journal article·2018-07

Inhibitory effect of three phenacyl derivatives on the oxidation of sphalerite (ZnS) in air-equilibrated acidic solution

Paul Chiriţă, Mădălina I. Duinea, Ana M. Sandu, Lucian M. Bîrsă, Laura G. Sârbu, Mihaela Baibarac, Florinel Sava, Mihai Popescu, Elena Matei

Corrosion Science· Volume 138
Publisher page

Abstract

Abstract Three phenacyl derivatives have been investigated as potential inhibitors for the aqueous oxidation of sphalerite (ZnS) in air-equilibrated solutions of HCl (pH 2.5 and 25 °C) using potentyodynamic polarization, aqueous batch experiments, scanning electron microscopy coupled with energy dispersive X-ray (SEM/EDX) analysis, Fourier transform infrared (FTIR) spectroscopy, Raman scattering and quantum chemical calculations. Findings show that the studied phenacyl derivatives are inhibitors of sphalerite aqueous oxidation. Quantum chemical calculations indicate that the adsorption of phenacyl derivatives on ZnS is energetically favorable and accounts for the observed inhibiting effects.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Calcium Carbonate Crystallization and Inhibition · Corrosion Behavior and Inhibition · Ionic liquids properties and applications

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