journal article·2018-10Open access

Influence of low CO concentration on catalysed carbon deposition on 20Cr25Ni steel in CO2 environments containing ethene

R. Ding, M.P. Taylor, H.E. Evans, C.W. Mowforth, N. Smith, Y.L. Chiu, B.J. Connolly

Corrosion Science· Volume 143

Abstract

Carbon deposition on 20Cr25Ni steel at 700 °C has been investigated in CO2-based gases containing 0.7 vol%, 1.0 vol% and 1.4 vol% CO, each with ∼1000vpm C2H4, at 700 °C. Filamentary carbon deposits were formed at the two lowest CO contents but not at 1.4 vol% CO. TEM analyses have shown that the different CO levels change the propensity for deposition by altering the ratio of Ni:Fe in the nanometre sized catalytic particles produced during oxidation.
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Research context

OpenAlex topics: Catalytic Processes in Materials Science · Catalysts for Methane Reforming · Catalysis and Oxidation Reactions

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