journal article·2012-04

Chronoamperometric study of the passive behaviour of tantalum in hostile media during water addition

J.L. Trompette, L. Massot

Corrosion Science· Volume 57
Publisher page

Abstract

The ability of tantalum to become passive through water addition in methanol solution during chronoamperometric experiments has been investigated. The achievement of passivity was found to be modulated according to the applied electrical potential and the nature of the aggressive anions. The chronoamperometric curves were interpreted as resulting from the balance between the influence of proton mobility in solution and the building of the passive film.
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Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Corrosion Behavior and Inhibition · Electronic and Structural Properties of Oxides

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References (36)

Show source-provided references
1. Influence of the anion specificity on the electrochemical corrosion of anodized aluminium substrates10.1016/j.electacta.2009.12.063 ↗
2. Influence of the anion specificity on the anodic polarization of titanium10.1016/j.corsci.2010.12.021 ↗
3. Viscosity B-coefficients of ions in solution10.1021/cr00040a004 ↗
4. The production and breakdown of the passivity of metals10.1016/S0010-938X(67)80023-4 ↗
5. The localized breakdown and repair of passive surfaces during pitting10.1016/0010-938X(89)90038-3 ↗
6. An overview of the passivity of metals10.1016/0010-938X(90)90086-K ↗
7. Seo · 1999
8. B. Mac Dougall, M.J. Graham, Growth and Stability of Passive Films, in: P. Marcus (Ed.), Corrosion Mechanisms in Theory and Practice, second ed., Marcel Dekker, New York, 2002, pp. 189–216 (Chapter 6).10.1201/9780203909188.ch6 ↗
9. Pitting corrosion of metals10.1149/1.1838615 ↗
10. Mechanism of pit nucleation by electrical breakdown of the passive film10.1016/S0010-938X(01)00113-5 ↗
11. Localized corrosion: a model of passivity breakdown including the role of the oxide layer structure10.1016/j.corsci.2008.06.047 ↗
12. A review of the theoretical modelling of crevice and pitting corrosion10.1016/0010-938X(87)90024-2 ↗
13. Growth mechanism of thin anodic oxide film on tantalum10.1149/1.2423556 ↗
14. Passive behaviour of tantalum10.1016/0013-4686(88)80033-1 ↗
15. Anodic growth of passive films on niobium and tantalum10.1016/0013-4686(91)85332-2 ↗
16. Phosphoric acid passivated niobium and tantalum EIS-comparative study10.1016/0013-4686(95)00123-V ↗
17. Tantalum pentaoxide (Ta2O5) thin films for advanced dielectric applications10.1016/S0927-796X(97)00023-5 ↗
18. Anodic film growth on tantalum in dilute phosphoric acid solution at 20 and 85°C10.1016/S0013-4686(02)00141-X ↗
19. Acid corrosion resistance of tantalum, columbium, zirconium and titanium10.1021/ie50484a023 ↗
20. Passivity and corrosion resistance of metal systems10.1016/0010-938X(64)90028-9 ↗
21. Corrosion behavior of niobium, tantalum and their alloys in boiling sulfuric acid solutions10.1016/S0263-4368(97)87506-3 ↗
22. Corrosion behavior of niobium, tantalum and their alloys in hot hydrochloric and phosphoric acid solutions10.1016/S0263-4368(99)00034-7 ↗
23. Electropolishing of tantalum in sulfuric acid-methanol electrolytes10.1016/S0013-4686(99)00056-0 ↗
24. Voltammetric current oscillations due to general and pitting corrosion of tantalum: implications for electrochemical-mechanical planarization10.1016/j.corsci.2010.05.031 ↗
25. Effect of bromide ions on the corrosion behavior of tantalum in anhydrous ethanol10.1016/j.electacta.2009.12.074 ↗
26. Electrochemical behaviors of tantalum in anhydrous ethanol containing hydrogen sulfate ions10.1016/S1003-6326(11)60696-1 ↗
27. Passivity pitting corrosion resistant pure metals Ta, Nb, Ti, Zr, Cr and Al in chloride solutions10.1016/S0010-938X(78)80087-0 ↗
28. Dielectric breakdown of anodic oxide films on valve metals10.1016/S0010-938X(67)80109-4 ↗
29. Kinetic of tantalum corrosion in aqueous electrolytes10.1149/1.2426597 ↗
30. Electrolytic breakdown crystallization of anodic oxide films on Al, Ta and Ti10.1016/0013-4686(70)80064-0 ↗
31. Breakdown of valve metal passivity induced by aggressive anions10.1016/S0013-4686(01)00664-8 ↗
32. Corrosion and passivity of metals in methanol solutions of electrolytes10.1007/s10008-008-0649-5 ↗
33. A study of the conductivity of certain acids and alkali halides in glycol and the influence of the addition of a second solvent10.1139/v58-065 ↗
34. Effect of water on proton migration in alcoholic solvent-I. The conductance of hydrogen chloride in n-butanol and iso-butanol at 25°C10.1016/0013-4686(71)85028-4 ↗
35. The electrochemistry of iron in methanolic solutions and its relation to corrosion10.1016/0010-938X(95)00052-L ↗
36. The Grotthus mechanism10.1016/0009-2614(95)00905-J ↗