journal article·2016-11Open access

Tailored platinum-nickel nanostructures on zirconia developed by metal casting, internal oxidation and dealloying

M. Terock, C.H. Konrad, R. Popp, R. Völkl, F. Yang, D.W. McComb, M.J. Mills, U. Glatzel

Corrosion Science· Volume 112

Abstract

Abstract Noble-metal nanostructures are crucial, highly active materials in applications such as fuel cells, sensors, electrodes and catalysts. The present work shows a new and efficient method for the in-situ synthesis of platinum-nickel nanostructures on porous zirconia. Ni-Zr-Y metallic alloys with defined Zr/Y-ratios and small amounts of platinum are internally oxidized. An interpenetrating network of yttria-stabilized zirconia (YSZ) in pure nickel is formed. Dealloying of the nickel matrix generates a multimodal porous ceramic support structure with platinum-nickel nanostructures on the surface of the zirconia-ceramic with a broad spectrum for tailored functionality, for example in after-treatment of exhaust gases.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nanoporous metals and alloys · Electrocatalysts for Energy Conversion · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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