journal article·2014-01

Thermal stability under air of tungsten–titanium diffusion barrier layer between silica and platinum

J. Nazon, P. Simon, B. Domenichini, S. Bourgeois

Corrosion Science· Volume 78
Publisher page

Abstract

Abstract The present work investigated the thermal stability of tungsten–titanium diffusion barrier layers intercalated between SiO 2 substrate and platinum thin film. The resulting structures were annealed under air in the temperature range 400–600 °C for annealing times up to 100 h. Chemical and structural characterizations at different stages of the treatment evidenced several phenomena occurring during annealing under air, especially the complete oxidation of the adhesive layer, the diffusion of tungsten oxide through platinum film at particle boundaries as well as the sublimation process of tungsten oxide. The results of film surface chemistry and microstructure were correlated with diffusion phenomena.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Semiconductor materials and devices · Semiconductor materials and interfaces · Copper Interconnects and Reliability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. A copper/polyimide metal–base packaging technology10.1007/BF02657424 ↗
2. Oxidation of Ta diffusion barrier layer for Cu metallization in thermal annealing10.1016/S0040-6090(01)00782-9 ↗
3. Diffusion barrier properties of TiW between Si and Cu10.1063/1.353135 ↗
4. Titanium–tungsten contacts to silicon. II. Stability against aluminum penetration10.1063/1.336470 ↗
5. Direct W–Ti contacts to silicon10.1063/1.95241 ↗
6. Al/TixW1−x metal/diffusion-barrier bilayers: interfacial reaction pathways and kinetics during annealing10.1063/1.366039 ↗
7. Diffusion of 18 elements implanted into thermally grownSiO210.1063/1.1624487 ↗
8. Interdiffusion of an Au/Ni/Cr multilayer metallization on silicon substrates10.1016/0040-6090(89)90535-X ↗
9. Reactively sputtered ZrNxbarrier films between Au and SiO2: surface and interface analysis10.1016/0169-4332(93)90566-T ↗
10. Tungsten–titanium diffusion barriers for silver metallization10.1016/j.tsf.2006.03.049 ↗
11. Stability of silver thin films on various underlying layers at elevated temperatures10.1016/S0040-6090(03)00034-8 ↗
12. Comparative study of Nb and TiW barrier layers between Au and a-SiO210.1116/1.572583 ↗
13. Stability of thin platinum films implemented in high-temperature microdevices10.1016/j.sna.2009.03.017 ↗
14. Highly (200)-oriented Pt films on SiO2/Si substrates by seed selection through amorphization and controlled grain growth10.1557/JMR.1999.0641 ↗
15. Titanium diffusion and residual stress of platinum thin films onTi/SiO2/Sisubstrate10.1063/1.1949715 ↗
16. Pt/Ti/SiO2/Si substrates10.1557/JMR.1995.1508 ↗
17. Influence of a TiO2adhesion layer on the structure and the orientation of a Pt Layer in Pt/TiO2/SiO2/Si structures10.1143/JJAP.42.2791 ↗
18. The support effect in oxidizing atmosphere on propane combustion over platinum supported on TiO2, TiO2–SiO2and TiO2–SiO2–WO310.1016/j.apcatb.2006.08.019 ↗
19. Total oxidation of propane on Pt/WOx/Al2O3 catalysts by formation of metastable Ptδ+ species interacted with WOx clusters10.1016/j.jhazmat.2012.05.011 ↗
20. Kern · 1979
21. Study of the structure and properties of thick vacuum condensates of nickel, titanium, tungsten, aluminium oxide and zirconium dioxide
22. High rate thick film growth10.1146/annurev.ms.07.080177.001323 ↗
23. TaC as a diffusion barrier between Si and Cu10.1063/1.1464652 ↗
24. XPS studies on surface reduction of tungsten oxide nanowire film by Ar+bombardment10.1016/j.elspec.2012.01.004 ↗
25. Highly sensitive hydrogen sensors based on co-sputtered platinum-activated tungsten oxide films10.1016/j.ijhydene.2010.10.011 ↗
26. Kinetics of platinum silicide formation followedin situby spectroscopic ellipsometry10.1116/1.581564 ↗
27. Deriving the kinetic parameters for Pt-silicide formation from temperature ramped in situ ellipsometric measurements10.1016/S0040-6090(99)00699-9 ↗
28. Nucleation and void formation mechanisms in SiC thin film growth on Si by carbonization10.1149/1.2044113 ↗
29. The formation of thin-film tungsten silicide annealed in ultrahigh vacuum10.1063/1.343587 ↗
30. Effects of anneal ambients and Pt thickness on Pt/Ti and Pt/Ti/TiN interfacial reactions10.1063/1.353212 ↗
31. Stress distributions in growing oxide films10.1016/S1359-6454(03)00009-0 ↗
32. Growth of epitaxial tungsten oxide nanorods10.1016/j.jcrysgro.2005.01.089 ↗
33. Structural and optical properties of WO3sputtered thin films nanostructured by laser interference lithography10.1016/j.apsusc.2013.03.072 ↗
34. CO sensing properties of W–Mo and tin oxide RGTO multiple layers structures10.1016/S0925-4005(03)00401-5 ↗
35. Study of tungsten oxidation inO2/H2/N2downstream plasma10.1116/1.2897316 ↗
36. Effect of the tungsten and molybdenum oxidation states on the thermal coloration of amorphous WO3and MoO3films10.1016/S0039-6028(01)00714-2 ↗