journal article·2020-02Open access

On the microstructural and electrochemical nature of hydrothermally treated Al-Zr and Al-Ti surfaces

Juan Tan, Marco Crosio, Nadja Vinkel, Peter Jensen, Shoshan Tamar Abrahami, Visweswara Chakravarthy Gudla, Rajan Ambat

Corrosion Science· Volume 163

Abstract

Hydrothermal treatment of sputtered Al-Zr and Al-Ti coatings was performed in an autoclave. Electron microscopy of generated conversion layers revealed dual layered boehmite films. Needle morphology at top, and thin compact oxide at interface with metal substrate was observed. X-ray Energy Dispersive, and photoelectron spectroscopy revealed enrichment of Zr or Ti in compact oxide, and oxidation of Zr, Ti and Al. Potentiodynamic polarisation showed decrease in passive current densities due to treatment. Treated Zr containing surfaces showed lower corrosion current density when compared to those containing Ti. The observed electrochemical properties are correlated with microstructure and composition of conversion layers.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · Aluminum Alloy Microstructure Properties · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (68)

Show source-provided references
1. Vargel · 2004
2. Hughes · 2011 · 223
3. A closer look at constituent induced localised corrosion in Al-Cu-Mg alloys10.1016/j.corsci.2016.10.018 ↗
4. Initiation and short crack growth behaviour of environmentally induced cracks in AA5083 H131 investigated across time and length scales
5. Influence of de-icing salt chemistry on the corrosion behavior of AA601610.1002/maco.201709907 ↗
6. Review of surface pretreatments for aluminium alloys10.1016/S0143-7496(96)00014-0 ↗
7. Chromate conversion coating on aluminum alloys10.1149/1.1736683 ↗
8. Corrosion inhibition of aluminum and aluminum alloys by soluble chromates, chromate coatings, and chromate-free coatings10.5006/1.3277570 ↗
9. Influence of the microstructure on the corrosion behaviour of 2024 aluminium alloy coated with a trivalent chromium conversion layer10.1016/j.corsci.2018.07.007 ↗
10. Replacements for chromium pretreatments on aluminum10.5006/1.3293580 ↗
11. Towards Cr(VI)-free anodization of aluminum alloys for aerospace adhesive bonding applications: a review
12. Interface strength and degradation of adhesively bonded porous aluminum oxides10.1038/s41529-017-0007-0 ↗
13. Recent trends in surface treatment technologies for airframe adhesive bonding processing: a review (1995–2008)10.1080/00218460903418345 ↗
14. Fluoride-induced interfacial adhesion loss of nanoporous anodic aluminum oxide templates in aerospace structures10.1021/acsanm.8b01361 ↗
15. SKPFM and SEM study of the deposition mechanism of Zr/Ti based pre-treatment on AA6016 aluminum alloy10.1016/j.surfcoat.2007.02.039 ↗
16. Formation of a zirconium-titanium based conversion layer on AA 6060 aluminium10.1016/S0257-8972(01)01663-2 ↗
17. Investigation of composition and structure for a novel Ti-Zr chemical conversion coating on 6063 aluminum alloy10.1016/j.porgcoat.2015.05.008 ↗
18. Formation of zirconium-based conversion coatings on aluminium and Al-Cu alloys10.1016/j.corsci.2012.08.031 ↗
19. Formation and characterisation of Ti-Zr based conversion layers on AA6060 aluminium10.1016/j.surfcoat.2003.11.003 ↗
20. Effect of pressurized steam on AA1050 aluminiumnull10.1108/00035591211224645 ↗
21. Accelerated growth of oxide film on aluminium alloys under steam: part II: effects of alloy chemistry and steam vapour pressure on corrosion and adhesion performance10.1016/j.surfcoat.2015.06.060 ↗
22. Performance comparison of steam-based and chromate conversion coatings on aluminum alloy 606010.5006/1624 ↗
23. Accelerated growth of oxide film on aluminium alloys under steam: part I: effects of alloy chemistry and steam vapour pressure on microstructure10.1016/j.surfcoat.2015.06.059 ↗
24. Adhesion at Al-hydroxide-polymer interfaces: influence of chemistry and evidence for microscopic self-pinning10.1016/j.msea.2010.05.020 ↗
25. A simple pre-treatment of aluminium cookware to minimize aluminium transfer to food10.1016/j.fct.2008.12.028 ↗
26. Role of acidic chemistries in steam treatment of aluminium alloys10.1016/j.corsci.2015.07.018 ↗
27. Steam assisted oxide growth on aluminium alloys using oxidative chemistries: part I Microstructural investigation10.1016/j.apsusc.2015.07.182 ↗
28. Microstructure and corrosion performance of steam-based conversion coatings produced in the presence of TiO2 particles on aluminium alloys10.1016/j.surfcoat.2016.03.093 ↗
29. Hydrogen production from aluminum-water reactions subject to varied pressures and temperatures10.1016/j.ijhydene.2019.03.140 ↗
30. Quantifying oxide layer growth at low pressures and temperatures for aluminum alloy 606110.1007/s11661-019-05256-3 ↗
31. A pseudoboehmite-silane hybrid coating for enhanced corrosion protection of AA2024-T310.1149/1.3477162 ↗
32. Can Cr(III) substitute for Al(III) in the structure of boehmite?10.1039/C6RA20234A ↗
33. Band gap tuning of amorphous Al oxides by Zr alloying10.1063/1.4961941 ↗
34. Anodisation of sputter deposited aluminium-titanium coatings: effect of microstructure on optical characteristics10.1016/j.surfcoat.2014.05.073 ↗
35. Anodization and optical appearance of sputter deposited Al-Zr coatings
36. Structure and mechanical properties of Ti–Al films deposited by magnetron sputtering10.1016/j.surfcoat.2005.01.078 ↗
37. Porous anodic film formation on Al-Ti alloys in sulphuric acid10.1016/j.corsci.2011.12.035 ↗
38. Anodic behaviour of a model second phase: Al-20at.%Mg-20at.%Cu10.1016/j.corsci.2005.05.007 ↗
39. High frequency pulse anodising of magnetron sputtered Al-Zr and Al-Ti Coatings10.1016/j.matdes.2016.01.091 ↗
40. The ubiquitous Beilby layer on aluminium surfaces10.1002/sia.3204 ↗
41. Near-surface deformed layers on rolled aluminum alloys10.1007/s11661-010-0538-2 ↗
42. Effect of thermo-mechanical processing on filiform corrosion of aluminium alloy AA300510.1016/S0010-938X(02)00036-7 ↗
43. Electrochemical profiling of multi-clad aluminium sheets used in automotive heat exchangers10.1016/j.corsci.2017.11.011 ↗
44. In-situ TEM investigation of microstructural evolution in magnetron sputtered Al-Zr and Al-Zr-Si coatings during heat treatment10.1016/j.matdes.2015.10.081 ↗
45. Characterization of blisters on powder coated aluminium AA5006 architectural profiles10.1016/j.engfailanal.2019.04.039 ↗
46. In situ study of the initiation of hydrogen bubbles at the aluminium metal/oxide interface10.1038/nmat4336 ↗
47. Growth defect density in PVD hard coatings prepared by different deposition techniques10.1016/j.surfcoat.2013.09.020 ↗
48. Boiling water and silane pre-treatment of aluminum alloys for durable adhesive bonding10.1016/S0143-7496(99)00046-9 ↗
49. Oxide formation on aluminum alloys in boiling deionised water and NaCl, CeCl3 and CrCl3 solutions10.1016/S0010-938X(02)00209-3 ↗
50. Improving the adhesion between epoxy coatings and aluminium substrates10.1016/j.porgcoat.2004.08.005 ↗
51. Effect of hydration pretreatment on tunnel etching behaviour of aluminium foil10.1016/j.corsci.2013.01.027 ↗
52. Characterization of the oxide/hydroxide surface of aluminum using X-ray photoelectron spectroscopy: a procedure for curve fitting the O 1s core level10.1002/1096-9918(200007)29:7<468::AID-SIA890>3.0.CO;2-V ↗
53. E.A. Kit, Thermo Scientific, (n.d.). http://xpssimplified.com/elements/aluminum.php. (Accessed 4 October 2016).
54. An XPS study of the interaction of oxygen with zirconium10.1016/0039-6028(89)90156-8 ↗
55. X-ray photoelectron spectroscopic studies on yttria, zirconia, and yttria-stabilized zirconia10.1063/1.349611 ↗
56. Initiation and growth of modified Zr-based conversion coatings on multi-metal surfaces10.1016/j.surfcoat.2013.09.059 ↗
57. Influence of pre- and post-treatments on formation of a trivalent chromium conversion coating on AA2024 alloy10.1016/j.tsf.2016.08.044 ↗
58. Evolution of the chemistry of passive films of sputter-deposited, supersaturated Al alloys10.1149/1.2086456 ↗
59. Formation of a trivalent chromium conversion coating on AA2024-T351 alloy10.1149/2.0771602jes ↗
60. Characterisation of oxide and hydroxide layers on technical aluminum materials using XPS10.1016/j.vacuum.2011.04.004 ↗
61. Study of the self-assembling of n -Octylphosphonic acid layers on aluminum oxide10.1021/la801978a ↗
62. Determination of the concentration of surface hydroxyl groups on metal oxide films by a quantitative XPS method10.1002/(SICI)1096-9918(199807)26:8<549::AID-SIA396>3.0.CO;2-Q ↗
63. XPS study of the major minerals in bauxite: gibbsite, bayerite and (pseudo-) boehmite10.1016/j.jcis.2005.09.054 ↗
64. XPS characterization of porous and sealed anodic films on aluminum alloys10.1149/1.2712148 ↗
65. Effect of iron-containing intermetallic particles on the corrosion behaviour of aluminium10.1016/j.corsci.2006.01.005 ↗
66. Coatings for corrosion prevention based on rare earths10.1533/9780857093585.186 ↗
67. A simple surface treatment and characterization of AA 6061 aluminum alloy surface for adhesive bonding applications10.1016/j.apsusc.2012.08.091 ↗
68. Effect of supplementary alloying elements on pitting corrosion susceptibility of 18Cr-14Ni stainless steel10.5006/0010-9312-20.5.166t ↗