journal article·2010-04

Oxidation of green rust suspensions containing different chromium ion species

Katsuya Inoue, Kozo Shinoda, Shigeru Suzuki, Yoshio Waseda

Corrosion Science· Volume 52· Issue 4
Publisher page

Abstract

Abstract The oxidation of hydrosulphate green rust (GR2(SO42−)) suspension containing different chromium ion species was investigated by X-ray diffraction, X-ray absorption spectroscopy and transmission electron microscopy. The pH, oxidation–reduction potential and amount of dissolved oxygen in aqueous solutions were measured during the reactions. The results show that the addition of Cr(III)2(SO4)3 solution suppresses the transformation of GR2(SO42−) into iron oxyhydroxides and oxides in aqueous solution, while the addition of Na2Cr(VI)O4 solution promotes the transformation of GR2(SO42−) in which Cr(VI) is reduced to Cr(III); α-FeOOH particles were refined by the addition of the chromium ions.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Iron oxide chemistry and applications · Phosphorus and nutrient management

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. Okada · Steel Inst. Jpn. · 1969 · 55 · 35510.2355/tetsutohagane1955.55.5_355 ↗
2. Misawa · Iron Steel Inst. Jpn. · 1993 · 79 · 6910.2355/tetsutohagane1955.79.1_69 ↗
3. Mössbauer spectroscopic study of rust formed on a weathering steel and a mild steel exposed for a long term in an industrial environment10.2320/matertrans.43.694 ↗
4. Cornell · 2003
5. Leygraf · 2000
6. Mass-balance and Eh−pH diagrams of FeII−III green rust in aqueous sulphated solution10.1016/j.corsci.2006.01.002 ↗
7. The Oxidation of ferrous hydroxide in chloride-containing aqueous media and pourbaix diagrams of green rust one10.1016/0010-938X(93)90101-L ↗
8. The preparation and thermodynamic properties of Fe(II)−Fe(III) hydroxide−carbonate (green rust 1); poubaix diagram of iron in carbonate-containing aqueous media10.1016/0010-938X(95)00096-3 ↗
9. Anion, cation distributions in Fe(II−III) hydroxysalt green rusts from XRD, Mössbauer analysis (carbonate, chloride, sulphate, …); the fougerite10.1016/j.solidstatesciences.2004.03.021 ↗
10. Formation of the Fe(II)−Fe(III) hydroxysulphate green rust during marine corrosion of steel10.1016/S0010-938X(02)00184-1 ↗
11. Mechanisms of formation and structure green rust one in aqueous corrosion of iron in the presence of chloride ions10.1016/S0010-938X(98)00066-3 ↗
12. Structure of the Fe(II−III) layered double hydroxysulphate green rust two from Rietveld analysis10.1016/S1293-2558(02)00019-5 ↗
13. In-situ X-ray diffraction of corrosion products formed on iron surfaces10.2320/matertrans.46.637 ↗
14. Ex-situ and in-situ X-ray diffractions of corrosion products freshly formed on the surface of an iron–silicon alloy10.1016/j.corsci.2006.06.029 ↗
15. Analysis of iron oxyhydroxides and oxides converted from green rust in aqueous solution10.2355/isijinternational.47.453 ↗
16. Characterization of different solid particles transformed from green rust in aqueous solution—using XRD, Mössbauer spectroscopy, and XANES10.2355/isijinternational.47.1452 ↗
17. Influence of manganese on iron oxyhydroxides and oxides formed in aqueous solution10.1016/j.corsci.2007.08.020 ↗
18. Reduction of copper ions in green rust suspension and oxidation of green rust containing metallic copper10.2320/matertrans.MAW200818 ↗
19. Characteristic behaviour of nickel ions during transformation of green rust to ferric oxyhydroxides in aqueous solution10.2320/matertrans.MBW200710 ↗
20. The long term growth of the protective rust layer formed on weathering steel by atmospheric corrosion during a quarter of a century10.1016/0010-938X(94)90158-9 ↗
21. Characterization of nanostructure of rusts formed on weathering steel10.2355/isijinternational.42.1534 ↗
22. Influence of chromium on the local structure and morphology of ferric oxyhydroxides10.1016/j.corsci.2003.10.011 ↗
23. Miyuki · Mater. Jpn. · 2002 · 41 · 3910.2320/materia.41.39 ↗
24. Local atomic structure around Ni, Nb, and Zr atoms in Ni−Nb−Zr−H glassy alloys studied by X-ray absorption fine structure method10.1063/1.3143039 ↗