10.1063/1.4776707 ↗
14. Graphene as a long-term metal oxidation barrier: worse than nothing10.1021/nn4014356 ↗
15. Zhou · 2011
16. Direct optical characterization of graphene growth and domains on growth substrates
17. Colors of graphene and graphene-oxide multilayers on various substrates10.1088/0957-4484/23/2/025708 ↗
18. Colorimetric and resistive polymer electrolyte thin films for real-time humidity sensors10.1021/am3011115 ↗
19. Colorimetric sensor array for determination and identification of toxic industrial chemicals10.1021/ac1020886 ↗
20. A colourimetric and microstructural study of the tarnishing of gold-based bulk metallic glasses10.1016/j.corsci.2014.04.024 ↗
21. Decoupling the dual source of colour alteration of architectural titanium: soiling or oxidation?10.1016/j.corsci.2013.03.019 ↗
22. Rapid synthesis of few-layer graphene over Cu foil10.1016/j.carbon.2011.11.033 ↗
23. Process optimization of graphene growth in a roll-to-roll plasma CVD system10.1063/1.4998770 ↗
24. Developments in surface contamination and cleaning
25. Atmospheric corrosion of copper and the colour, structure and composition of natural patinas on copper10.1016/j.corsci.2005.09.011 ↗
26. Raman spectrum of graphene and graphene layers10.1103/PhysRevLett.97.187401 ↗
27. Spatially resolved Raman spectroscopy of single-and few-layer graphene10.1021/nl061702a ↗
28. Synthesis of few-layer graphene via microwave plasma-enhanced chemical vapour deposition10.1088/0957-4484/19/30/305604 ↗
29. Plasma-enhanced chemical vapor deposition of graphene on copper substrates10.1063/1.4873157 ↗
30. Quantitative analysis of copper oxide nanoparticle composition and structure by X-ray photoelectron spectroscopy10.1021/cm061596d ↗
31. Chemical information from XPS—applications to the analysis of electrode surfaces10.1116/1.570934 ↗
32. Electronic structure of Cu 2 O and CuO10.1103/PhysRevB.38.11322 ↗
33. Direct observation of grain boundaries in chemical vapor deposited graphene10.1016/j.carbon.2017.01.009 ↗
34. Protecting nickel with graphene spin-filtering membranes: a single layer is enough10.1063/1.4923401 ↗
35. Low-temperature in situ growth of graphene on metallic substrates and its application in anticorrosion10.1021/acsami.5b09453 ↗
36. Optical properties of nickel oxide10.1103/PhysRev.114.1507 ↗
37. The colours due to thin films on metals10.1098/rspa.1925.0017 ↗